• Title/Summary/Keyword: PASADENA

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The ALTADENA and PASADENA studies in benchtop NMR spectrometer

  • So, Howon;Jeong, Keunhong
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.1
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    • pp.6-11
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    • 2019
  • Parahydrogen induced hyperpolarization (PHIP) technique is extensively studied to increase the sensitivity of the conventional NMR spectroscopy and recently try to apply this advanced technique into the revolutionary future of the MRI. The other hyperpolarization technique, which is widely utilized, is DNP (Dynamic Nuclear Polarization)-based hyperpolarization one. Despite its great advances in these fields, it contains several drawbacks to overcome: fast relaxation time, expensive equipment is needed, long build-up time is required (several hours), and batch scale material is hyperpolarized. To overcome all those limitations, one can effectively harness the hyperpolarized spin state of parahydrogen. One important step for utilizing the spin state of parahydrogen is doing well-developed experiments of ALTADENA and PASADENA. Based on those concepts, we successfully obtain the hydrogenation signals of ALTADENA and PASADENA from styrene by using benchtop NMR spectrometer. Also those signals were conceptually analyzed and confirmed with different mechanisms. To our best knowledge, those experiments using 1.4T (benchtop NMR) is the first reported one. Considering these experiments, we hope that parahydrogen-based hyperpolarization transfer studies in NMR/MRI will be broadened in Korea in the future.

Streetscape Design of Arroyo Parkway, Pasadena, California (아로요 파크웨이 조경설계)

  • Jeong Wook-Ju
    • Journal of the Korean Institute of Landscape Architecture
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    • v.32 no.4
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    • pp.105-117
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    • 2004
  • The Pasadena Freeway follows the Arroyo Seco through foothills and scenic passes to link Downtown Los Angeles with Pasadena. The approximately 10 mile road was the first freeway built in the West during the 1930's and is today designated as a Historic Parkway. As it approaches Pasadena, it terminates at a traffic light intersection at Glenarm Street, and then becomes a commercial road the Arroyo Parkway. This one and a quarter mile long, north south road moves significant volumes of traffic both into and out of Pasadena. The Arroyo Parkway is thus a major 'gateway' and an important axis of orientation and movement, terminating in the City's core civic, commercial and retail district. Planting, lighting, signage, paving, furnishing and fixtures ought to all be properly designed and coordinated to create a distinctive 'gateway' experience arriving to Pasadena and driving along the Arroyo Parkway. Alternate design studies, developed in discussion with City officials and others involved in the redevelopment of the area, would need to be done to properly decide on the best direction. Issues of heritage and traditional streetscape will likely have to be reconciled with both the reality of the vehicular character of the road and more contemporary themes. Obviously with such large parcels of property available in the Arroyo Fair Oaks corridor, there is a huge potential for redevelopment and building. This potential would only be strengthened by the Light Rail Line and its stations, the improvements to the Arroyo Parkway, and the redevelopment of the Arts Center College of Design. Guides and controls to the development process, including programming and physical design studies, would need to be developed in order to ensure that the maximum potential for the corridor be realized. This concept proposal suggests that the whole strip might be developed as a Arts and Technology corridor, with special emphases on education, public culture, media and lifestyle. The full programming possibilities need to be further developed. Additionally, appropriate urban design guidelines to ensure high quality development also need to be incorporated into an overall development plan.

Force Fields and Elastic Properties of Syndiotactic Isoregic Poly(viny1 fluoride) Crystal (Syndiotactic isoregic 폴리비닐플로라이드 결정의 Force Fields 및 Elastic Properties)

  • Geo, G;Lee, Jeong-Gu;Hong, Jin-Hu
    • Korean Journal of Materials Research
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    • v.4 no.7
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    • pp.792-797
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    • 1994
  • Force fields of syndiotactic isoregic PVF crystal have been extracted by optimizing a structure of 2,4,6-trifluoroheptane with ab initio Quantum mechanical method with 6-31G * * basis set, and applied to calculate the structure parameters and elastic constants of the material. The cell parameters turned out to be 5.205$\AA$, of a axis(chain axis), 8.457$\AA$, of b axis and 4.621$\AA$ of c axis. These parameters are in fair agreement with those of the atactic X-ray structure(5.04$\AA$, 8.57$\AA$, and 4.95$\AA$,respectively). The young's modulus of defect free syndiotactic PVF crystal was computed to be 267 GPa comparable to those of polyvinilidene fluoride(277-293 GPa) and polyethylene(264-337 GPa) crystals. Bulk modulus value obtained at optimum geometry is more than twice greater than that obtained at experimental geometry due to large difference of elastic compliance constant (especially Sgj element) at these two different geometries.

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