• Bulletin of the Korean Chemical Society
• /
• v.10 no.2
• /
• pp.161-167
• /
• 1989

The results of ab initio(MP2/6-31G) molecular orbital calculations of the dipole moment derivatives and gas phase IR intensities in chloromethanes are reported. The theoretical polar tensors are analyzed into the net charge, charge-flux, and overlap contributions. The charge-flux contribution was found to be dominant in the Cl atom polar tensor, while the net charge effect was the most prominent contribution for the H atom polar tensor. The Cl atom polar tensor appeared, in a good approximation, to be transferable among various chloro molecules. On the other hand, for the prediction of IR spectra of complex hydrocarbons containing chlorine atoms, some empirical adjustment of the H-atom polar tensor seemed to be made depending on the number of Cl atoms bound to the certain carbon atom.

• ETRI Journal
• /
• v.45 no.1
• /
• pp.150-162
• /
• 2023

The polar delta-sigma modulator (DSM) transmitter architecture exhibits good coding efficiency and can be used for software-defined radio applications. However, the necessity of high clock speed is one of the major drawbacks of using this transmitter architecture. This study proposes a low-complexity timeinterleaved architecture for the polar DSM transmitter baseband part to reduce the clock speed requirement of the polar DSM transmitter using an upsampling technique. Simulations show that using the proposed four-branch timeinterleaved polar DSM transmitter baseband part, the clock speed requirement of the transmitter is reduced by four times without degrading the signal-tonoise-and-distortion ratio.

• ETRI Journal
• /
• v.46 no.2
• /
• pp.175-183
• /
• 2024

Recently, polar code has attracted the attention of many scholars and has been developed as a code technology in coded-cooperative communication. We propose a polar code scheme based on Plotkin structure and quasi-uniform punching (PC-QUP). Then we apply the PC-QUP to coded-cooperative scenario and built to a new coded-cooperative scheme, which is called PCC-QUP scheme. The coded-cooperative scheme based on polar code is studied on the aspects of codeword construction and performance optimization. Further, we apply the proposed schemes to space-time block coding (STBC) to explore the performance of the scheme. Monte Carlo simulation results show that the proposed cooperative PCC-QUP-STBC scheme can obtain a lower bit error ratio (BER) than its corresponding noncooperative scheme.

• Atmosphere
• /
• v.19 no.1
• /
• pp.79-91
• /
• 2009

Seoul National University General Circulation Model (SNUGCM) has been run for 100 years to obtain daily temperature and meridional velocity at the Northern lower stratosphere. The model results are compared with the NCEP/NCAR reanalysis data. The polar temperature and the eddy heat flux from the model show that the model-produced climatology has well-known cold bias and weaker planetary wave activities. The model climatology also has a lag in the seasonal evolution. The relationship between the model-produced polar temperature and the eddy heat flux is investigated with respect to the interannual and decadal time scales. The interannual variation of the polar temperature is related with both total and stationary eddy heat flux in January and March, which is in agreement with observation. The model, however, does not reproduce the relationship between the decadal variation of the polar temperature and transient eddy heat flux, which is revealed in the observed data.

• Journal of Astronomy and Space Sciences
• /
• v.27 no.1
• /
• pp.43-54
• /
• 2010

This study was performed by the policy research project of Ministry of Land, Transport and Maritime Affairs, which title is "Developing safety standards and management of space radiation on the polar route". In this research, total six experiments were performed using Korean commercial flights (B747). Three of those are on the polar route and the other three are on the north pacific route. Space radiation exposure measured on the polar route is the average 84.7 uSv. The simulation result using CARI-6M program gives 84.9 uSv, which is very similar to measured value. For the departure flight using the north pacific route, the measured space radiation is the average 74.4 uSv. It seems that is not so different to use the polar route or not for the return flight because the higher latitude effect causing the increase of space radiation is compensated by the shortened flight time effect causing decreasing space radiation exposure.

• Journal of Microbiology and Biotechnology
• /
• v.18 no.6
• /
• pp.1016-1023
• /
• 2008

Lichens are predominant and important components of flora in the terrestrial ecosystem of Antarctica. However, relatively few researches on the phylogenetic position of Antarctic lichen-forming fungi have been accomplished. In this study, partial sequences of nuclear large subunit rDNAs from 50 Antarctic specimens were obtained and the phylogeny was reconstructed. Antarctic lichen species were distributed in 4 orders, including the monophyletic order Agyrales, paraphyletic orders Pertusariales and Teloschistales, and polyphyletic order Lecanorales. Species diversity was highest in the order Lecanorales, followed by Teloschistales and Pertusariales. Based on the phylogeny and sequence similarity analyses, it is proposed that the taxonomy of Stereocaulon alpinum, Physcia caesia, Usnea aurantiacoatra, and Cladonia species should be revised by careful examination of their phenotypic and molecular characteristics. Six species known to be endemic to Antarctica, Catillaria corymbosa, Himantormia lugubris, Leptogium puberulum, Pertusaria pertusa, Rhizoplaca aspidophora, and Umbilicaria antarctica, formed unique lineages, implying independent origins in the Antarctic area.

