• Title/Summary/Keyword: PBN

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Development of ozone passive sampler with fluorescence intensity method (형광광도법을 이용한 오존 passive sampler의 개발)

  • 김한수;김선태;윤은영;김신도
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.245-246
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    • 2001
  • 우리나라에서는 지금까지 대기 오염과 관련하여 환경기준 달성을 위한 정책수립에 있어서 대상물질은 주로 이산화황(SO$_2$)과 먼지(TSP) 등으로 경제개발과 산업발전과정 등에서 발생되는 오염물질이었다. 그러나 최근 몇 년사이 급격한 자동차의 증가로 인한 이산화질소(NO$_2$)와 휘발성유기화합물(VOCs)의 배출이 증가하고 있어 환경규제정책도 점차 변하고 있는 실정이다. 이러한 오염물질들이 대기중에서 태양복사에너지에 의해 광화학 반응을 일으켜 오존(ozone), PAN(peroxyacethyl nitrate), PBN(peroxy benzoyl nitrate), 아크로레인(carolein), 포름알데히드(HCHO, formaldehyde) 등 광화학 산화제를 생성하여 인체, 동ㆍ식물 및 재산상의 피해를 유발하고 있다. (중략)

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A study on the vulcaniz러on characteristic of combined antioxidants in NR and SBR compounds (NR 및 SBR의 노화방지제(老化防止劑) 병용효과(倂用效果)에 의(依)한 가황특성(加黃特性) 연구(硏究))

  • Choi, Jae-Woon;Lee, Ki-Jong
    • Elastomers and Composites
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    • v.17 no.2
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    • pp.77-90
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    • 1982
  • The purpose of this study is to get comparative results on the combined antioxidant systems comprised of MHPPD with IPPD, MHPPD with PBN and MHIPPD with MB when they are individually added to NR and SBR compound. Vulcanization characterstics and physical properties of the combined antioxidants have been studied by means of the Mooney viscometer, the Monsanto disc rheometer and so on. According to the test results, MHPPD with IPPD system has shown faster cure rate, better optimum cure time and shorter scorch time than other systems. The vulcanizate comprised of the MHPPD with IPPD antioxidant system has taken advantage of heat resistance, fluid resistance and antiozone resistance.

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Gate-to-Gate with Modernized GPS, GALILEO and GBAS

  • Schuster, Wolfgang;Ochieng, Washington
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.1
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    • pp.3-8
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    • 2006
  • This paper discusses current challenges, as a result of the rapid increase in air travel, and future navigation needs of Civil Aviation. The objectives pursued by ANASTASIA, a sixth framework European Commission project, are presented. The methods used in the derivation of the navigation performance requirements are introduced and discussed in the context of precision approaches. High-level impacts on the avionics receiver of integrating additional multi-frequency ranging signals from a modernized GPS and Galileo into the current navigation architecture are investigated. Expected performance achievements are presented.

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항공 AIDC를 응용한 VTS 관제센터간 선박관제권 이양절차 도입

  • Yu, Jae-Man;Jeong, Gyeong-Hwa
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2013.06a
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    • pp.368-370
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    • 2013
  • 현재 전 세계 체약국들은 증가하는 항공수요를 충족하고 공역의 이용 효율성 및 항공기 운항의 경제성 등을 제고하기 위해 국제민간항공기구(ICAO)에서 전략적으로 개발하고 채택한 차세대항법시스템(New CNS/ATM, PBN 등)의 각종 항법 및 통신 어플리케이션 등을 도입 적용하고 있다. 이 가운데 AIDC(ATS inter-facility Data Communication)는 조종사와 관제사간 반복적으로 이루어지는 교신(Verbal Communication)사항을 포맷화한 후 데이터로 송출하여 조종사와 관제사 양측 모두의 업무로드를 감소시키며 주파수 점유 시간을 단축시켜 주파수 활용도를 크게 증가시키고 있다. 또한, 비영어권 국가와의 음성 통신시 부정확한 발음 등으로 야기 될 수 있는 인적요인(Human Factor)을 사전 제거하는 등 많은 혜택(Benefits)을 제공하고 있다. 비록 이번 연구에서 항공 AIDC의 모든 요소가 VTS에 1:1 적용 되지는 않지만 AIDC의 주요 요소(TOC, AOC 등)와 우리 해상교통 실정에 맞는 응용 요소(RTOC)를 추가하여 주파수와 관제센터는 다르지만 관제구역이 서로 인접해 있는 구역에 적용시켜 잠재적 위험요소를 사전에 예방하고, 궁극적으로 Service provider로서 이용자 중심의 VTS를 설계하고자 한다.

