• 제목/요약/키워드: PBN

검색결과 63건 처리시간 0.027초

형광광도법을 이용한 오존 passive sampler의 개발 (Development of ozone passive sampler with fluorescence intensity method)

  • 김한수;김선태;윤은영;김신도
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2001년도 추계학술대회 논문집
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    • pp.245-246
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    • 2001
  • 우리나라에서는 지금까지 대기 오염과 관련하여 환경기준 달성을 위한 정책수립에 있어서 대상물질은 주로 이산화황(SO$_2$)과 먼지(TSP) 등으로 경제개발과 산업발전과정 등에서 발생되는 오염물질이었다. 그러나 최근 몇 년사이 급격한 자동차의 증가로 인한 이산화질소(NO$_2$)와 휘발성유기화합물(VOCs)의 배출이 증가하고 있어 환경규제정책도 점차 변하고 있는 실정이다. 이러한 오염물질들이 대기중에서 태양복사에너지에 의해 광화학 반응을 일으켜 오존(ozone), PAN(peroxyacethyl nitrate), PBN(peroxy benzoyl nitrate), 아크로레인(carolein), 포름알데히드(HCHO, formaldehyde) 등 광화학 산화제를 생성하여 인체, 동ㆍ식물 및 재산상의 피해를 유발하고 있다. (중략)

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NR 및 SBR의 노화방지제(老化防止劑) 병용효과(倂用效果)에 의(依)한 가황특성(加黃特性) 연구(硏究) (A study on the vulcaniz러on characteristic of combined antioxidants in NR and SBR compounds)

  • 최재원;이기종
    • Elastomers and Composites
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    • 제17권2호
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    • pp.77-90
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    • 1982
  • The purpose of this study is to get comparative results on the combined antioxidant systems comprised of MHPPD with IPPD, MHPPD with PBN and MHIPPD with MB when they are individually added to NR and SBR compound. Vulcanization characterstics and physical properties of the combined antioxidants have been studied by means of the Mooney viscometer, the Monsanto disc rheometer and so on. According to the test results, MHPPD with IPPD system has shown faster cure rate, better optimum cure time and shorter scorch time than other systems. The vulcanizate comprised of the MHPPD with IPPD antioxidant system has taken advantage of heat resistance, fluid resistance and antiozone resistance.

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Gate-to-Gate with Modernized GPS, GALILEO and GBAS

  • Schuster, Wolfgang;Ochieng, Washington
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2006년도 International Symposium on GPS/GNSS Vol.1
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    • pp.3-8
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    • 2006
  • This paper discusses current challenges, as a result of the rapid increase in air travel, and future navigation needs of Civil Aviation. The objectives pursued by ANASTASIA, a sixth framework European Commission project, are presented. The methods used in the derivation of the navigation performance requirements are introduced and discussed in the context of precision approaches. High-level impacts on the avionics receiver of integrating additional multi-frequency ranging signals from a modernized GPS and Galileo into the current navigation architecture are investigated. Expected performance achievements are presented.

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항공 AIDC를 응용한 VTS 관제센터간 선박관제권 이양절차 도입

  • 유재만;정경화
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2013년도 춘계학술대회
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    • pp.368-370
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    • 2013
  • 현재 전 세계 체약국들은 증가하는 항공수요를 충족하고 공역의 이용 효율성 및 항공기 운항의 경제성 등을 제고하기 위해 국제민간항공기구(ICAO)에서 전략적으로 개발하고 채택한 차세대항법시스템(New CNS/ATM, PBN 등)의 각종 항법 및 통신 어플리케이션 등을 도입 적용하고 있다. 이 가운데 AIDC(ATS inter-facility Data Communication)는 조종사와 관제사간 반복적으로 이루어지는 교신(Verbal Communication)사항을 포맷화한 후 데이터로 송출하여 조종사와 관제사 양측 모두의 업무로드를 감소시키며 주파수 점유 시간을 단축시켜 주파수 활용도를 크게 증가시키고 있다. 또한, 비영어권 국가와의 음성 통신시 부정확한 발음 등으로 야기 될 수 있는 인적요인(Human Factor)을 사전 제거하는 등 많은 혜택(Benefits)을 제공하고 있다. 비록 이번 연구에서 항공 AIDC의 모든 요소가 VTS에 1:1 적용 되지는 않지만 AIDC의 주요 요소(TOC, AOC 등)와 우리 해상교통 실정에 맞는 응용 요소(RTOC)를 추가하여 주파수와 관제센터는 다르지만 관제구역이 서로 인접해 있는 구역에 적용시켜 잠재적 위험요소를 사전에 예방하고, 궁극적으로 Service provider로서 이용자 중심의 VTS를 설계하고자 한다.

