• Title/Summary/Keyword: POLYCARBONATE

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Ultrashort Pulsed Laser Machining for Biomolecule Trapping

  • Choi, Hae-Woon;Farson, Dave F.;Lee, L.James;Lee, Ho
    • Journal of the Optical Society of Korea
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    • v.13 no.3
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    • pp.335-340
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    • 2009
  • Ultrashort pulse laser drilling of polycarbonate track-etched membrane (pTEM) material was used to fabricate a mouse embryo cell trapping device. Holes with a diameter of $2{\mu}m$ to $5{\mu}m$ were fabricated on a $10{\mu}m$ thick membrane using a femtosecond laser with a 150 fs pulse width and 775 nm wavelength and multiple-pulse irradiation. In cell trapping tests, the overall cell occupancy of the machined holes in the fabricated pTEM was found to be more than 80%. The results of a single pulse and multiple pulse irradiation were compared in terms of the surface quality. It was generally found that a single pulse with high energy was less desirable than irradiation with multiple pulses of lower energy.

Fabrication and Characteristics of Indium Tin Oxide Films on Polycarbonates CR39 Substrate for OTFTs

  • Kwon, Sung-Yeol
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.232-235
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    • 2007
  • Indium tin oxide (ITO) films were deposited on polycarbonate CR39 substrate using DC magnetron sputtering. ITO thin films were deposited at room temperature because glass-transition temperature of CR39 substrate is $130^{circ}C$ ITO thin films are used as bottom and top electrodes and for organic thin film transparent transistor (OTFT). The electrodes electrical properties of ITO thin films and their optical transparency properties in the visible wavelength range (300-800 nm) strongly depend on the volume of oxygen percent. The optimum resistivity and transparency of ITO thin film electrode was achieved with a 75 W plasma power, 10 % volume of oxygen and a 27 nm/min deposition rate. Above 85% transparency in the visible wavelength range (300-800 nm) was measured without post annealing process, and resistivity as low as $9.83{\times}^{TM}10^{-4}{\Omega}$ cm was measured at thickness of 300 nm.

Electro-optic Properties of a Guest-Host System Containing a Phenothiazine-based Chromophore: Effect of the Chromophore Density on the Macroscopic Optical Nonlinearity

  • Lee, Sang-Kyu;Cho, Min-Ju;Yoon, Hyuk;Lee, Seung-Hwan;Kim, Jae-Hong;Qing Zhang;Choi, Dong-Hoon
    • Macromolecular Research
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    • v.12 no.5
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    • pp.484-489
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    • 2004
  • We have prepared a phenothiazine-based nonlinear optical (NLO) chromophore that displays a fairly high microscopic nonlinearity through intramolecular charge transfer. The phenothiazine unit plays important roles of contributing its high electron donating ability and connecting the resonance pathway through a conjugative effect in the cyclized ring adjacent to the aromatic ring. Theoretical calculations and an absorption spectroscopic study provided useful information concerning the microscopic nonlinearity of the chromophores. We investigated the electro-optic (EO) properties of the guest-host systems in amorphous polycarbonate containing the synthesized chromophores at different concentrations under different poling temperatures. A real-time pole and probe method provided a much greater amount of information regarding how the EO properties can arise and how they can be optimized.

Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS

  • Nguyen, Congtranh;Kim, Jin-Hwan
    • Macromolecular Research
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    • v.16 no.7
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    • pp.620-625
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    • 2008
  • A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.

Evaluation of Mechanical Characteristic of Plate-Type Polymer in Thermal-Nanoindentation Process for Hyperfine Pit Structure Fabrication (극미세 점 구조체 제작을 위한 열간나노압입공정에서 평판형 폴리머소재의 기계적 특성 평가)

  • Lee, E.K.;Lee, S.M.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.10a
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    • pp.108-111
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    • 2007
  • It's important to measure quantitative properties about thermal-nano variation conduct of polymer for producing high quality components using NIL process. NanoScale indents can be used ad cells for molecular electronics and drug deliver, slots for integration into nanodevices, and defects for tailoring the structure and properties. In this study, it's to evaluate mechanical characteristic of polymer such as PMMA and PC at high temperature for manufacture of nano/micro size of polymer using indenter at high temperature. At high temperature mechanical properties of polymer have extreme variation. Because heating the polymer, it becomes softer than room temperature. In this case it is especially important to study for mechanical properties of polymer at high temperature.

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Rejection Properties of Silica Nanoparticles from Ultrafiltration Membranes

  • Hiromitsu Takaba;Yoshiaki Ito;Nakao, Shin-ichi
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.54-60
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    • 2003
  • The rejection properties and flux rates of silica nanoparticles in ultrafiltration membranes has been investigated. Cross-flow permeation experiments were conducted using polycarbonate track-etch flat membranes with pore sizes of 30 and 50 nm, and a silica nanoparticle solute with particle sizes of 5 and 18 nm with narrow size distributions. The fluxes and rejection factors were investigated at various particle concentrations, cross-flow velocities, pH, and ionic strengths of solution. Even though the size of the silica nanoparticles was much smaller than that of the membrane pores, the observed rejection rates were very high compared with those for a similar-sized polymer (dextran). The observed rejection rate decreased with increasing ionic strength, which implies that the transport mechanism of the silica nanoparticles is significantly influenced by electrostatic repulsion between particles and membranes.

