• Title/Summary/Keyword: PLASMA ETCHING

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The Effects of O2 Plasma Treatment on Electrical Properties of Graphene Grown by Chemical Vapor Deposition

  • Kim, Yun-Hyeong;Park, Jin-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.384.2-384.2
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    • 2014
  • We investigated the electrical and structural properties of chemical vapor deposition (CVD)-grown graphene and post treated by O2 plasma. For the patterning of graphene, the plasma technology is generally used and essential for etching of graphene. But, the cautious O2 plasma treatments are required to avoid the damage in graphene edge which can be the harmful effects on the device performance. To analyze the effects of plasma treatment on structural properties of graphene, the change of surface morphology of graphene are measured by scanning electron microscope and atomic force microscope before and after plasma treatment. In addition, the binding energy of carbon and oxygen are measured through to X-ray photoelectron spectroscopy. After plasma treatment, the severe changes of surface morphology and binding energy of carbon and oxygen were observed which effects on the change of sheet resistance. Finally, to analyze of graphene characteristics, we measured the Raman spectroscopy. The measured results showed that the plasma treatment makes the upward of D-peak and downward of G'-peak by elevated power of plasma.

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Design of inductively couple dplasma ashing chamber (유도 결합형 플라즈마를 이용한 감광제 제거 반응로의 설계)

  • 김철식;김철호;이현중;이용규;배경진;이종근;박세근
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.339-342
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    • 1998
  • Plasma etching of photoresist needs high etch rate, good uniformity and rae, good uniformity and low damage in low cost. ICP asher is expected to satisfy these requriement for next eneration semiconductor devices. ICPsimulator has been used to design the ashing chamber to redcue the development time and cost, and its results have been verified by QMS, OES and langmuir probe measurments. Plasma characteristics are monitored in terms of RF power and chamber pressure.

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The Field Emission Properties of Density Controlled Carbon Nanotubes

  • Lee, Tae-Young;Kim, Do-Yoon;Yoo, Ji-Beom;Park, Chong-Yun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.845-848
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    • 2003
  • We investigated a field emission property of CNTs grown on pre-treated substrates by $H_{2}$ plasma etching method in vacuum chamber (<${10^{-7}}$ Torr). To improve the emission characteristics, various catalysts and buffer layers were used. The morphology and density of catalyst layer was controlled by the different plasma pre-treatment conditions, resulting in the control of the growth characteristics of CNTs.

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The Silylation Photo Resist Process and the Enhanced-Inductively Coupled Plasma (E-ICP) (Silylation Photo resist 공정과 Enhanced-Inductively Coupled Plasma (E-ICP))

  • 정재성;박세근;오범환
    • Proceedings of the IEEK Conference
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    • 1999.06a
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    • pp.922-925
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    • 1999
  • The Silylation photo-resist etch process was tested by Enhanced-ICP dry etcher. The comparison of the two process results of micro pattern etching with 0.25${\mu}{\textrm}{m}$ CD by E-ICP and ICP reveals that E-ICP has better quality than ICP The etch rate and the microloading effect was improved in E-ICP Especially, the problem of the lateral etch was improved in E-ICP.

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Thickness control of MoS2 by using O2 plasma (산소 플라즈마를 이용한 2차원 소재 MoS2의 두께제어 기술 연구)

  • Kim, Seo-Hyeon;Qua, Deshun;Ra, Chang-Ho;Yu, Won-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.289-290
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    • 2014
  • Single layer $MoS_2$가 가지고 있는 전기적 특성, 광특성 등을 이용하기 위해 본 연구에서는 $O_2$ plasma를 이용해 경제적이며 효과적인 방법을 제시하고자 한다. 미세 etching을 통해 linear하게 thickness가 변화하는 것을 확인하고, pristine과 비슷하거나, 더 향상된 $MoS_2$를 제작하였다.

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Remote Plasma Etching of Photoresist Using Pin-To-Plate Dielectric Barrier Discharge

  • Park, Jae-Beom;Gyeong, Se-Jin;Yeom, Geun-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.82-83
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    • 2007
  • DBD type을 이용한 remote plasma에서 발생된 대기압 플라즈마를 이용하여, PR에 대한 식각 실험을 진행하였다. 과거 습식 화학적 공정에서 오던 기술적 제한의 극복과 진공 플라즈마 가지는 단점을 극복하기 위해 대기압 플라즈마를 이용한 건식 세정에 관한 연구를 진행하였고, 이 때 Gas는 $N_2/O_2$+$SF_6$ 의 조합으로 사용하였으며, 각 gas의 유량에 다른 remote 플라즈마의 전기적, 광학적 특성에 대해 관찰하였다.

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AFM and Specular Reflectance IR Studies on the Surface Structure of Poly(ethylene terephthalate) Films upon Treatment with Argon and Oxygen Plasmas

  • Seo, Eun-Deock
    • Macromolecular Research
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    • v.12 no.1
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    • pp.134-140
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    • 2004
  • Semi-crystalline poly(ethylene terephthalate) (PET) film surfaces were modified with argon and oxygen plasmas by radio-frequency (RF) glow discharge at 240 mTorr/40 W; the changes in topography and surface structure were investigated by atomic force microscopy (AFM) in conjunction with specular reflectance of infrared microspectroscopy (IMS). Under our operating conditions, analysis of the AFM images revealed that longer plasma treatment results in significant ablation on the film surface with increasing roughness, regardless of the kind of plasma used. The basic topographies, however, were different depending upon the kind of gas used. The specular reflectance analysis showed that the ablative mechanisms of the argon and oxygen plasma treatments are entirely different with one another. For the Ar-plasma-treated PET surface, no observable difference in the chemical structure was observed before and after plasma treatment. On the other hand, the oxygen-plasma-treated PET surface displays a significant decrease in the number of aliphatic C-H groups. We conclude that a constant removal of material from the PET surface occurs when using the Ar-plasma, whereas preferential etching of aliphatic C-H groups, with respect to, e.g. , carbonyl and ether groups, occurs upon oxygen plasma.

Actinometric Investigation of In-Situ Optical Emission Spectroscopy Data in SiO2 Plasma Etch

  • Kim, Boom-Soo;Hong, Sang-Jeen
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.3
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    • pp.139-143
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    • 2012
  • Optical emission spectroscopy (OES) is often used for real-time analysis of the plasma processes. OES has been suggested as a primary plasma process monitoring tool. It has the advantage of non-invasive in-situ monitoring capability but selecting the proper wavelengths for the analysis of OES data generally relies on empirically established methods. In this paper, we propose a practical method for the selection of OES wavelength peaks for the analysis of plasma etch process and this is done by investigating reactants and by-product gas species that reside in the plasma etch chamber. Wavelength selection criteria are based on the standard deviation and correlation coefficients. Moreover, chemical actinometry is employed for the normalization of the selected wavelengths. We also present the importance of chemical actinometry of OES data for quantitative analysis of plasma. Then, the suggested OES peak selection method is employed.. This method is used to find out the reason behind abnormal etching of PR erosion during a series of $SiO_2$ etch processes using the same recipe. From the experimental verification, we convinced that OES is not only capable for real-time detection of abnormal plasma process but it is also useful for the analysis of suspicious plasma behavior.