• Ocean and Polar Research
• /
• v.23 no.4
• /
• pp.395-400
• /
• 2001

A time-series sediment trap was deployed at 1,034 m water depth in the eastern Bransfield Strait from December 25, 1998 to December 24, 1999. About 99 % of total mass fluxes were observed during the austral summer and fall (January, February, and March). The annual total mass flux was $49.2g\;m^{-2}$. Biogenic materials including biogenic silica, organic matter, and carbonate accounted for about 67% of total particle flux, and lithogenic materials contributed about 29%. Biogenic silica was the most dominant (42% of the total flux) in these components. The next most important biogenic component was organic matter, comprising 24% of total mass flux. Calcium carbonate contributed a small fraction of total mass flux, only 0.6%. The annual organic carbon flux was $5.2g\;C\;m^{-2}$ at 1,034m water depth. The annual primary production was estimated to be $21.6g\;C\;m^{-2}$ at the sediment trap site, which seems to be highly underestimated. About 5.5% of the surface water production of organic carbon sinks below 1,034m water depth.

• Journal of Astronomy and Space Sciences
• /
• v.31 no.2
• /
• pp.169-176
• /
• 2014

Since the operation of the King Sejong Station (KSS) started in Antarctic Peninsula in 1989, there have been continuous efforts to perform the observation for the upper atmosphere. The observations during the initial period of the station include Fabry-Perot Interferometer (FPI) and Michelson Interferometer for the mesosphere and thermosphere, which are no longer in operation. In 2002, in collaboration with York University, Canada, the Spectral Airglow Temperature Imager (SATI) was installed to observe the temperature in the mesosphere and lower thermosphere (MLT) region and it has still been producing the mesopause temperature data until present. The observation was extended by installing the meteor radar in 2007 to observe the neutral winds and temperature in the MLT region during the day and night in collaboration with Chungnam National University. We also installed the all sky camera in 2008 to observe the wave structures in the MLT region. All these observations are utilized to study on the physical characteristics of the MLT region and also on the wave phenomena such as the tide and gravity wave in the upper atmosphere over KSS that is well known for the strong gravity wave activity. In this article, brief introductions for the currently operating instruments at KSS will be presented with their applications for the study of the upper atmosphere.

• The Journal of the Institute of Internet, Broadcasting and Communication
• /
• v.14 no.5
• /
• pp.55-59
• /
• 2014

Multi-band and multi-mode transmitters are needed for SDR and CR. Recently many types of polar transmitters have been studied in order to implement a multi-band and multi-mode transmitter. Polar transmitters have many advantages, such as a simple structure, high efficiency and etc. In this paper we consider the number of D/A bit and the effects of a delay mismatch as design parameters for implementing polar transmitters. From the simulation we know that a 10 bit D/A is sufficient and a delay mismatch must be maintained small than 1/64 chip for satisfying the spectrum mask characteristics. We implement a polar transmitter based on the design parameters and the measured output signal meet the spectrum mask of 800MHz CDMA.

• Ocean and Polar Research
• /
• v.28 no.3
• /
• pp.215-224
• /
• 2006

Spatial variation of heavy metal accumulation was investigated in Manila clam Ruditapes philippinarum collected from several tidal flats. Sediment metal levels varied highly among the sites, which was attributed primarily to differences in Fe and organic carbon contents and in part to gain size. Significant differences in metal concentrations also were found in the clam tissue among the different sampling sites. However, except for a few metals (Mn, Zn, Pb), which showed some elevation, the variations in the clam tissue were not related to the variations in the sediment. This is likely because most metals in filter-feeding herbivores such as R. philippinarum accumulated as a result of feeding on suspended particles such as phytoplankton and organic detritus in the water column, not in bottom sediment. In addition, tissue weight for a specific shell size varied significantly among the sites, and increased tissue mass indicating a good nutritive condition likely caused a subsequent dilution of body metals leading to reduced weight-specific concentrations of some metals (Cd, Zn, Cu, Co).