• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.121.2-121.2
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• 2016

PFA 라이닝 밸브 (PFA Lined Valve)는 고온 (~120oC) 고압 (~10 bar)에서 강한 부식성을 갖은 화학물질 (염산, 황산, 질산 등)을 이송시킬 수 있도록 내식성, 비점착성, 내열성 향상을 위한 불소계 수지 PFA (Perfluoroalkoxy)가 밸브 내면부에 가공되어 있으며, 고순도 화학약품 및 반도체 LCD 석유화학 제철 제약 분야 등의 제조공정에서 사용되고 있다. 미국 EPA (Environmental Protection Agency)에서는 석유화학 플랜트에서 발생되는 비산배출 (fugitive emission)의 대부분인 60% 정도가 밸브에서 발생된다고 보고하고 있으며, 근래 빈번한 불산 노출사고 내용을 매스컴에서 접할 수 있는 것처럼 PFA 라이닝 밸브가 설치되는 산업현장에서는 미소 누설에도 치명적인 인명피해 사고가 발생하기 때문에 국제규격에 따른 PFA 라이닝 밸브의 기밀누설에 관한 규제 및 관리가 중요하다. 본 논문에서는 가압진공법을 이용하여 PFA 라이닝 볼밸브의 비산배출 측정하였으며, 작동횟수/온도변화에 따른 PFA 라이닝 볼밸브의 비산배출 특성을 고찰하였다.

• Analytical Science and Technology
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• v.14 no.1
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• pp.21-27
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• 2001

In this work, analytical performance of a laboratory built double membrane desolvator (DMD) was studies using perfluoroalkoxy (PFA) nebulizer and microconcentirc nebulizer (MCN) in inductively coupled plasma atomic emission spectrometry. Compared with MCN, PFA nebulizer coupled to DMD showed similar analytical sensitivity for aqueous solution and better sensitivity for isopropyl alcohol. Since PFA resisted various acids, HCI, $H_2SO_4$ and HF solution were analyzed with less than 2% RSD. Rinse-out time for the signal reduction to 1% was obtained to be 35 s for PFA but about 45 s for MCN.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.10a
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• pp.561-568
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• 2002

PFA(Paper Fly Ash) are reclaimed mainly or used in cement industry field as mixture agent in terms of materials recycling. Recently, research for recycling PFA as embankment materials or soil stabilization agent are undergoing in geotechnical engineering field. In this study, physical characteristics of PFA stabilization agent-soil admixtures are examined in change of water content, void ratio, consistency, grain distribution, specific gravity and density. Futhermore, the physical characteristics are compared with unconfined strength as engineering characteristics. Test results showed that unconfined strength and density are increased with increasing of PFA stabilization agent mixed ratio. On the other hand, specific gravity, void ratio and water content are decreased with increasing of PFA stabilization agent mixed ratio. It would be concluded that natural high water content ratio weak soil could be highly improved engineering and physical characteristics with PFA stabilization agent

• The KSFM Journal of Fluid Machinery
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• v.19 no.4
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• pp.39-42
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• 2016

A PFA lined ball valve, which is machined with fluorinated resin PFA to its inner part for improving corrosion resistance, non-stickness, heat-resistance, has been widely used to the chemical/pharmaceutical industries, the semiconductor/LCD manufacturing processes, etc. with the high purity chemicals as working fluid. EPA stated that 60% of all fugitive emissions come from the valve stem packing in a typical petroleum or chemical processing plant. They monitor regulated components for leaks and maintain seal performance at acceptable levels. Korean industrial standards only deals with the bubble test for in-line leakage of valves, which has the detectable leak rate of $10^{-4}$ [$mbar{\cdot}L{\cdot}s^{-1}$], therefore, it is not sufficient to check fugitive emissions. In this study, we conducted Helium leak detection from a PFA lined ball valve and evaluated fugitive emissions according to ISO 15848-1, which has the detectable leak rate of $10^{-9}$ [$mbar{\cdot}L{\cdot}s^{-1}$], for manufacturing the high-reliable PFA lined ball valves against fugitive emissions.

• Magazine of the Korea Concrete Institute
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• v.7 no.1
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• pp.126-135
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• 1995

The strength development of PFA concretes were invest~gated in this study. The work undertaken was divided into two parts which considered both the influence of PFA replacement level up to 45% and the effect of cement type at the high PRA leveI(45%). The additiorlal cement considered included a rapdhardemng portland ccnlent. The full range of concrete struc tural grades were studied anti ciight cu~ing contlltiorls covering those 11:ied 111 practlce were examined. The early strength retluced wit11 increasing PFA content. However, post 28days, the reverse was observed. It was posslhle through the use of rapid hardening portland cement at the high PFA level to achieve similar early strength to OPC concrete, with the same benefits noted above also being obtained post 28 days. The compressive strength uf hlgh PYA content concrt:tes at hgh temperature m s found to be higher than the ccmtrol at all ages hoth in water and alr. The same trends were observed at low t.ernperature in air. However, the reverse occur-ed at the low temperature In water.

