• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.12
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• pp.23-32
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• 2020

This study investigated the thermal degradation and fading behavior of PTT dyed with vat dye and its dyeing ability. The PTT sample was dyed with vat dye using an acid treatment and pad-steam method to improve the dyeing performance. This method made dye particle nanosize and allowed it to penetrate the polymer material easily. The sample dyed using the pad-steam method showed level dyeing and enhanced dyeing affinity, compared to the batch-dyeing method. The degradation behavior of PTT dyed with vat dye after each heat and UV treatment was examined with the change in tensile strength or K/S value on the sample. The tensile strength and K/S values of the sample dyed with vat dye after the heat and UV treatment decreased with increasing temperature and exposure time. Although they showed high degradation under severe conditions, its rate constant was improved compared to the samples dyed with disperse dye. Consequently, acid treatment and the pad-steam method resulted in the introduction of vat dye on PTT. In addition, the PTT dyed with vat dye showed enhanced thermal and UV resistance because of their high molecular weight and chemical structure for stable adsorption behavior.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.3
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• pp.587-596
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• 2021

Naval battleships have systems to perform special purposes, such as the Command and Fire Control System (CFCS). Some of the this equipment should be equipped with an Uninterruptible Power System (UPS ) to ensure operational continuity and the backup of important data, even during unexpected power outages caused by problems with the ship's power generator. Heavy combat losses can occur if the equipment cannot satisfy the function. Therefore, it is important to design a stable UPS. The battery and Battery Management System (BMS) are two of the most important factors for designing a stable UPS. A power outage will be encountered if the battery and BMS are not stable. The customer will be exposed to abnormal situations, loss of important tactical data, and inability to operate some of the CFCS. As a result, an enhanced safety system should be designed. Thus, this study implemented and verified the improved system in terms of three methods, such as comparative analysis of the batteries, improvement about leakage current of the circuit, and tests of the aggressive environmental resistance to improve the UPS for CFCS.

• Clean Technology
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• v.27 no.1
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• pp.24-32
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• 2021

Unburned carbon (UC) was successfully separated from fly ash by up to 85.8% in weight via froth flotation using soybean oil as a collector. An 18 wt% yield of microceramics (CM) could be achieved by employing a hydro cyclone separator located immediately after the flotation equipment. UC and CM were tested as alternatives to weight-adding material and polymer (especially polypropylene in this study) filler, respectively. Large particles of UC were broken down into smaller ones via ball milling to have an average particle diameter of 10.2 ㎛. When crushed UC was used as an alternative to clay as a rubber weight-adding material, a somewhat lower tensile strength and elongation rate than the allowed values were unfortunately obtained. In order to satisfy the standard limits, further treatment of UC is required to enhance surface energy for more intimate bonding with rubber. CM was observed in spherical forms with an average diameter of 5 ㎛. The surface of the CM particles was modified with phenol, polyol, stearic acid, and oleic acid so that the surface modified CM could be used as a polypropylene-filling agent. The flowability was good, but due to the lack of coupling forces with polypropylene, successful impact strength and flexural strength could not be obtained. However, when mixing the surface-modified CM with 1% silane by weight, a drastic increase in both the impact strength and flexural strength were obtained.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.25-33
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• 2020

To investigate the relationship between strain distribution and tensile properties of brittle material, five types of tensile coupon of carbon fiber reinforced polymer (CFRP) modified the tab portion in order to have a strain distribution including S0, SD1, SD2, SV1, SV2 were tested. The ultimate stress and strain of SD2 and SV2 which was intended to have larger strain distribution were smaller than those of SD1 and SV1, that was more clearly shown in the test results of the symmetric coupons (SV series) than the asymmetric coupons (SD series). In addition, the ultimate stress and strain of most coupons with strain distribution in this study were decreased when compared to the control group with uniform strain. These results were analyzed in various ways through 1) the average of the strain values directly measured by the strain gages, 2) the converted strain calculated by dividing the total deformation by the effective length, and 3) the ultimate effective strain derived from both the elastic modulus and the ultimate load. The values measured by strain gage indicates response of the local region precisely, but it does not represent the response from whole section. However, the converted strain and effective strain can supplement disadvantage of gage because they represent the average response of whole section. In particular, the effective strain can provide rupture strain conservatively, which can be utilized in practice, when the value obtained by strain gage was not effective due to gage damage or abnormal gage readings near ultimate load. This value provides a value that can be used even when partial rupture has occurred and is reasonably useful for specimens with strain distribution.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.61-67
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• 2021

In this study, the adsorption decolorization process of sea buckthorn oil was carried out to verify the possibility of the sea buckthorn oil as a natural UV absorber. The optimization was carried out by using the central composite design model-response surface methodology (CCD-RSM). The response values of CCD-RSM were selected as the decolorization effect through the process, acid value after decolorization, and UV absorbance of the decolored oil at 290nm. The amount of adsorbent, temperature and time were selected as the process variables for the experiments. According to the results of CCD-RSM, the results of optimization were all consistent. The optimal conditions, which satisfy CCD-RSM statically and mathematically, were 4.32 wt.%, 134.90 ℃, and 19.8 min for the amount of adsorbent, temperature and time, respectively. The estimated response values expected under these optimal conditions values were 94.78%, 2.08 mg/g KOH, and 2.91 for the decolorization effect, acid value and UV absorbance at 290 nm, respectively. Also the average error from actual experiment for verifying the conclusions was smaller than 2%. Therefore, it was confirmed that the application of CCD-RSM to the adsorption decolorization process of sea buckthorn oil showed a very high level of acceptable results and that the sea buckthorn oil has high possibility to be used as a natural UV absorber.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.9-16
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• 2020

