• Title/Summary/Keyword: Ozone sensitivity

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Sensitivity Experiment of Surface Reflectance to Error-inducing Variables Based on the GEMS Satellite Observations (GEMS 위성관측에 기반한 지면반사도 산출 시에 오차 유발 변수에 대한 민감도 실험)

  • Shin, Hee-Woo;Yoo, Jung-Moon
    • Journal of the Korean earth science society
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    • v.39 no.1
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    • pp.53-66
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    • 2018
  • The information of surface reflectance ($R_{sfc}$) is important for the heat balance and the environmental/climate monitoring. The $R_{sfc}$ sensitivity to error-induced variables for the Geostationary Environment Monitoring Spectrometer (GEMS) retrieval from geostationary-orbit satellite observations at 300-500 nm was investigated, utilizing polar-orbit satellite data of the MODerate resolution Imaging Spectroradiometer (MODIS) and Ozone Mapping Instrument (OMI), and the radiative transfer model (RTM) experiment. The variables in this study can be cloud, Rayleigh-scattering, aerosol, ozone and surface type. The cloud detection in high-resolution MODIS pixels ($1km{\times}1km$) was compared with that in GEMS-scale pixels ($8km{\times}7km$). The GEMS detection was consistent (~79%) with the MODIS result. However, the detection probability in partially-cloudy (${\leq}40%$) GEMS pixels decreased due to other effects (i.e., aerosol and surface type). The Rayleigh-scattering effect in RGB images was noticeable over ocean, based on the RTM calculation. The reflectance at top of atmosphere ($R_{toa}$) increased with aerosol amounts in case of $R_{sfc}$<0.2, but decreased in $R_{sfc}{\geq}0.2$. The $R_{sfc}$ errors due to the aerosol increased with wavelength in the UV, but were constant or slightly decreased in the visible. The ozone absorption was most sensitive at 328 nm in the UV region (328-354 nm). The $R_{sfc}$ error was +0.1 because of negative total ozone anomaly (-100 DU) under the condition of $R_{sfc}=0.15$. This study can be useful to estimate $R_{sfc}$ uncertainties in the GEMS retrieval.

Sensitivity Analysis by Using Global Imager for Retrieval of Biomass Burning Aerosols

  • Lee, Hyun-Jin;Kim, Jae-Hwan
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.79-85
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    • 2011
  • The purpose of this study is to evaluate the strength of the near-UV wavelength of 380 nm relative to visible and near-IR bands, and to find the suitable wavelength for detecting aerosols by using the Global Imager (GLI) sensor aboard the Advanced Earth Observing Satellite-II (ADEOS-II). Sensitivity analysis is performed for the retrieval of biomass burning aerosols by employing the radiative transfer model Rstar5b. It is determined that background surface reflectance in the blue band is similar to that in the near-UV band, and that wavelengths in the blue bands are more sensitive to the Aerosol Optical Thickness (AOT) than wavelengths in the near-UV band. The Total Ozone Mapping Spectrometer (TOMS) Aerosol Index (AI) is used in the indirect method used for aerosol retrieval, and the wavelength pair 380 nm and 460 nm is determined to be the most sensitive to the AOT. The results of this study suggest that wavelengths in the blue bands are suitable for detecting biomass burning aerosols over the Korean peninsula.

Evaluation of Sensitivity and Retrieval Possibility of Land Surface Temperature in the Mid-infrared Wavelength through Radiative Transfer Simulation (복사전달모의를 통한 중적외 파장역의 민감도 분석 및 지표면온도 산출 가능성 평가)

  • Choi, Youn-Young;Suh, Myoung-Seok;Cha, DongHwan;Seo, DooChun
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1423-1444
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    • 2022
  • In this study, the sensitivity of the mid-infrared radiance to atmospheric and surface factors was analyzed using the radiative transfer model, MODerate resolution atmospheric TRANsmission (MODTRAN6)'s simulation data. The possibility of retrieving the land surface temperature (LST) using only the mid-infrared bands at night was evaluated. Based on the sensitivity results, the LST retrieval algorithm that reflects various factors for night was developed, and the level of the LST retrieval algorithm was evaluated using reference LST and observed LST. Sensitivity experiments were conducted on the atmospheric profiles, carbon dioxide, ozone, diurnal variation of LST, land surface emissivity (LSE), and satellite viewing zenith angle (VZA), which mainly affect satellite remote sensing. To evaluate the possibility of using split-window method, the mid-infrared wavelength was divided into two bands based on the transmissivity. Regardless of the band, the top of atmosphere (TOA) temperature is most affected by atmospheric profile, and is affected in order of LSE, diurnal variation of LST, and satellite VZA. In all experiments, band 1, which corresponds to the atmospheric window, has lower sensitivity, whereas band 2, which includes ozone and water vapor absorption, has higher sensitivity. The evaluation results for the LST retrieval algorithm using prescribed LST showed that the correlation coefficient (CC), the bias and the root mean squared error (RMSE) is 0.999, 0.023K and 0.437K, respectively. Also, the validation with 26 in-situ observation data in 2021 showed that the CC, bias and RMSE is 0.993, 1.875K and 2.079K, respectively. The results of this study suggest that the LST can be retrieved using different characteristics of the two bands of mid-infrared to the atmospheric and surface conditions at night. Therefore, it is necessary to retrieve the LST using satellite data equipped with sensors in the mid-infrared bands.