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GNSS 대안항법시스템 요구사항 및 기술 분석 (Alternative PNT Requirements and Technology Analysis)

  • 조상훈;강승은;강자영;고상호
    • 한국항공운항학회지
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    • 제20권3호
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    • pp.28-34
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    • 2012
  • The recent transition to Performance Based Navigation in aviation enhances the accuracy of aircraft position, safety and efficiency in air traffic operations by using satellite-based navigation system such as GNSS. However, intentional interferences with GNSS signal as well as ones coming from natural phenomena such as solar storm increase. GNSS have very low power and therefore their signals are more susceptible to interferences than ground-based navigation signals. This paper introduces requirements of alternative positioning, navigation and timing(APNT) system and relevant technologies when the GNSS signals are not valid.

Effect of Process Parameters of UV Enhanced Gas Phase Cleaning on the Removal of PMMA (Polymethylmethacrylate) from a Si Substrate

  • Kwon, Sung Ku;Kim, Do Hyun
    • Transactions on Electrical and Electronic Materials
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    • 제17권4호
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    • pp.204-207
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    • 2016
  • Experimental study of UV-irradiated O2/H2 gas phase cleaning for PMMA (Polymethylmethacrylate) removal is carried out in a load-locked reactor equipped with a UV lamp and PBN heater. UV enhanced O2/H2 gas phase cleaning removes polymethylmethacrylate (PMMA) better at lower process pressure with higher content of H2. O2 gas compete for UV (184.9 nm) absorption with PMMA producing O3, O(1D) and lower dissociation of PMMA. In our experimental conditions, etching reaction of PMMA at the substrate temperature between 75℃ and 125℃ had activation energy of about 5.86 kcal/mol indicating etching was controlled by surface reaction. Above the 180℃, PMMA removal was governed by a supply of reaction gas rather than by substrate temperature.

타이어 기본강성 설계에 따른 타이어 라벨링 성능변화 연구 (A Study on Tire Labeling Performance for Tire Stiffness Design)

  • 강영규;김건호;장인성;오약전
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2013년도 추계학술대회 논문집
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    • pp.265-267
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    • 2013
  • Tire labeling is an important issue to reduce $CO_2$ and to secure the safety of tire/vehicle on wet road. A basic study on the effects of tire basic stiffness design on tire labeling performance has been done through experimental test. The pass-by noise is affected by tire structural design. The tire with lower side part stiffness and lower tread part stiffness has the lowest PBN level and the best wet grip. And the tire with higher tread part stiffness and higher side part stiffness has the better RR performance. Also it is observed that the trade-off between RR and wet grip exists for various tire stiffness design.

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Schiff Base Co(II) 착물이 변성된 유리질 탄소전극에서 산소 환원의 전기촉매 효과 (Electrocatalytic Effect of Dioxygen Reduction at Glassy Carbon Electrode Modified with Schiff Base Co(II) Complexes)

