• Title/Summary/Keyword: PMMA resin

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Preparation and Characteristics of PC and PMMA-Based Diffusers for LED Backlight Unit (PC 및 PMMA 수지를 이용한 LED 백라이트용 확산판의 제조 및 특성 연구)

  • Kim, Nam Yi;Kim, Hyo Jin;Kim, Dong Won;Jo, Jae Hyun;Kim, Seong Woo
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.1
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    • pp.21-27
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    • 2012
  • The optical diffuser for direct-lit LED backlight unit was prepared by using extrusion compounding followed by thermoforming process. Poly(methyl methacrylate) (PMMA) with superior optical characteristics and polycarbonate (PC) with good thermal property were used as base resins, and crosslinked polystyrene (PS) and PMMA beads as diffusing agents were incorporated into resin matrix to derive light scattering and diffusing action. In the compounded plate, the diffusing beads were observed to be dispersed uniformly and distinctly in the continuous phase. The inclusion of polymeric beads up to 3 wt% substantially enhanced the optical characteristics such as luminance, luminance uniformity, haze for the diffuser. Two different diffusers of PC and PMMA-based compound with various compositions were compared in terms of measured optical, thermal, and mechanical properties, which would be expected to be utilized for the industrial application of LED backlight unit.

Surface characteristics and bonding performance of polymer restorative materials for dental CAD/CAM systems (치과 캐드캠 시스템에서 사용되는 고분자 수복재료들의 표면특성과 접착양상)

  • Kim, Jae-Hong;Kim, Ki-Baek
    • Journal of Technologic Dentistry
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    • v.41 no.3
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    • pp.203-209
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    • 2019
  • Purpose: The purpose of this study was to investigate the mechanical properties of polymer prosthetic and restorative materials for dental CAD/CAM using two test method; surface characteristics and shear bond strength. Methods: Commercialized CAD/CAM polymer blanks were investigated; One kinds of PMMA, and one PEKK blanks. A total of 20 PMMA and PEKK specimens were prepared, and each group was divided into 10 specimens. Average surface roughness was observed under surface profilometer. The contact angle was measured with a surface electrooptics. The bond strength was evaluated by a universal testing machine at a crosshead speed of 5mm/min. The data were statistically analyzed using independent t-test and Fisher's exact test(P<0.05). Results: The PMMA and PEKK group showed a significant difference in the shear bond strength with the composite resin(P<0.05). The surface roughness of the PEKK group was higher than that of the PMMA group. The fracture mode were observed in PEKK groups with 50% showing adhesive remnant index score. Conclusion: PEEK is used as substructure material and composite veneering material is applied. PEKK resins will contribute to the development of successful products that will provide structural and aesthetic satisfaction.

Effect of BLU Ingredient on Electrical and Optical Properties of Light Diffusing Film used for TFT-LCD TV (백라이트 유니트 구성요소가 TFT-LCD TV용 광확산필름의 전기, 광학적 특성에 미치는 영향)

  • Ahn, Cheol-Heung;Kim, Geon-Joong
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.397-402
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    • 2006
  • We have investigated the effect of each ingredient in the light diffusing film (LDF) which was used as backlight unit (BLU) of TFT-LCD TV on physical, electrical, thermal and optical properties of LDF. In anti-blocking layer, the excellent anti-blocking ability was obtained when 0.5~1.5 wt% of acrylic bead was added, and good decay-time and water-stability were shown when 0.8 wt% of tertiary ammonium salt was added. Optimal results for adhesion strength, curing rates and flexibility on the surface of PET film have been obtained in the light diffusing layer by using acrylic polyol as a binder resin, and by addition of 30~35 wt% non-yellowing type HDI crosslinker. In addition, the highest normal luminance value was obtained by addition of 250 wt% poly-dispersive polystyrene ($20{\mu}m$ PS) and polymethylmethacrylate ($20{\mu}m$ PMMA) beads into the binder resin (100 wt%). The higher normal luminance could be got for PMMA beads than PS beads because of the transmittance difference.