A CFRP sheet has been applied as a structural reinforcement in the field, and various studies are conducted to evaluate the effect of CFRP sheets on reinforced concrete. Although many experiments were performed from previous studies, there are still limitations to analyze structural behaviors with various parameters in experiments directly. This study shows the FEA on structural behaviors of RC beams reinforced with CFRP sheets using ABAQUS software. To simulate debonding failure of CFRP sheets which is a major failure mode of RC beam with CFRP sheets, a cohesive element was applied between the bottom surface of RC beam and CFRP sheets. Both quasi-static method and 2-D symmetric FE model technique were performed to solve nonlinear problems. Results obtained from the FE models show good agreements with experimental results. It was found that reinforcement level of CFRP sheets is closely related to structural behavior of reinforced concrete including maximum strength, initial stiffness and deflection at failure. Also, as over-reinforcement of CFRP sheets could give rise to the brittle failure of RCstructure using CFRP sheets, an appropriate measure should be required when installing CFRP sheets in the structure.

• Membrane Journal
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• v.31 no.6
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• pp.434-442
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• 2021

Poly(vinylidene fluoride) (PVDF) membrane has a good membrane durability because of its high mechanical resistance, thermal and chemical stability. However, the strong hydrophobic property of PVDF membrane can induce a low water permeability and easy fouling by proteins and organic matters. In order to improve the anti-fouling properties of PVDF membrane, the PVDF mixed matrix asymmetric membranes impregnated with biofunctional material 𝛽-cyclodextrin (𝛽-CD) in the membrane structure were prepared by phase inversion method. The membrane filtration experiments of pure water and BSA solution were performed using the PVDF/𝛽-CD mixed matrix asymmetric membranes prepared according to the 𝛽-CD contents. The experiments showed that the introduction of 𝛽-CD into the PVDF polymer matrix contributed to increase in the hydrophilic property of the PVDF membranes, and this led to the reduction of contact angles and improvement of anti-fouling properties. The PVDF/𝛽-CD membrane which was prepared using the dope solution with a 2 wt% 𝛽-CD content represented 64 L/m²·h of pure water flux, 95% of BSA rejection and maximum 80% of flux enhancements compared to flux results of the pristine PVDF membrane.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.217-222
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• 2022

It is very important to analyze the OCV change behavior during the open circuit potential holding (OCV holding) process, which accelerates the evaluation of the electrochemical durability of the PEMFC membrane. In this study, an empirical formula using the experimental data of three MEAs with different durability was created and compared. The durability evaluation time of the reinforced membrane MEA without radical scavenger inside the membrane was 383 h, and the durability evaluation time of the reinforced membrane MEA with radical scavenger inside the membrane was 1,000 and 1,650 h, respectively. The degradation of the membrane was divided into the reversible degradation that can be recovered by activation and the irreversible degradation that is not recovered. The irreversible degradation of the membrane was indicated by an increase in hydrogen permeability, and the change in hydrogen permeability was similar to the irreversible degradation constant c of all three MEAs. The initiation of irreversible deterioration without recovery is indicated by an increase in hydrogen permeability, and the OCV is not recovered due to an increase in hydrogen permeability, so the slope of the OCV recovery line (ORL) decreases, which can be confirmed by an increase in the constant c value of the empirical formula.

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.296-301
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• 2022

Due to the fact that zirconium based metal-organic frameworks (Zr-MOFs), such as UiO-66, have a large specific surface area and excellent selective adsorption capacity, Zr-MOFs are gaining attention as materials that can provide protection from the attack of chemical warfare agents in battleground. However, most of the metal-organic frameworks have an issue of selective adsorption capacity degraded by water molecules when exposed to the atmosphere, because of the weak metal-organic ligand bonds and the presence of voids. Therefore, polydimethylsiloxane (PDMS), a representative hydrophobic polymer material, was coated on the surface of UiO-66 to enhance the sustainability of the diisopropyl methylphosphonate (DIMP) sorption capacity in the battleground condition. Through the analysis of surface structure and organic functional group distribution of PDMS coated UiO-66, silicon was confirmed to be evenly coated. The contact angle increased by over 30° for the PDMS coated UiO-66, indicating that the hydrophobicity was improved. In addition, both the UiO-66 and PDMS coated UiO-66 were used as adsorbents for DIMP, a similar chemical warfare agent, to investigate the durability of adsorption capacity in a high humidity environment. The PDMS coated UiO-66 showed higher durability of adsorption capacity for 20 days than that of pristine UiO-66.

• Journal of the Korean Electrochemical Society
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• v.24 no.4
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• pp.100-105
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• 2021

Recently, all-solid-state batteries have attracted much attention to improve safety of rechargeable lithium batteries, but the solid-state batteries of conductive ceramics or solid polymer electrolytes show poor electrochemical properties because of several problems such as high interfacial resistance and undesired reactions. To solve the problems of the reported all-solid-state batteries, a hybrid solid electrolyte is suggested, in this study, NASICON-type nanoparticle Li_1.5Al_0.5Ti_1.5P₃O₁₂ (LATP) conductive ceramic, PVdF-HFP, and a carbonate-based liquid electrolyte were composited to prepare a quasi-solid electrolyte. The hybrid solid electrolyte has a high voltage stability of 5.6 V and shows an suppress effect of lithium dendrite growth in the stripping-plating test. The LiNi_0.83Co_0.11Mn_0.06O₂ (NCM811)-based battery with the hybrid solid electrolyte exhibits a high discharge capacity of 241.5 mAh/g at a high charge-cut-off voltage of 4.8V and stable electrochemical reaction. The NCM811-based battery also shows 139.4 mAh/g discharge capacity without short circuit or explosion at 90℃. Therefore, the LATP-based hybrid solid electrolyte can be an effective solution to improve the safety and electrochemical properties of rechargeable lithium batteries.