• Journal of the Korean Electrochemical Society
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• v.12 no.2
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• pp.173-180
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• 2009

In order to develop a novel polymer electrolyte membrane for direct methanol fuel cell (DMFC), styrene monomer was graft-polymerized into poly(tetrafluoroethylene perfluoropropyl vinyl ether) (PFA) film followed by a sulfonation reaction. The graft polymerization was prepared by the $\Upsilon$-ray radiation-grafting method. Subsequently, sulfonation of the radiation-grafted film was carried out in a chlorosulfonic acid/1,2-dichloroethane (2 v/v%) solution. The chemical, physical, electrochemical and morphological properties of the radiation-grafted membranes (PFA-g-PSSA) were characterized by fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The water uptake, ionic conductivity, and methanol permeability of the PFA-g-PSSA membrane were also measured. The cell performances of MEA prepared with the PFA-g-PSSA membranes were evaluated and the cell resistances were measured by an impedance analyzer. The MEA using PFA-g-PSSA membranes showed superior performance for DMFCs in comparison with the commercial Nafion 112 membrane.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.32 no.1
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• pp.85-93
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• 2009

In this paper, the geometric design for the body of a 3"-PFA-lined plug valve is concerned, and body model which has less deformed PFA-resin after infection molding process is proposed. A CAE software is used to simulate the deformation due to heat in cooling. To reduce the deformation, some small shapes are added to PFA-resin surfaces related on wall of the valve housing. And thermal stress simulation with FEM methodology is followed after that. Also, the 3D-CAD package is used during the design processes. In this study, I tried to present the possibility to use the FEM analysis in the solid modeling process. So, the design engineer will be able to use analysis package effectively on his job within the limited range.

• Journal of Radiation Industry
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• v.6 no.4
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• pp.323-328
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• 2012

In this study, a facile method to fabricate superhydrophobic surfaces on perfluoroalkoxy (PFA) films using ion implantation was developed. PFA films were implanted at 100 keV with a fluence ranging from $4{\times}10^{16}$ to $7{\times}10^{16}ions\;cm^{-2}$. The surface properties of the implanted films were investigated in terms of their surface morphology, wettability, and chemical composition. As the fluence increased to $6{\times}10^{16}ions\;cm^{-2}$, the surface morphology and surface roughness of the PFA films were dramatically changed. The PFA surface implanted at a fluence of $6{\times}10^{16}ions\;cm^{-2}$ showed a maximum contact angle (CA) of $157.1^{\circ}$, while the control CA of the smooth PFA surface was $103.6^{\circ}$. Thus, the superhydrophobic surface was successfully fabricated by ion implantation.

• The KSFM Journal of Fluid Machinery
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• v.19 no.4
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• pp.35-38
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• 2016

A PFA lined ball valve, which is machined with fluorinated resin PFA to its inner part for improving corrosion resistance, non-stickness, heat-resistance, has been widely used in semiconductor/LCD manufacturing processes with the high purity chemicals as working fluid. Due to the safety concerns, the experiments for measuring the flow coefficient of a PFA lined ball valve should be conducted with water at room temperature according to IEC standards. However, it is required to know the real flow coefficient with the real working fluid, because the flow coefficient is critical to correctly design valves in piping system. In this study, we calculated the flow coefficient of a PFA lined ball valve 40A with hydrochloric acid ($40^{\circ}C$ 36% HCl) as the working fluid using a commercial CFD package, ANSYS CFX v15. The computational results had a good agreement with the measured data and showed a little difference between water and hydrochloric acid as the working fluid of a PFA lined ball valve.

• The KSFM Journal of Fluid Machinery
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• v.17 no.4
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• pp.76-80
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• 2014

PFA fluoropolymer lined technology revolutionized ball valve development and design decades ago and continues to be pivotal for many products and valve solutions in diverse industries and applications, such as chemical process, semiconductor/LCD manufacturing processes, pharmaceutical and others. Because of the extreme operating conditions such as high-temperature (${\sim}120^{\circ}C$) and high-pressure (~10 bar), the reliability of the valve is very important for minimizing in-line leakage and fugitive emissions of strong corrosive chemicals (hydrochloric acid, hydrofluoric acid, nitric acid, etc.) transported through the lines. In this study, we investigated the flow characteristics with flow coefficient in a PFA lined ball valve for different opening degrees using CFD analyses. The results should be the guidance for a new PFA lined ball valve design that will incorporate all the acclaimed and demonstrated benefits of the current design approaches.