Interfacial fracture analysis of human tooth/composite resin restoration using acoustic emission (음향방출법을 이용한 치아/복합레진 수복재의 계면부 파괴해석)

  • Gu, Ja-Uk;Choi, Nak-Sam;Arakawa, Kazuo
    • Composites Research
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    • v.22 no.6
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    • pp.45-51
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    • 2009
  • The marginal integrity at the composite resin-tooth interface has been analyzed in real time through acoustic emission (AE) monitoring during the polymerization shrinkage of composite resin subjected to the light exposure. It was found that AE signals were generated by the polymerization shrinkage. Most AE hit events showed a blast type signal having the principal frequency band of 100-200kHz. Bad bonding states were indicated by many hit events in the initial curing period of 1 minute with high contraction rate. The quantity of hit events for the human molar dentin specimen was much less than that for the steel ring specimen but more than that for the PMMA ring specimen. The better the bonding state, the less the AE hit events. The AE characteristics were related with the tensile crack propagation occurring in the adhesive region between the composite resin and the ring substrate as well as the compressive behavior of the ring substrate, which could be used for a nondestructive characterization of the marginal disintegrative fracture of the dental restoration.

Synthesis of Acryl Phosphate Antistatic Agent and Its Effect on the Antistatic, Thermal and Mechanical Properties of PMMA

  • Park, Eu-Soo;Cho, Eun-Bum;Kim, Duk-Joon
    • Macromolecular Research
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    • v.15 no.7
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    • pp.617-622
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    • 2007
  • A simple and economic antistatic agent, (2-methacryloyloxyethyl)acid phosphate (acryl phosphate), was synthesized via the reaction of 2-hydroxyethyl methacrylate with phosphorus pentoxide. The acryl phosphate antistatic agent, synthesized in this study, was introduced into poly(methyl methacrylate) (PMMA) resin via copolymerization with MMA. This antistatic agent provides the PMMA matrix with excellent antistatic properties, including surface resistance and electric charge. A comparison of the present antistatic agent with other commercial agents demonstrated the excellence of not only its electrical, but also its thermal and mechanical properties.

Precision evaluation of impression surface of lower complete dentures reinforced with glass fiber (유리섬유 보강재를 삽입한 하악 레진의치 인상면의 정밀성 평가)

  • Kim, Dong-Yeon;Yang, Cheon-Seung;Lee, Gwang-Young;Kim, Ji-Hwan
    • Journal of Technologic Dentistry
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    • v.42 no.1
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    • pp.27-33
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    • 2020
  • Purpose: This study is to compare and analyze the precision of glass fiber resin dentures. Methods: A lower edentulous model was prepared. Ten study models were produced using Type IV stone. Ten wax lower resin dentures containing artificial teeth were prepared. The lower wax denture was buried with plaster and deflasking was performed to remove the wax. Five conventional lower resin dentures and five glass fiber lower resin dentures were produced. The scanning spray was coated on the impression surface and then scanned. Independent sample t-test were performed using statistical software. Results: In the color different map, which is a qualitative evaluation, the green area of the precision of the conventional lower resin denture occupied the whole. The glass fiber conventional resin dentures had many negative and positive area. In quantitative evaluation, the RMS of conventional lower resin was 89.83 ㎛ and that of fiberglass resin was 224.92 ㎛. The two groups showed statistically significant differences (p<0.05). Conclusion: Conventional lower resin dentures were superior in precision, and glass fiber resin dentures would have to improve the process.

