• Title/Summary/Keyword: P/C Based Method

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The Investigation of a Novel Indicator System for Trace Determination and Speciation of Selenium in Natural Water Samples by Kinetic Spectrophotometric Detection

  • Gurkan, Ramazan;Ulusoy, Halil Ibrahim
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1907-1914
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    • 2010
  • A novel catalytic kinetic method is proposed for the determination of Se(IV), Se(VI) and total inorganic selenium in water based on the catalytic effect of Se(IV) on the reduction of bromate by p-nitrophenylhydrazine at pH 3.0. The generated bromine, $Br_2$ or $Cl_2$ plus $Br_2$ in 0.1 M NaCl (or NaBr) environment efficiently decolorized Calmagite and the reaction was monitored spectrophotometrically at 523 nm as a function of time. In this indicator reaction, bromide acted as an activator for the catalysis of selenium (IV) and a reducing agent for selenium (VI) at pH 3.0, which allowed the determination of total selenium. The fixed time method was adopted for the determination and speciation of inorganic selenium. Under the optimum conditions, the calibration graph are linear in the range 1 - 35 ${\mu}gL^{-1}$ of Se(IV) for the fixed time method at $25^{\circ}C$. The detection limit based on statistical $3S_{blank}$/m-criterion was 0.215 ${\mu}gL^{-1}$ for the fixed time method (7 min). All of the variables that affect the sensitivity at 523 nm were investigated, and the optimum conditions were established. The interference effect of various cations and anions on the Se (IV) determination was also studied. The selectivity of the selenium determination was greatly improved with the use of the strongly cation exchange resin such as Amberlite IR120 plus. The proposed kinetic method was validated statistically and through recovery studies in natural water samples. The RSDs for ten replicate measurements of 5, 15 and 25 ${\mu}gL^{-1}$ of Se(IV) and Se(VI) was changed between 2.1 - 4.85%. Analyses of a certified standard reference material (NIST SRM 1643e) for selenium using the fixed-time method showed that the proposed kinetic method has good accuracy. Se(IV), Se(VI) and total inorganic selenium in environmental water samples have been successfully determined by this method after selective reduction of Se(VI) to Se(IV).

Investigation on the property and preparation of ferroelectric Pb(Zr,Ti)$O_3$ by Sol-Gel method (Sol-Gel법에 의한 강유전체 Pb(Zr, Ti)$O_3$의 제조 및 특성에 관한 연구)

  • 임정한;김영식;장복기
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.496-503
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    • 1994
  • In recent years Sol-Gel processing provides an interesting alternative method for the fabrication of ferroelectric thin layers and powder. PZT powder was prepared from an alkoxide-based solution by a Sol-Gel method. Gelation of synthesized complex solutions, microstructure, thermal analysis and crystallization behaviors of the calcined powder were studied in accordance with a water content and a catalyst. Especially gelation and crystallization behavior were analysed with the change of pH. The gelation time decreased as the pH of the mixed solution increased. For PZT powder with 650.deg. C heat treatment, 100% perovskite phase was formed by using either acidic or basic catalyst. By using either acidic or basic catalyst, we were able to get very fine powders of uniform shape with an average particle size of 0.8-1.mu.m.

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A study on MPPT control using the balace/unbalance control (평형/불평형 제어를 이용한 MPPT제어에 과한 연구)

  • K., T.K.;K., G.H.;C., K.J.;P., J.W.;Matsui, M.;L., H.W.
    • Proceedings of the KIEE Conference
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    • 2005.10c
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    • pp.334-336
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    • 2005
  • This paper proposes a simple MPPT control scheme of a Current- Control-Loop Error system Based that can be obtains a lot of advantage to compare with another digital control method, P&O and IncCond algorithm, that is applied mostly a PV system. An existent method is needed an expensive processor such as DSP that calculated to change the measure power of a using current and voltage sensor at the once. But, a proposed method is easy to solve the cost reduction and power unbalance problems that it is used by control scheme to limit error of a current control of common sensor. This proposed algorithm had verified through a simulation and an experiment on battery charger using PIC that is the microprocessor of a low price.