  • 성정섭;채희남;최용국
    • 분석과학
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    • 제11권6호
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    • pp.460-468
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    • 1998
  • $SOPDH_2$, $SNDH_2$, $EBNH_2$, $PBNH_2$ Schiff base 리간드와 이들의 [$Co(II)(SND)(H_2O)_2$], [$Co(II)(SOPD)(H_2O)_2$], [$Co(II)(EBN)(H_2O)$], [$Co(II)(PBN)(H_2O)$] 착물들을 합성하였다. Co(II) 착물들에서 Schiff base 리간드와 Co(II)의 몰 결합 비는 1:1로 주어졌으며 6배위 결합을 합성하였다. Co(II) 착물이 수식된 유리질 탄소전극을 사용하여 1 M KOH 수용액에서 산소 환원 반응을 순환 전압전류법으로 알아보았다. Schiff base Co(II) 착물이 수식된 전극에서의 산소의 환원 전류는 알몸 유리질 탄소전극에서 보다 더 증가하였고 환원 전위는 양전위 방향으로 더 이동하였다. 산소 환원 반응에 관여한 전자수와 교환 속도 상수 값은 순환 전압전류 곡선으로부터 구하였다. 산소 환원 반응경로는 최종 생성물이 $H_2O_2$로 가는 $2e^-$ 전이 반응을 나타내었으며 촉매가 수식된 전극에서의 교환 속도 상수는 알몸전극의 값에 비해 약 2~10배 정도 증가하였다.

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Effects of Mitochondrial Reactive Oxygen Species on Neuronal Excitability in Rat Spinal Substantia Gelatinosa Neurons

  • Lee, Hae-In;Park, A-Reum;Chun, Sang-Woo
    • International Journal of Oral Biology
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    • 제37권1호
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    • pp.17-23
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    • 2012
  • Recent studies indicate that reactive oxygen species (ROS) are critically involved in persistent pain primarily through spinal mechanisms, and that mitochondria are the main source of ROS in the spinal dorsal horn. To investigate whether mitochondrial ROS can induce changes in membrane excitability on spinal substantia gelatonosa (SG) neurons, we examined the effects of mitochondrial electron transport complex (ETC) substrates and inhibitors on the membrane potential of SG neurons in spinal slices. Application of ETC inhibitors, rotenone or antimycin A, resulted in a slowly developing and slight membrane depolarization in SG neurons. Also, application of both malate, a complex I substrate, and succinate, a complex II substrate, caused reversible membrane depolarization and enhanced firing activity. Changes in membrane potential after malate exposure were more prominent than succinate exposure. When slices were pretreated with ROS scavengers such as phenyl-N-tert-buthylnitrone (PBN), catalase and 4- hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPOL), malate-induced depolarization was significantly decreased. Intracellular calcium above $100{\mu}M$ increased malateinduced depolarization, witch was suppressed by cyclosporin A, a mitochondrial permeability transition (MPT) inhibitor. These results suggest that enhanced production of spinal mitochondrial ROS can induce nociception through central sensitization.

Effects of NaOCl on the Intracellular Calcium Concentration in Rat Dorsal Root Ganglion Neurons

  • Lee, Hae-In;Chun, Sang-Woo
    • International Journal of Oral Biology
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    • 제35권3호
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    • pp.129-135
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    • 2010
  • Recent studies have implicated reactive oxygen species (ROS) as determinants of the pathological pain caused by the activation of peripheral neurons. It has not been elucidated, however, how ROS activate the primary sensory neurons in the pain pathway. In this study, calcium imaging was performed to investigate the effects of NaOCl, a ROS donor, on the intracellular calcium concentration ($[Ca^{2+}]i$) in acutely dissociated dorsal root ganglion (DRG) neurons. DRG was sequentially treated with 0.2 mg/ml of both protease and thermolysin, and single neurons were then obtained by mechanical dissociation. The administration of NaOCl then caused a reversible increase in the $[Ca^{2+}]i$, which was inhibited by pretreatment with phenyl-N-tertbuthylnitrone (PBN) and isoascorbate, both ROS scavengers. The NaOCl-induced $[Ca^{2+}]i$ increase was suppressed both in a calcium free solution and after depletion of the intracellular $Ca^{2+}$ pool by thapsigargin. Additionally, this increase was predominantly blocked by pretreatment with the transient receptor potential (TRP) antagonists, ruthenium red ($50\;{\mu}M$) and capsazepine ($10\;{\mu}M$). Collectively, these results suggest that an increase in the intracellular calcium concentration is produced from both extracellular fluid and the intracellular calcium store, and that TRP might be involved in the sensation of pain induced by ROS.