• Title/Summary/Keyword: PC 폴리머

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Improving the Wettability of Polymeric Surfaces and Surface Modification of Ceramic by Ion Beam in Reactive gases Environments (반응성 가스 분위기하에서 이온빔을 이용한 폴리머 표면의 친수성 증대 및 세라믹표 면개질)

  • 손용배
    • Journal of the Microelectronics and Packaging Society
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    • v.3 no.1
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    • pp.11-24
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    • 1996
  • 부분압이 다른 여러 가지 반응성 가스분위기하에서 이른곤 이온을 이용하여 PC, PET PMMA 그리고 PTFE 폴리머 표면의 삼차 증류수에대한 진수성을 증대하였다. 폴리머 표면의 친수성의 변화는 여러 가지 반응성 가스 분위기하에서 아르곤 이온의 조사량을 1014 부터 1x1017cm2까지 변화하면서 조사하였다. 접촉감은 아르곤 이온이 조사되는 폴리머 표면 근처에 유입된 가스의 방응성(O2>N2>H2)에 따라 많이 감소하였다, 폴리머 표면에 형성된 친수성기는 XPS Cls, Ols, 그리고 Nls 스펙트럼을 분석하여 확인하였다. 표면 개질된 PC와 PTFE에 대한 Al 금속의 접착력 증대를 Scotch tape와 인장실험을 통하여 확인하였다. 접착 력 증가는 표면 에너지 중 polar force의 증가에 의한 것으로 입증되었다. 에너지를 가진 아 르곤 입자 폴리머 체인 그리고 반응성 가스 사이의 반응기구는 2단계 모델로 설명가능하였 는데 그 기구는 첫 번째 이온의 조사에 의한 불안정한 폴리머 체인의 형성과 두 번째 단계 로 이렇게 형성된 폴리머 체인과 반응성 가스들 사이의 화학반응으로 이루어진다. 질화아루 미늄의 표면을 산소분위기하에서 아르곤 빔을 조사하여 표면개질한후 AlON층이 새롭게 형 성된 것을 XPS를 이용하여 확인할수 있었다. 개질된 질화알루미늄과 구리금속 박막간의 접 착력을 scratch 실험을 통하여 조사하였다.

Minimization of Pattern Size on Polycarbonate Material in V-grooving (PC 폴리머 재료의 미세 V-홈 절삭가공 시 패턴 크기 최소화)

  • Kim, Gi-Dae
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.5
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    • pp.523-527
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    • 2011
  • Polycarbonate (PC) polymer is an engineering plastic which has large tensile strength and impact resistance and is wildly used as functional parts like micro mold. Direct machining of PC materials produces lots of burrs and rough surface due to large ductility and weak heat resistance and hence it is very difficult to machine PC materials using cutting tool to make micro-parts. In this study, elliptical vibration cutting (EVC) or 2-dimensional vibration cutting was performed to minimize the size of micro V-grooves on PC material. From the experimental results, it was observed that as the cutting depth and pattern size become smaller, the better machining quality was obtained, which is attributed to the positive effect of EVC that is dependent on the ratio of vibration amplitude to cutting depth. As the height of V-groove becomes less than $1.8{\mu}m$, however, the machining quality becomes lower as the pattern size decreases.

Surface Characteristics of Functional Polymer Film by Ion Beam Irradiation (이온빔 조사에 의한 기능성 고분자 필름의 표면 특성)

  • Kim, Young Jun;Hong, Seong Min;Noh, Yong Oh
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.431-436
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    • 2013
  • Polycarbonate (PC) films have been irradiated with various kinds of ions according to energy and dose. Change of the optical transmittance and chemical characteristics were confirmed by UV-VIS and FTIR (ATR) spectroscopy respectively. These UV-A block in 400 nm was variable from 10 to 100% according to energy and doses. Surface electrical resistance of PC film irradiated by ion beam was $10^6-10^{13}{\Omega}/cm^2$, which reveal variation of conduction. Contact angle of film irradiated by ion beam was decreased than the pristine film. Polymer surface morphology was examined by means of atomic force microscopy (AFM). As expected, degradation of polymer film was higher after irradiation with heavier Xe ions but the roughness in the polymer surface morphology were more pronounced for Ar ions. This observed effect can be explained by stronger compaction of polymer surface layer in the case of Xe irradiation, connected with a reduction of free volume available.

Strength Characteristics on Sulfuric Acid Corrosion of Recycled PET Polymer Concrete with Different Fillers (충전재 종류에 따른 PET재활용 폴리머콘크리트의 황산부식에 대한 강도 특성)

  • Jo Byung-Wan;Shin Kyung-Chul;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.499-504
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    • 2005
  • Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete Is drawing a strong interest as high-performance materials in the construction industry Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems Posed by plastics and save energy. An objective of this paper is to estimate the damage of sulfuric acid, through investigating recycled PET polymer concrete, immersed at sulfuric acid solution for 84 days. As a result of testing, recycled PET PC, used $CaCO_3$ as filler, makes a problem of appearance and strength if they are exposed for long term at corrosion environment. On the other hand, recycled PET PC, used fly-ash as filler, had less effect on decrease in weight and strength. Recycled PET PC is excellent chemical resistance, resulting in the role of unsaturated polyester resin which consists of polymer chain structure accomplishes bond of aggregates and filler strongly. Also, recycled PET PC, used fly-ash as filler, is stronger resistance of sulfuric acid corrosion than $CaCO_3$, because it is composed of $SiO_2$ and very strong glassy crystal structure. Therefore, recycled PET PC, used fly-ash as filler, is available under corrosion circumstances like sewer pipe or waste disposal plant.