Fabrication and characteristics of NOx gas sensors using WO3 and In2O3 thick films to monitor air pollution

  • Son, M.W.;Choi, J.B.;Hwang, H.I.;Yoo, K.S.
    • Journal of Sensor Science and Technology
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    • v.18 no.4
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    • pp.263-268
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    • 2009
  • With the increasing number of automobiles, the problem of air pollution from the exhaust gases of automobiles has become a critical issue. The principal gases that cause air pollution are nitrogen oxide or NO$_x$(NO and NO$_2$), and CO. Because NO$_x$ gases cause acid rain and global warming and produce ozone(O$_3$) that leads to serious metropolitan smog from photochemical reaction, they must be detected and reduced. Mixtures of WO$_3$ and $In_2O_3$(WO$_3$:$In_2O_3$=10:0, 7:3, 5:5, 3:7, and 0:10 in wt.%), which are NO$_x$ gas-sensing materials, were prepared, and thick-film gas sensors that included a heater and a temperature sensor were fabricated. Their sensitivity to NO$_x$ was measured at 250$\sim$400$^{\circ}C$ for NO$_x$ concentrations of 1$\sim$5 ppm. The $In_2O_3$ thick-film sensor showed excellent sensitivity($R_{gas}/R_{air}$=10.22) at 300$^{\circ}C$ to 5-ppm NO. The response time for 70 % saturated sensitivity was about 3 seconds, and the sensors exhibited very fast reactivity to NO$_x$.

The Use of Indicator Species for Photochemical Ozone Sensitivity Analysis (지시종을 이용한 수도권 광화학 오존의 민감도 분석)

  • 김경렬;백성욱;이강웅;이동수;이미혜;조석연;이종범;이석조;한진석
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.137-138
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    • 2003
  • 광화학 오존의 생성에 필수적인 3가지 요소 중에서 인위적으로 조절가능한 부분은 질소화합물과 유기화합물의 배출량이다. 하지만 배출량 감소를 유도하여 이들의 대기 중 농도를 줄일 경우 오존 발생이 저감될 지의 여부는 매우 다양하고 복잡한 화학반응들을 평가한 결과 단순한 상관 관계가 아닐 수 있다는 것이 밝혀져 있다. 이는 어떤 경우 이들 오염물질의 배출량 감소에도 불구하고 오존의 농도는 오히려 증가할 수 있는 가능성을 지시한다. 결국 오존발생에 관여하는 질소 화합물과 휘발성유기화합물의 정확한 정량적인 평가가 우선되어야 한다. (중략)

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Method development for detecting superoxide/hydroperoxyl radical

  • Kwon, Bum-Gun;Lee, Jai H.
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.165-166
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    • 2001
  • HO$_2$ radical plays pivotal roles in the tropospheric $O_3$ formation chemistry. This radical oxidizes NO to NO$_2$ and thus HO$_2$ radical can lead to in-situ ozone formation. Numerous methods have been tried to measure concentrations of atmospheric HO$_2$ in gas phase. Detecting methods applied in the air are a chemical amplifier (Cantrell et al., 1996), FAGE (Fluorescence Assay with Gas Expansion) (Hard et al., 1984), and LIF (Laser-induced Fluorescence) (Stevens et al., 1994). These methods have been limited because of low sensitivity and interferences such as $O_3$, NO, and itself (Stevens et al.,1994). (omitted)

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The Study On Safety of Olive Oil Production Ozonized of Hair and Skin Improvement (모발 및 피부 개선의 오존화 올리브 오일 생산에 대한 안전성에 관한 연구)

