• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.107-110
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• 2001

폴리에틸렌 나프탈레이트(PEN)는 PET의 벤젠 고리 대신에 나프탈렌 고리로 치환 되어 있어 주사슬의 강직성으로 유리전이 온도와 용융 온도가 높고 기계적 물성이 뛰어나며 열수축이 적고 헝태 안정성이 우수하다고 알려져 있다[1]. 그러나 PEN의 원료 물질이 비싸기 때문에 블렌드를 이용해 PEN의 장점을 보다 폭넓게 활용하기 위한 연구가 활발히 진행되고 있다[2-3]. 한편 폴리에틸렌 테레프탈레이트(PET)는 섬유용 및 각종 산업용 소재로 가장 널리 이용되고 있는 고분자 중의 하나이다. (중략)

• Polymer(Korea)
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• v.35 no.3
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• pp.249-253
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• 2011

The effect of morphological development in PET/PEN blending on the physical properties of PET/PEN blend film as a flexible substrate was investigated. The two phase morphology was obtained in PET/PEN blends and it caused the improvement of dimensional stability of PET/PEN blend as a flexible substrate. The two phase morphology and crystallinity of PET/PEN blends could be controlled by the transesterification between PET and PEN during the film processing and this macroscopic structural development affected the dimensional stability of PET/PEN blend films. Better dimensional stability was obtained with increasing crystallinity and decreasing the level of transesterification.

• Biomedical Science Letters
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• v.15 no.3
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• pp.199-205
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• 2009

This study was designed to investigate direct effects of [D-$Pen^2$, D-$Pen^5$]-enkephalin, a $\delta$-opioid receptor agonist on the neuronal activity of medial vestibular nuclear (MVN) neurons by whole-cell configuration patch clamp experiments. The spike frequency of MVN neuron was increased to $9.50{\pm}0.55$ (P<0.05) and $10.56{\pm}0.66$ (P<0.05) by 5 and $10{\mu}M$ [D-$Pen^2$, D-$Pen^5$]-enkephalin from the control level of $8.05{\pm}0.55$ spikes/sec, respectively (n=18). The resting membrane potential of the neurons was increased to $-37.86{\pm}0.92$ and $-36.97{\pm}0.97$ (P<0.05) from $-38.74{\pm}1.13\;mV$ by 5 and $10{\mu}M$ [D-$Pen^2$, D-$Pen^5$]-enkephalin, respectively. The amplitude of afterhyperpolarization was decreased to $23.78{\pm}0.65$ and $21.67{\pm}0.89$ (P<0.05) from $23.73{\pm}0.53\;mV$ by 5 and $10{\mu}M$ [D-$Pen^2$, D-$Pen^5$]-enkephalin, respectively. The spike width was changed to $2.22{\pm}0.08$ and $2.24{\pm}0.07$ from $2.20{\pm}0.08\;mV$ by 5 and $10{\mu}M$ [D-$Pen^2$, D-$Pen^5$]-enkephalin, respectively. After pretreatment of naltrindole, a highly selective 8-opioid receptor antagonist, [D-$Pen^2$, D-$Pen^5$]-enkephalin did not change firing rate, resting membrane potential, afterhyperpolarization amplitude, and spike width of MVN neurons. The above experimental results suggest that [D-$Pen^2$, D-$Pen^5$]-enkephalin increases the neuronal activity of MVN neurons via inhibition of calcium-dependent potassium currents underlying the afterhyperpolarization.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.21 no.8
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• pp.113-120
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• 2007

This paper presents the electric shock hazards and solutions of loss of the combined protective and neutral (PEN) conductor in TN-C-S system. In order to mitigate the touch voltage on exposed-conductive-parts in a break in the PEN conductor, the touch voltages on exposed-conductive-parts in a break in the PEN conductor were experimentally investigated as a function of the ground resistances of the source grounding electrode and customer's additional grounding electrode. As a result, the equipotential bonding is one of important requirements for installations supplied by TN-C-S system. A solution of mitigating the touch voltages on exposed-conductor-parts caused by a loss of the PEN conductor would be the installation of the additional grounding electrode at the customer's service entrance. The ground resistance of additional grounding electrode necessary to limit the touch voltage to a safety voltage of less than 50[V] depends on the load and circuit parameters. In addition, the undervoltage sensing devices oner affordable solutions to detect a loss of the PEN conductor in TN-C-S system.

• Polymer(Korea)
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• v.30 no.1
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• pp.22-27
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• 2006

The effect of transesterification on the rheological property of poly(ethylene naphthalate)/poly(butylene tore-phthalate) (PEN/PBT) blends has been investigated. The melt viscosity of PEN/PBT blends decreased with increasing PBT content due to the relatively low melt viscosity of PBT as well as introducing ransesterification between PEN and PBT Further melt viscosity decrease was achieved by the thermal annealing which caused both the chain scission and the acceleration of transesterfication. Calcium stearate (CaST) was applied as a lubricant in order to lower the melt viscosity of PEN and it was found that CaST was acting as the catalyst of transesterification as well. In general, reactive melt blending of PEN and PBT by transesterification resulted in the decrease of molecular weight of PEN and PBT, as a result, the loss of mechanical properties in PEN/PET blend was inevitable.