Mechanical and Durability Properties of Partial-Depth Patch Materials using Polymer Materials for Concrete Pavement (단면보수용 콘크리트 패치재료의 역학적 특성 및 내구성 실험)

  • Yang, Sung-Chul;Hwang, In-Dong;Han, Seong-Hwan;Kim, Seong-Min
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.23-32
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    • 2009
  • In this paper an experimental program was launched to determine the mechanical and durability properties of spall repair materials (RCC: 3 items, PCC: 2 items, PC: 3 items). Test items were mechanical property tests such as setting times, strengths, modulus of elasticity, plastic shrinkage, and durability tests such as dynamic modulus ratio, bond property with freeze-thaw, water absorption, chemical resistance, ultraviolet exposure. Modulus of the PC products exhibits ductile while the modulus is in the order of RCC > PCC > PC. At early ages the PC products experience higher plastic shrinkage than others, henceforth stable at 28 days. Other test results such as dynamic modulus ratio, absorption, and chemical resistance show that the PCs are superior to the PCCs and the RCCs. Except for PC-2, all patch materials had bond strength more than 1.3MPa after freeze-thaw cycles of 200~300 while the PCs and the PCCs seem to be better than the RCCs. With 500 hours of ultraviolet exposure, all patch materials showed to have no crack or deterioration at the surface.

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A Study on Characteristics of Flexural Behavior of High-strength Polymer Concrete Beams Using Recycled PET (PET 재활용 고강도 폴리머 콘크리트보의 휨거동에 관한 연구)

  • Cho Byung-Wan;Park Jong-Hwa;Park Seung-Kook;Bea Sung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.483-486
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    • 2005
  • The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. Polymer concrete beams using unsaturated polyester resins based on recycled polyethylene terephthalate (PET) plastic waste were used in our study for grasping its structural behavior of static and fatigue. As a result of static test, Compression stress distribution of Polymer concrete indicates linear behavior such as triangles. Although polymer concrete is high strength materials, its ductility capacity is excellent. From the fatigue test results, There was almost no difference on flexural characteristics between before and after fatigue loading. Therefore, recycled PET polymer concrete remains excellent structural ability after fatigue loading.

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Waterproofing technology for PC double arch tunnel using synthetic rubber polymer gel and cooper sheet for root barrier (합성고무 폴리머 겔과 구리 방근시트를 이용한 P.C 쌍아치 터널 구조물 방수기술)

  • Lee, Jong-Yong;Park, Sang-Tai;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.44-45
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    • 2020
  • The purpose of this study was to contemplate the effectual waterproofing materials and construction methods for the restoration of underground infrastructures using precast arches(PC-Arch). Until now, there were no proper waterproofing guidelines for waterproofing precast arch tunnel when restoring cultural heritage or building underground infrastructures for noise control. Asphalt membrane sheets were commonly used, but the efficacy of waterproofing done on the precast segment was vulnerable. This study aims to examine the Synthetic Rubber Polymerised Gel(SRPG) proposed in ISO TR 16475, a guideline for the repair of water-leakages, and to demonstrate field applicability based on the waterproofing solution used on the road improvement project in front of Changgyeonggung Palace in Yulgok-ro, Seoul, Republic of Korea.

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Analysis of Research Trends on Concrete-Polymer Composite (콘크리트-폴리머 복합체에 관한 연구동향 분석)

  • 연규석;김광우;김관호;박순무
    • Proceedings of the Korea Concrete Institute Conference
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    • 1992.10a
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    • pp.63-69
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    • 1992
  • Research trends of concrete-polymer composite were analyzed based on 549 papers that were presented at international Congresses on Polymer in Concrete that have been opened seven times all around world since 1975. The analysis revealed that relative quantities of the papers about PC, PCC, PIC and others were 51%, 24%, 13% and 12%, in the order. Basic research was the main stream for PCC, PC, PIC. In PC study, however, it was shown that many researches were actively performed for application of PC.

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The Fabrication an dCharacteristic Analysis with Novel High Efficiency Organic Polymer Green Electroluminescence (새로운 고효울 유기 폴리머 녹색발광소자의 제작 및 특성 분석)

  • Oh, Hwan-Sool
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.12
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    • pp.1-7
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    • 2001
  • Single-layer polymer green electroluminescent devices were fabricated with novel material synthesis by using moleculely-dispersed TTA and NIDI into the polymer PC(B79) emitter layer doped with C6 fluorescent dye which has low operating voltage and high quantum efficiency. A EL cell structure of glass substrate/indium-tin-oxide/PC:TTA:NIDI:C6/Ca/Al was employed and compared with various low work function cathode electrodes Ca and Mg metals. By adjusting the concentration of the fluorescent dye C6, low turn-on voltage of 2.4V was obtained, maximum quantum efficiency of 0.52% at 0.08mole% has been improved by about a factor of ~50 times in comparison with the undoped cell. The PL and EL colors can't be turned by changing the concentration of the C6 dopant. PL emission peaking was obtained at 495nm and EL emission peaking at 520nm with FWHM ~70nm

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