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Alternative PNT Requirements and Technology Analysis (GNSS 대안항법시스템 요구사항 및 기술 분석)

  • Jo, Sanghoon;Kang, Seung-Eun;Kang, Ja-Young;Ko, Sangho
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.20 no.3
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    • pp.28-34
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    • 2012
  • The recent transition to Performance Based Navigation in aviation enhances the accuracy of aircraft position, safety and efficiency in air traffic operations by using satellite-based navigation system such as GNSS. However, intentional interferences with GNSS signal as well as ones coming from natural phenomena such as solar storm increase. GNSS have very low power and therefore their signals are more susceptible to interferences than ground-based navigation signals. This paper introduces requirements of alternative positioning, navigation and timing(APNT) system and relevant technologies when the GNSS signals are not valid.

Effect of Process Parameters of UV Enhanced Gas Phase Cleaning on the Removal of PMMA (Polymethylmethacrylate) from a Si Substrate

  • Kwon, Sung Ku;Kim, Do Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.4
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    • pp.204-207
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    • 2016
  • Experimental study of UV-irradiated O2/H2 gas phase cleaning for PMMA (Polymethylmethacrylate) removal is carried out in a load-locked reactor equipped with a UV lamp and PBN heater. UV enhanced O2/H2 gas phase cleaning removes polymethylmethacrylate (PMMA) better at lower process pressure with higher content of H2. O2 gas compete for UV (184.9 nm) absorption with PMMA producing O3, O(1D) and lower dissociation of PMMA. In our experimental conditions, etching reaction of PMMA at the substrate temperature between 75℃ and 125℃ had activation energy of about 5.86 kcal/mol indicating etching was controlled by surface reaction. Above the 180℃, PMMA removal was governed by a supply of reaction gas rather than by substrate temperature.

A Study on Tire Labeling Performance for Tire Stiffness Design (타이어 기본강성 설계에 따른 타이어 라벨링 성능변화 연구)

  • Kang, Young Kyu;Kim, GunHo;Jang, InSung;Oh, YagJeon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2013.10a
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    • pp.265-267
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    • 2013
  • Tire labeling is an important issue to reduce $CO_2$ and to secure the safety of tire/vehicle on wet road. A basic study on the effects of tire basic stiffness design on tire labeling performance has been done through experimental test. The pass-by noise is affected by tire structural design. The tire with lower side part stiffness and lower tread part stiffness has the lowest PBN level and the best wet grip. And the tire with higher tread part stiffness and higher side part stiffness has the better RR performance. Also it is observed that the trade-off between RR and wet grip exists for various tire stiffness design.

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Electrocatalytic Effect of Dioxygen Reduction at Glassy Carbon Electrode Modified with Schiff Base Co(II) Complexes (Schiff Base Co(II) 착물이 변성된 유리질 탄소전극에서 산소 환원의 전기촉매 효과)

