• Title/Summary/Keyword: PP2B

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Comparison of Structural Types of Proline Pentamer by Quantum Chemical Calculation (QCC)

  • Jae-Ho Sim
    • International Journal of Advanced Culture Technology
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    • v.11 no.2
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    • pp.323-329
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    • 2023
  • In this study, Proline pentamer model was used to investigate change in the dihedral angle, intramolecular hydrogen bonding and formation energies during structural optimization. L-Proline (LP, as an imino acid residue) pentamers having four conformation types [β: φ/ψ=t−/t+, α: φ/ψ=g−/g−, PPII: φ/ψ=g−/t+ and Plike: φ/ψ= g−/g+] were carried out by QCC [B3LYP/6-31G(d,p)]. The optimized structure and formation energy were examined for designated structure. In LP, P-like and PPII types did not change by optimization, and β types were transformed into PPII having no H-bond independently of the designated ψ values. PPII was more stable than P-like by about 2.2 kcal/mol/mu. The hydrogen bond distances of d2(4-6) type H-bonds were 1.94 - 2.00Å. In order to understand the processes of the transformations, the changes of φ/ψ, distances of NH-OC (dNH/CO) and formation energies (ΔE, kcal/mol/mu) were examined.

A study on evaluation of flexural toughness of synthetic fiber reinforced shotcrete (구조용 합성섬유 보강 숏크리트 휨인성 평가에 관한 연구)

  • Moon, Kyoung-Sun;Kim, Seog-Jin;Kim, Yeon-Deok;Min, Byeong-Heon;Kim, Sang-Hwan
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.3
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    • pp.433-452
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    • 2019
  • This study deals with shotcrete reinforcing performance according to the amount of synthetic fiber (PP fiber) and proper evaluation method. The shotcrete compressive strength, flexural strength and flexural toughness were tested by setting the mixing amounts of steel fiber ($37.0kg/m^3$) and synthetic fiber (PP fiber) as parameters ($5.0kg/m^3$, $7.0kg/m^3$ and $9.0kg/m^3$). Particularly, circular panel flexural toughness test (Road and Traffic Authority, RTA) was performed to evaluate the shotcrete energy absorption capacity. As a result, the compressive strength and the bending strength of the steel fiber reinforced shotcrete were large, but the flexural toughness of the synthetic fibe (PP fiber) reinforced shotcrete was large. Therefore, synthetic fiber (PP fiber) reinforced shotcrete is considered to have a reinforcing effect comparable to that of steel fiber reinforced shotcrete. Analysis of the relationship between the flexural toughness and the energy absorption capacity of synthetic fiber (PP fiber) reinforced shotcrete revealed that the energy absorbing ability is exhibited at a flexural toughness lower than the allowable standard (3.0 MPa). (Class A: 2.55 MPa = 202J, Class B: 2.72 MPa = 282J, Class C: 3.07 MPa = 403J). As a result of this study, it can be concluded that the actual shotcrete support performance can be evaluated by evaluating the support performance of the shotcrete measured at less than the allowable standard (3.0 MPa) at the actual tunnel site.

Changes in soft tissue chin resulting from premolar extraction and incisor retraction in adult female patients (성인 여성에서 소구치 발치와 전치부 후방 견인에 따른 이부 연조직 변화)

  • Kim, Yang-Hee;Son, Woo-Sung
    • The korean journal of orthodontics
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    • v.31 no.5 s.88
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    • pp.535-548
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    • 2001
  • The purpose of this study was to evaluate changes in soft tissue chin thickness and to investigate correlations between hard and soft tissues measurements after orthodontic treatment conducted by premolars extraction and incisor retraction. The sample consisted of 35 female adults with Angle classification class I or class II division 1 malocclusion. Using lateral cephalometric radiographs taken before and after treatment, hard and soft tissue structures were measured and reproducible six landmark on soft chin tissue were used to locate the various points of soft tissue contour of the chin. The res에ts were as follows : 1. There were signigicant correlations between pretreatment B-B', Pm-Pm' and pretreatment vortical skeletal measurements such as $MP{\perp}HP,\;MP{\perp}PP$, ALFH and between a-a', b-b', Me-Me' and measurements of sym-physeal morphology such as SL, SW, PL. 2. There were significant decreases at B-B', Pm-Pm' and significant increases at a-a', b-b' between pre-and posttreatment mea surements. 3. There were significant correlations among soft tissues changes and hard tissue changes except for changes at B-B' and the range of correlation coefficient was about 0.3-0.4. 4. There were significant differences at ${\Delta}UI-VP,\;LI{\perp}, and B-B' measurements between subgroups divided by posttreatment Pog-Pog' changes. 5. There were significant differences at ${\Delta}overbite,\;NPog{\perp}HP,\;and\;Me-Me'$ measurements between subgroups divided by posttreatment Me-Me' changes.