Biofilm-forming ability and adherence to poly-(methyl-methacrylate) acrylic resin materials of oral Candida albicans strains isolated from HIV positive subjects

  • Uzunoglu, Emel;Bicer, Arzu Zeynep Yildirim;Dolapci, Istar;Dogan, Arife
    • The Journal of Advanced Prosthodontics
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    • v.6 no.1
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    • pp.30-34
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    • 2014
  • PURPOSE. This study evaluated the adhesion to acrylic resin specimens and biofilm formation capability of Candida albicans strains isolated from HIV positive subjects' oral rinse solutions. MATERIALS AND METHODS. The material tested was a heat-cured acrylic resin (Acron Duo). Using the adhesion and crystal violet assays, 14 oral Candida albicans isolated from HIV-positive subjects and 2 references Candida strains (C. albicans ATCC 90028 and C. albicans ATCC 90128) were compared for their biofilm production and adhesion properties to acrylic surfaces in vitro. RESULTS. There were no significant differences in adhesion (P=.52) and biofilm formation assays (P=.42) by statistical analysis with Mann-Whitney test. CONCLUSION. Denture stomatitis and increased prevalence of candidal carriage in HIV infected patients is unlikely to be related to the biofilm formation and adhesion abilities of C. albicans to acrylic resin materials.

Behavior of Polymerization Shrinkage Stress of Methacrylate-based Composite and Silorane-based Composite during Dental Restoration (Methacrylate 기질 복합레진과 Silorane 기질 복합레진의 치아 수복 시 중합수축응력거동)

  • Park, Jung-Hoon;Choi, Nak-Sam
    • Composites Research
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    • v.28 no.1
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    • pp.6-14
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    • 2015
  • Polymerization shrinkage stress analysis of dimethacrylate-based composite (Clearfil AP-X, Kuraray) and silorane-based composite (Filtek P90, 3M ESPE) used for dental composite restorations was performed using strain-gage measurement and FEM analysis. A theoretical equation based on Young's modulus and polymerization shrinkage of the composite resin was proposed to predict the polymerization shrinkage stress. Experimental results showed that the maximum shrinkage stress of Clearfil AP-X was about 2.8 times higher than Filtek P90. FEM analysis agreed with such experimental stress behaviours and showed that the maximum Von-Mises stress appeared near the margin of the filled resin adhered with PMMA ring. The stress concentration at the interface on the specimen surface was higher than that in the interior. The maximum error of shrinkage stress by the theoretical equation was reasonable within 5% in comparison to FEM results under plane stress.

Physical Properties of Medical Radiation Shielding Sheet According to Shielding Materials Fusion and Resin Modifier Properties (차폐 재료의 융합과 개질제 특성에 따른 의료방사선 차폐 시트 물리적 특성 고찰)

  • Kim, Seon-Chil
    • Journal of the Korea Convergence Society
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    • v.9 no.12
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    • pp.99-106
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    • 2018
  • The modifier proposed in this research is for enhancing the affinity of the glass component with the high polymer resin and the molecular weight. The particle packing, tensile strength and shielding performance of the shielding sheet made of the tungsten oxide were evaluated. The best effect can be obtained when 20% of the modifier PMMA used to improve the shielding performance and maintain the affinity and strength with the sealant is mixed. The fusion of the materials presented in this study and the mass production of the shielding sheet through the modifier are possible and will contribute to the production of lightweight shielding sheets in the future.

Case series of implant-supported fixed prostheses using a high-performance polymer (PEKK) framework veneered with three different materials for six years (고기능성 폴리머(PEKK)를 프레임워크로 하는 임플란트 지지 고정성 보철물의 6년 경과관찰 증례)

  • Yeon-Kyung Park;Ji-Suk Shim;Jeong-Yol Lee
    • The Journal of Korean Academy of Prosthodontics
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    • v.62 no.1
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    • pp.20-27
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    • 2024
  • As a high-performance polymer, Polyetherketoneketone (PEKK) has good biocompatibility and excellent physical properties and is used in several areas, including dentistry. Many successful cases of implant-supported fixed prostheses with a PEKK framework have been reported; however, a long-term observation of the reported cases and discussion of complications are not available. In this case report, we present three cases of implant-supported fixed prostheses with a PEKK framework veneered with composite resin, lithium disilicate crown, and high-impact polymethyl methacrylate (PMMA), and discuss their 6-year follow-up results.