  • Seong, Jeong-Sub;Chae, Hee-Nam;Choi, Yong-Kook
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.460-468
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    • 1998
  • Schiff base ligands such as $SOPDH_2$, $SNDH_2$, $EBNH_2$, and $PBNH_2$ and their Co(II) complexes such as [$Co(II)(SND)(H_2O)_2$], [$Co(II)(SOPD)(H_2O)_2$], [$Co(II)(EBN)(H_2O)$], and [$Co(II)(PBN)(H_2O)$] have been synthesized. The mole ratio of Shiff base ligand to cobalt(II) for the Co(II) complexes was found to be 1:1. Also these complexes have been configurated with hexa-coordination. Reduction of dioxygen was investigated by cyclic voltammetry at glassy carbon electrodes modified with Schiff base Co(II) complexes in 1 M KOH aqueous solution. At modified glassy carbon electrode with Schiff base Co(II) complexes, reduction peak current of oxygen was increased and peak potential was shifted to more positive direction compared to bare glassy carbon electrode. The electrokinetic parameters such as number of electron and exchange rate constant were calculated from the results of cyclic voltammogrms. The reduction of dioxygen at glassy carbon electrode has been $2e^-$ reaction pathway. Exchange rate constant at glassy carbon electrode modified with Co(II) complexes was increased 2~10 times compared to bare electrode.

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Effects of Mitochondrial Reactive Oxygen Species on Neuronal Excitability in Rat Spinal Substantia Gelatinosa Neurons

  • Lee, Hae-In;Park, A-Reum;Chun, Sang-Woo
    • International Journal of Oral Biology
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    • v.37 no.1
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    • pp.17-23
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    • 2012
  • Recent studies indicate that reactive oxygen species (ROS) are critically involved in persistent pain primarily through spinal mechanisms, and that mitochondria are the main source of ROS in the spinal dorsal horn. To investigate whether mitochondrial ROS can induce changes in membrane excitability on spinal substantia gelatonosa (SG) neurons, we examined the effects of mitochondrial electron transport complex (ETC) substrates and inhibitors on the membrane potential of SG neurons in spinal slices. Application of ETC inhibitors, rotenone or antimycin A, resulted in a slowly developing and slight membrane depolarization in SG neurons. Also, application of both malate, a complex I substrate, and succinate, a complex II substrate, caused reversible membrane depolarization and enhanced firing activity. Changes in membrane potential after malate exposure were more prominent than succinate exposure. When slices were pretreated with ROS scavengers such as phenyl-N-tert-buthylnitrone (PBN), catalase and 4- hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPOL), malate-induced depolarization was significantly decreased. Intracellular calcium above $100{\mu}M$ increased malateinduced depolarization, witch was suppressed by cyclosporin A, a mitochondrial permeability transition (MPT) inhibitor. These results suggest that enhanced production of spinal mitochondrial ROS can induce nociception through central sensitization.

Effects of NaOCl on the Intracellular Calcium Concentration in Rat Dorsal Root Ganglion Neurons

  • Lee, Hae-In;Chun, Sang-Woo
    • International Journal of Oral Biology
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    • v.35 no.3
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    • pp.129-135
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    • 2010
  • Recent studies have implicated reactive oxygen species (ROS) as determinants of the pathological pain caused by the activation of peripheral neurons. It has not been elucidated, however, how ROS activate the primary sensory neurons in the pain pathway. In this study, calcium imaging was performed to investigate the effects of NaOCl, a ROS donor, on the intracellular calcium concentration ($[Ca^{2+}]i$) in acutely dissociated dorsal root ganglion (DRG) neurons. DRG was sequentially treated with 0.2 mg/ml of both protease and thermolysin, and single neurons were then obtained by mechanical dissociation. The administration of NaOCl then caused a reversible increase in the $[Ca^{2+}]i$, which was inhibited by pretreatment with phenyl-N-tertbuthylnitrone (PBN) and isoascorbate, both ROS scavengers. The NaOCl-induced $[Ca^{2+}]i$ increase was suppressed both in a calcium free solution and after depletion of the intracellular $Ca^{2+}$ pool by thapsigargin. Additionally, this increase was predominantly blocked by pretreatment with the transient receptor potential (TRP) antagonists, ruthenium red ($50\;{\mu}M$) and capsazepine ($10\;{\mu}M$). Collectively, these results suggest that an increase in the intracellular calcium concentration is produced from both extracellular fluid and the intracellular calcium store, and that TRP might be involved in the sensation of pain induced by ROS.