Transport of Transferrin-Horseradish Peroxidase Conjugate Through Cultured Caco-2 Cell Monolayer (배양 Caco-2 세포 단층막 실험계에서 트란스페린과 옥시다아제효소 포합체의 세포막투과)

  • Kim, Dong-Chool;Kim, Jie-Hae
    • Journal of Pharmaceutical Investigation
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    • v.29 no.4
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    • pp.287-293
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    • 1999
  • Transport study of horseradish peroxidase and transferrin-horseradish peroxidase conjugate was performed using an in vitro Caco-2 cell cultured monolayer grown on a polycarbonate membrane of $Transwell^{\circledR}$, Horseradish peroxidase was not transported across Caco-2 cell monolayer. Transferrin-horseradish peroxidase conjugate was transported through Caco-2 cell monolayer. The apparent membrane permeability coefficient $(P_{app})$ of transferrin horseradish peroxidase conjugate was $6.54{\times}10^{-7}\;cm/sec$. The $P_{app}$ value of transferrin-horseradish peroxidase conjugate across Caco-2 cell monolayer was increased to $11.9{\times}10^{-7}\;cm/sec$ in the presence of $50\;{mu}g/ml$ brefeldin-A. These results suggest the transferrin receptor mediated transcytosis of transferrin-horseradish peroxidase conjugate across Caco-2 cell monolayer.

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Cytotoxicity of Environmental Estrogenic Compound, Bisphenol A, via Generation of Free Radicals (내분비계 장애물질인 Bisphenol A의 free radical 생성을 통한 독성발현)

  • 안광현;김봉희
    • Environmental Analysis Health and Toxicology
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    • v.18 no.3
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    • pp.175-182
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    • 2003
  • Bisphenol A shares similarities in structure, metabolism and action with DES, a known human teratogen and carcinogen. Bisphenol A, a monomer of polycarbonate and epoxy resins, has been detected in canned food and human saliva. The purpose of the this study was to evaluate the cytotoxicity, cell proliferation of bisphenol A In the presence of a rat liver S9 mix, contaning cytochrome P450 enzymes, and Cu (II). In the present study, Bisphenol A in combination with Cu (II) exhibited a enhancement in cytotoxicity which were inhibited by free radical scavengers. The content of malondialdehyde, an end product of lipid peroxidation, was also found to increase with concentration of bisphenol A. Also, we examined the change of CuZn-SOD, Mn-SOD, catalase and GPx activities in the MCF-7 cells exposed to bisphenol A. The activities of CuZn-SOD, CPx, catalase were found to decrease with bisphenol A concentration. Meanwhile, the activity of Mn-SOD was unchanged. This indicated that elevated oxidative stress caused by imbalance between the production and removal of free radicals occurred in cells.

Dispersions of partially reduced graphene oxide in various organic solvents and polymers

  • Kim, Hye Min;Kim, Seo Gyun;Lee, Heon Sang
    • Carbon letters
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    • v.23
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    • pp.55-62
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    • 2017
  • We report on the dispersion state of partially reduced graphene oxide (PRGO) in organic solvents, namely methyl ethyl ketone, ethyl acetate, methylene chloride, toluene, and xylene, by controlling the carbon to oxygen (C/O) atomic ratio of the PRGOs. A two-phase solvent exchange method is also proposed to transfer PRGO from water to an aprotic solvent, such as methyl ethyl ketone. We achieve relatively good dispersion in aprotic and non-polar solvents by controlling the C/O atomic ratio of the PRGOs and applying the two-phase solvent exchange method. There is an increase in the glass transition temperatures with the dispersion of PRGOs into amorphous polymers, in particular a $4.4^{\circ}C$ increase for poly(methyl methacrylate) and $3.0^{\circ}C$ increase for polycarbonate. Good dispersion of PRGO in a nonpolar polymer, such as linear low density polyethylene, is also obtained.

The Development of Decal Panel for Night Vision Imaging System of Aircraft (항공기 야시조명계통 데칼패널 개발)

  • 권종광
    • Journal of the Korea Institute of Military Science and Technology
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    • v.6 no.2
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    • pp.35-44
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    • 2003
  • A Decal Panel is developed for the Night Vision Imaging System of XKO-1 aircraft. The Decal Panel is a kind of lighting system kits and is installed on each system switch box in crewstation. The Decal Panel consists of upper panel made of polycarbonate and lower panel which is a printed circuit board. This paper includes the design, manufacture, test and evaluation of Decal Panel in addition to items and conditions of environmental test. Besides it is confirmed the Key for manufacturing a decal panel, is depth of paint, dry time period and frequency, and diffusion material for spreading of light.