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Phylogenetic relationships of Coryloideae based on waxy and atpB-rbcL sequences (Waxy와 atpB-rbcL 염기서열 분석에 의한 Coryloideae의 계통 유연관계)

  • Yoo, Ki-Oug;Wen, Jun
    • Korean Journal of Plant Taxonomy
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    • v.38 no.4
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    • pp.371-388
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    • 2008
  • Phylogenetic studies were conducted for 35 populations of the subfamily Coryloideae (Betulaceae) based on waxy gene of nuclear DNA and atpB-rbcL intergenic spacer region of chloroplast DNA. Waxy data analysis suggest that Coryloideae is monophyletic; Corylus is monophyletic and basally branching within the subfamily Coryloideae; Ostryopsis is sister to the Carpinus and Ostrya clade, and the Ostrya is monophyletic (BS=86, PP=99). AtpB-rbcL intergenic spacer region analysis shows that Ostryopsis appeared as the most basal clade within the Coryloideae; Corylus is monophyletic(BS=98, PP=100) and placed between Carpinus-Ostrya and Ostryopsis clade; Carpinus and Ostrya formed a clade with a high support value(BS=100, PP=100). Carpinus sect. Carpinus is monophyletic, whereas sect. Distegocarpus is paraphyletic in the waxy tree. Corylus formed two subclades, but discordance at the infrageneric classification based on morphological characters. In the atpB-rbcL tree, Carpinus and Corylus taxa form a polytomy within the each clade. Results from the two data sets differ mainly in the relative position of Ostryopsis, the monophyly of Ostrya, and the relationships within the Carpinus-Ostrya clade. Further studies are needed for clarify the taxonomic position and the generic limitation.

A study of size and frictional effect on the evolution of melting PartII: Twin screw extruder

  • Kim, D.S.;Lee, B.K.;Kim, H.S.;Lee, J.W.;C.G. Gogos
    • Korea-Australia Rheology Journal
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    • v.13 no.2
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    • pp.89-95
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    • 2001
  • Effects of particulate size and frictional characteristics were examined on the melting behavior of PP(polypropylene) in a twin screw extruder. Powder and pellet types of PP were used and each component was blended with PE(polyethylene) wax and clay, respectively. It was observed that small size particulates, 1.e. powder systems exhibit accelerated melting behavior; and it was also found that the abrasive auditive acts as an effective agent for fast melting of PP powder. Retardation of melting due to the reduced friction was observed in both types of PP, contrary to the result found in a batch mixer. The tendency observed in variation of torque and exit temperature was explained in terms of frictional effect and length of compacted region formed during evolution of melting.

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Double layer $TiB_2$-TiN Films

  • LizhiChen;YunjieYang;ZhihongZheng;XiWang;XianghuaiLiu;Han, J.G.;Yoon, J.S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1995.06a
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    • pp.141-141
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    • 1995
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A follow-up study of electrocardiographic changes following the corrective surgery for atrial septal defect in adult (성인에 있어서 심방중격결손증 교정수술후 심전도의 경시적 변화에 관한 연구)

  • Lee, Young-Thak;Chae, Hurn;Suh, Kyung-Phill
    • Journal of Chest Surgery
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    • v.20 no.2
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    • pp.241-250
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    • 1987
  • We scrutinized the preoperative electrocardiographic and hemodynamic findings in adult atrial septal defects older than 15 years, and then followed up the postoperative electrocardiographic changes sequentially. In preoperative electrocardiographs, the mean PR interval [0.17 sec] was prolonged than normal adults [M;0.13,F;0.15], and the mean QRS axis [93.1*] was deviated to rightward than normal [M;63.7*,F;64.4*], and 122 cases of all 159 patients [77.8%] were in RAD quadrant. The QRS morphology was classified into three groups; a] crista supraventricularis hypertrophy, 25 cases, b] right ventricular outflow tract hypertrophy, 89 cases, c] right ventricular hypertrophy, 44 cases, and normal rs pattern, 1 case. Comparing the QP/QS, Pp/Ps, Rp/Rs in these three groups, Qp/Qs increased a] 2.65 to b] 2.97 and decreased b] 2.97 to c] 2.55, Pp/Ps increased a] 0.27 to b] 0.35 to c] 0.44, and Rp/Rs increased a] 0.1 to b] 0.14 to c] 0.2. In comparing the atrial fibrillation with sinus rhythm, the patient`s mean age was increased [26.4 to 45.7], the mean Qp/Qs was decreased [2.97 to 2.7], the mean Pp/Ps was increased [0.35 to 0.46], the mean Rp/Rs increased [0.14 to 0.2], and the QRS morphology was RVOT hypertrophy;7 cases, RVH;2 cases in all 11 cases. Therefore, the atrial fibrillation was appeared in progressed status. Increasing the mean pulmonary arterial pressure, size of the R` wave in Vl lead increased, and the QRS morphology tended to become severe patterns. Postoperatively, the PR interval shortened and QRS axis tended to normal axis quadrant, and size of R` wave decreased sequentially, atrial fibrillation disappeared in 4 cases. Conclusively, by use of the conventional surface electrocardiography, we could anticipate the hemodynamic changes and the prognosis at outpatient department.