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Evidence of Significant Effects of Stunning and Chilling Methods on PSE Incidences

  • Park, B.Y.;Kim, J.H.;Cho, S.H.;Hah, K.H.;Lee, S.H.;Choi, C.H.;Kim, D.H.;Lee, J.M.;Kim, Y.K.;Ahn, J.N.;Hwang, I.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.2
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    • pp.257-262
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    • 2007
  • The current study was conducted to investigate the optimum stunning voltage and chilling regime with emphasis on reduction in pale, soft and exudative (PSE) pork. The experiments were conducted at seven Korean major pig abattoirs using a total of 91,082 industrial population. Frequencies of PSE meat was found to be significantly (p<0.05) increased as stunning voltage was elevated from 220-240 (13.14%), 250-280 (29.32%) to 430 volts (36.74%). Chilling methods after slaughter, either with cold water showing or rapid chilling reduced PSE meat by 22% compared to a classic chiller-based slow chilling regime. The current study also revealed that chiller temperature during the first 90 minutes had a significant (p<0.001) effect on PSE incidences. Pigs chilled between -5 to $7^{\circ}C$ resulted in the lowest PSE meat (17.8%), followed by higher than $7^{\circ}C$ (21.3%) and lower than $-5^{\circ}C$ (37.5%). The current data implies that low voltage stunning method (eg., 220-240 volts), followed by rapid chilling regime, maintaining chiller temperature between approximately -5 to $7^{\circ}C$ could reduce PSE incidences.

A Study on Application of RCM Method to Power Distribution System using Ordinal Optimization (Ordinal Optimization을 이용한 배전계통에 RCM 적용기법에 관한 연구)

  • Moon, Jong-Fil;Ji, Pyeong-Shik
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.61 no.2
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    • pp.67-73
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    • 2012
  • This paper proposes optimal maintenance strategies for power distribution systems that involve the use of the reliability-centered maintenance (RCM) method. We developed an improved decision model based on the Markov process. This model can obtain the optimal inspection interval and maintenance method based on the total expected cost. We used ordinal optimization for solving the optimal problem. Optimal maintenance strategies were presented by applying the developed method to the RBTS model. A B/C analysis proved that these strategies offer maximum benefit-to-cost.

Towards Thermally Stable Tandem Organic Solar Cells

  • Yang, Feng;Wang, Sihan;Kim, Ji-Hwan;Kim, Yong-Sang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.410.2-410.2
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    • 2016
  • Tandem structure is promising in organic solar cells because of its double open-circuit voltage (VOC) and efficient photon energy conversion. In a typical tandem device, the two single sub-cells are stacked and connected by an interconnecting layer. The fabrication of two sub-cells are usually carried out in a glovebox filled with nitrogen or argon gas, which makes it expensive and laborious. We report a glovebox-free fabricated inverted tandem organic solar cells wherein the tandem structure comprises sandwiched interconnecting layer based on p-doped hole-transporting, metal, and electron-transporting materials. Complete fabrication process of the tandem device was performed outside the glove box. The tandem solar cells based on poly(3-hexylthiophene) (P3HT) and (6,6)-phenyl C61-butyric acid methyl ester (PCBM) can realize a high VOC, which sums up of the two sub-cells. The tandem device structure was ITO/ZnO/P3HT:PCBM/PEDOT:PSS/MoO3/Au/Al/ZnO-d/P3HT:PCBM/PEDOT:PSS/Ag. The separate sub-cells were morphologically and thermally stable up to 160 oC. The high stability of the active layer benefits in the fabrication processes of tandem device. The performance of tandem organic solar cells comes from the sub-cells with an 50 nm thick active layer of P3HT:PCBM, achieving an average power conversion efficiency (PCE) of 2.9% (n=12) with short-circuit current density (JSC) = 4.26 mA/cm2, VOC = 1.10 V, and fill factor (FF) = 0.62. Based on these findings, we propose a new method to improve the performance and stability of tandem organic solar cells.