• Polymer(Korea)
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• v.29 no.5
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• pp.475-480
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• 2005

The lowering of melt viscosity has been investigated to achieve the processability enhancement in poly(ethylene naphthalate) (PEN) melt processing by the reactive melt blending with poly(ethylene terephthalate) (PET) and introducing lubricant as well. CaST lubricant resulted in the lowering of PEN melt viscosity but noticeable mechanical property drop was found in PEN with more than $2wt\%$ of lubricant due to the acceleration of thermal degradation by excess lubricant. PEN/PET (90/10) blend has less melt viscosity than PEN and transesterification between two polymers caused the additional viscosity depression. further viscosity lowering was found in PEN/PET blend with CaST since CaST is acting as the catalyst of transesterification as well as a lubricant in PEN/PET blend.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.377-380
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• 2002

PET는 합성섬유를 비롯한 필름 및 각종 공업용 소재에 이르기까지 매우 광범위한 용도를 가지는 대표적인 범용 고분자의 하나이다. 그러나 최근 고성능 재료에 대한 관심의 증가로 PET를 개질하여 그 용도를 넓히려는 연구[1-2]가 많이 진행되고 있지만 PET 자체의 한계로 인해 실제 응용 면에서 어려운 점들이 야기되고 있다. 특히 PET 보다 열안정성, 형태안정성 및 기계적특성이 우수한 PEN을 이용하여 PET와 용융 블렌딩함으로써 PEN의 장점을 보다 폭넓게 활용하는 동시에 PET의 이러한 단점을 개선하려는 연구 [3-4]들이 일부 보고되고 있지만 고점도 PEN을 이용한 PEN/PET용융 블렌드 필라멘트의 제조와 물성에 대한 연구는 미흡한 실정이다. (중략)

• Journal of Korean Society of Industrial and Systems Engineering
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• v.21 no.45
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• pp.357-364
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• 1998

This study deals with the performance evaluation of writing for designing handwriting instruments ergonomically. Experimental tests were executed on ballpoint pen., felt-tip pen, pencil, sharp-pencil, and fountain pen for ease of use and reduction of the muscles fatigue. The writing time and the degree of comfort of writing by subjects were measured on the diameters of five writing instruments. The results indicated that the ballpoint pen was rated significantly superior to the others in writing speed attribute and the instrument with the least fatigue was the fountain pen. There was a significant interaction effect between the types of instruments and their size in diameters. The diameter of instruments for considering time and comfort together was verified that the size of 9.5mm was efficient for ballpoint pen, the size of 8.1mm for felt-tip pen, the size of 7.5mm for pencil, the size of 8.2mm for sharp-pencil, and the size of 9.1mm for fountain pen.

• Polymer(Korea)
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• v.24 no.5
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• pp.664-672
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• 2000

It is generally agreed that transesterification provides the, copolymer in the melt blending of poly(ethylene naphthalate) (PEN) and poly($\varepsilon$-caprolactone) (PCL). Effects of the conditions of transesterification reaction and catalyst on the degree of randomness and average sequence length of PEN/PCL blends were investigated and results were used to interpret the biodegradability of PEN/PCL blends. It was found that degree of randomness values of obtained copolymer lied between 0 and 1, and it indicated that this blend consisted with physical blends of PEN/PCL and PEN/PCL block copolymers. The degree of randomness reached almost 1 which is the theoretical value of random copolymers and the average sequence length became shorter by the further transesterification reaction. In additions, it was found that the increase of copolymers, especially random copolymers reduced the biodegradability in PEN/PCL blends.

• Polymer(Korea)
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• v.37 no.6
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• pp.711-716
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• 2013

The effect of chain orientation and relaxation on the characteristics of poly(ethylene naphthalate) (PEN) flexible substrate has been studied. It was found that the coefficient of thermal expansion (CTE) of PEN under $100^{\circ}C$ decreased as low as $20ppm/^{\circ}C$ due to the lowering of chain mobility by chain orientation. The thermal shrinkage was found to appear near glass transition temperature because of chain relaxation. It could be minimized by thermal annealing but CTE increased again up to $70ppm/^{\circ}C$ which was 65% of intrinsic CTE of PEN. Unstrained thermal annealing made possible to avoid the thermal shrinkage with maintaining low CTE obtained by chain orientation. Chain orientation did not affect the optical transmittance; however, thermal annealing caused the decrease of optical transmittance up to 5%. This was understood by the minor crystallization due to the thermal annealing near glass transition temperature.