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The bio-complex "reaction pattern in vertebrate cells" reduces cytokine-induced cellular adhesion molecule mRNA expression in human endothelial cells by attenuation of NF-kappaB translocation

  • Ronnau, Cindy;Liebermann, Herbert E. H.;Helbig, Franz;Staudt, Alexander;Felix, Stephan B.;Ewert, Ralf;Landsberger, Martin
    • BMB Reports
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    • v.42 no.2
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    • pp.106-112
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    • 2009
  • The bio-complex "reaction pattern in vertebrate cells"(RiV) is mainly represented by characteristic exosome-like particles - probably as reaction products of cells to specific stress. The transcription factor NF-kappaB plays a central role in inflammation. We tested the hypothesis that RiV particle preparations (RiV-PP) reduce cellular adhesion molecule (CAM) expression (ICAM-1, VCAM-1, E-selectin) by the attenuation of NF-kappaB translocation in human umbilical vein endothelial cells (HUVEC). After 4 hours, pre-incubation of HUVEC with RiV-PP before stimulation with TNF-alpha significantly reduced ICAM-1 (65.5${\pm}$10.3%) and VCAM-1 (71.1${\pm}$12.3%) mRNA expression compared to TNF-alpha-treated cells (100%, n=7). ICAM-1 surface expression was significantly albeit marginally reduced in RiV/TNF-alpha- treated cells (92.0${\pm}$5.6%, n=4). No significant effect was observed on VCAM-1 surface expression. In RiV/TNF-alpha-treated cells (n=4), NF-kappaB subunits p50 (85.7${\pm}$4.1%) and p65 (85.0${\pm}$1.8%) nuclear translocation was significantly reduced. RiV-PP may exert an anti-inflammatory effect in HUVEC by reducing CAM mRNA expression via attenuation of p50 and p65 translocation.

Effects of Planting Pattern and Plant density on Seed Production of a Modified Single Cross Corn Hybrid (파종양식과 재식밀도가 옥수수 변형단교잡종 교배친의 생육 및 채종량에 미치는 영향)

  • Park, K.Y.;Kang, Y.K.;Park, S.E.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.29 no.1
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    • pp.62-66
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    • 1984
  • One row of pollen parent to two rows of seed parent (1:2), 2:4 and solid (1:2) planting patterns (PP) were compared in seed parent densities of 3,500, 5,000 and 6,500 plants per 10 ares to determine effects of PP and plant density on growths of seed and pollen plants, and seed yield of seed parent of modified single cross corn hybrid. Planting pattern did not significantly affect agronomic characteristics of seed plant except ear number per 100 plants and seed yield which were greater in solid and 1:2 PP than in 2:4 PP. Significant PP x plant density interaction did not exist for agronomic characteristics of seed parent. In the seed parent, plant height and 100 kernel weight were not affected by plant density, but ear height, ear number per 100 plants, and kernel number per ear were linearly decreased with increased plant densities. Seed yield ranged from 330 to 460 kg per 10 ares and overall yield response to plant density was quadratic. Tassel length and spikelet number per tassel of the pollen parent were significantly affected by PP and plant density. Significant PP x plant density interaction existed for tassel length and spikelet number per tassel. Tassel length and spikelet number per tassel were greater in 1:2 and 2:4 PP compared to solid PP and were greatly reduced with increased plant densities in solid and 1:2 PP. The results indicated that 1:2 or 2:4 PP at around 5,000 plants per 10 ares for seed parent would be suitable for seed production of modified single cross com hybrid.

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Development of a SHA with 100 MS/s for High-Speed ADC Circuits (고속 ADC 회로를 위한 100 MS/s의 샘플링의 SHA 설계)

  • Chai, Yong-Yoong
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.2
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    • pp.295-301
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    • 2012
  • In this article, we have designed SHA, which has 12 Bit resolution at an input signal range of 1 $V_{pp}$ and operates at a sampling speed of 100 MS/s in order to use at front of high speed ADC. SFDR(Spurious Free Dynamic Range) of the proposed system drops to approximately 66.3 dB resolution when the input frequency is 5 MHz, and the sampling frequency is 100 MHz, however, the circuit without a feedthrough has 12 bit resolution with approximately 73 dB.