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Development of DB index method simulator for induced voltage in steady state (DB Index 방식 상시 유도전압 시뮬레이터의 개발)

  • Jun, Fu;Kwon, O.S.;Kim, C.H.;Jung, C.S.;Yoo, Y.P.
    • Proceedings of the KIEE Conference
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    • 2006.07a
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    • pp.284-285
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    • 2006
  • This paper presents DB Index method simulator for induced voltage to a communication line from an overhead power transmission line in steady state. DB index method is based on EMTP simulation results. The simulation is implemented for 3,500,000 cases which are combined by employing transmission line parameter of KEPCO.

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p-Type Activation of AlGaN-based UV-C Light-Emitting Diodes by Hydrogen Removal using Electrochemical Potentiostatic Activation (전기화학적 정전위 활성화를 사용한 수소 제거에 의한 AlGaN기반의 UV-C 발광 다이오드의 p-형 활성화)

  • Lee, Koh Eun;Choi, Rak Jun;Kumar, Chandra Mohan Manoj;Kang, Hyunwoong;Cho, Jaehee;Lee, June Key
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.4
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    • pp.85-89
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    • 2021
  • AlGaN-based UV-C light-emitting diodes (LEDs) were applied for p-type activation by electrochemical potentiostatic activation (EPA). The p-type activation efficiency was increased by removing hydrogen atoms through EPA treatment using a neutral Mg-H complex that causes high resistance and low conductivity. A neutral Mg-H complex is decomposed into Mg- and H+ depending on the key parameters of solution, voltage, and time. The improved hole carrier concentration was confirmed by secondary ion mass spectroscopy (SIMS) analysis. This mechanism eventually improved the internal quantum efficiency (IQE), the light extraction efficiency, the leakage current value in the reverse current region, and junction temperature, resulting in better UV-C LED lifetime. For systematic analysis, SIMS, Etamax IQE system, integrating sphere, and current-voltage measurement system were used, and the results were compared with the existing N2-annealing method.

Test of Hypothesis in Assessing Process Capability Index Cpmk (공정능력지수 Cpmk를 평가함에서의 바람직한 가설검정)

  • Cho, Joong-Jae;Yu, Hye-Kyung;Hana, Jung-Su
    • Communications for Statistical Applications and Methods
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    • v.17 no.3
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    • pp.459-471
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    • 2010
  • Higher quality level is generally perceived by customers as improved performance by assigning a correspondingly higher satisfaction score. Usually, the quality level is measured by process capability indices. The index is used to determine whether a production process is capable of producing items within a specified tolerance. The third generation index $C_{pmk}$ is more powerful than two useful indices $C_p$ and $C_{pk}$. which have been widely used in six sigma industries to assess process performance. Most evaluations on process capability indices focus on point estimates, which may result in unreliable assessments of process performance. In this paper, we consider better testing procedure on assessing process capability index $C_{pmk}$ for practitioners to use in determining whether a given process is capable. It is easy to use the proposed method for assessing process capability index $C_{pmk}$. Whether a process is clearly normal or nonnormal, our bootstrap testing procedure could be applied effectively without the complexity of calculation. A numerical result based on our proposed method is illustrated.

Analysis and Synthesis of GF(2p) Multiple Attractor Cellular Automata (GF(2p) 다중 끌개를 갖는 셀룰라 오토마타의 합성 및 분석)

  • Choi, Un-Sook;Cho, Sung-Jin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.13 no.6
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    • pp.1099-1104
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    • 2009
  • Cellular Automata(CA) has been used as modeling and computing paradigm for a long time. While studying the models of systems, it is seen that as the complexity of the physical system increase, the CA based model becomes very complex and becomes to difficult to track analytically. Also such models fail to recognize the presence of inherent hierarchical nature of a physical system. In this paper we analyze the properties of GF($2^p$) multiplue attractor cellular automata(GF($2^p$) MACA) C and give a method of synthesis of C which is a special class of hierarchical cellular automata proposed as an alternative to solve the problem.