  • Park, Sun-Yee
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.583-587
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    • 2015
  • This Purpose of this study is to develop a system for stable production without troubling side effects, scalp and skin, and sensitivity to temperature and humidity, but the ozone-cream at a constant effective value and the durability of peroxide safe discharge tube. Furthermore, olive oil and ozone is reacted with the wish to apply to the manufacturing technology. If peroxide value of ozonized olive oil exceeded 1200 meg/kg, there may be microbial disinfection. However, to be produced with a minimum of risk because they look to the scalp and skin sensitization is the purpose of the present study. And also the durability of the discharge tube was tested during the production unit for stable production. And the experimental results, Peroxide value of the ozonized olive oil was measured to less than 1300 meg/kg, also it showed a stable result of the discharge tube.

Investigation of SO2 Effect on TOMS O3 Retrieval from OMI Measurement in China (OMI 위성센서를 이용한 중국 지역에서 TOMS 오존 산출에 대한 이산화황의 영향 조사 연구)

  • Choi, Wonei;Hong, Hyunkee;Kim, Daewon;Ryu, Jae-Yong;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.32 no.6
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    • pp.629-637
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    • 2016
  • In this present study, we identified the $SO_2$ effect on $O_3$ retrieval from the Ozone Monitoring Instrument (OMI) measurement over Chinese Industrial region from 2005 through 2007. The Planetary boundary layer (PBL) $SO_2$ data measured by OMI sensor is used in this present study. OMI-Total Ozone Mapping Spectrometer (TOMS) total $O_3$ is compared with OMI-Differential Optical Absorption Spectrometer (DOAS) total $O_3$ in various $SO_2$ condition in PBL. The difference between OMI-TOMS and OMI-DOAS total $O_3$ (T-D) shows dependency on $SO_2$ (R (Correlation coefficient) = 0.36). Since aerosol has been reported to cause uncertainty of both OMI-TOMS and OMI-DOAS total $O_3$ retrieval, the aerosol effect on relationship between PBL $SO_2$ and T-D is investigated with changing Aerosol Optical Depth (AOD). There is negligible aerosol effect on the relationship showing similar slope ($1.83{\leq}slope{\leq}2.36$) between PBL $SO_2$ and T-D in various AOD conditions. We also found that the rate of change in T-D per 1.0 DU change in PBL, middle troposphere (TRM), and upper troposphere and stratosphere (STL) are 1.6 DU, 3.9 DU and 4.9 DU, respectively. It shows that the altitude where $SO_2$ exist can affect the value of T-D, which could be due to reduced absolute radiance sensitivity in the boundary layer at 317.5 nm which is used to retrieve OMI-TOMS ozone in boundary layer.

Vulnerability Assessment for Public Health to Climate change Using Spatio-temporal Information Based on GIS (GIS기반 시공간정보를 이용한 건강부문의 기후변화 취약성 평가)

  • Yoo, Seong-Jin;Lee, Woo-Kyun;Oh, Su-Hyun;Byun, Jung-Yeon
    • Spatial Information Research
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    • v.20 no.2
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    • pp.13-24
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    • 2012
  • To prevent the damage to human health by climate change, vulnerability assessment should be conducted for establishment of adaptation strategies. In this study, vulnerability assessment was conducted to provide information about vulnerable area for making adaptation policy. vulnerability assessment for human health was divided into three categories; extreme heat, ozone, and epidemic disease. To assess vulnerability, suitable indicators were selected by three criteria; sensitivity, adaptive capacity, and exposure, spatial data of indicators were prepared and processed using GIS technique. As a result, high vulnerability to extreme heat was shown in the low land regions of southern part. And vulnerability to harmful ozone was high in the surrounding area of Dae-gu basin and metropolitan area with a number of automobiles. Vulnerability of malaria and tsutsugamushi disease have a region-specific property. They were high in the vicinity of the Dimilitarized zone and south-western plain, respectively. In general, vulnerability of human health was increased in the future time. Vulnerable area was extended from south to central regions and from plain to low mountainous regions. For assessing vulnerability with high accuracy, it is necessary to prepare more related indicators and consider weight of indicators and use climate prediction data based on the newly released scenario when assessing vulnerability.

Vulnerability Assessment of the Air Pollution Using Entropy Weights : Focused on Ozone (엔트로피 가중치를 활용한 대기오염 취약성 평가 - 오존을 중심으로 -)

  • Lee, Sang-hyeok;Kang, Jung Eun;Bae, Hyun Joo;Yoon, Dong Keun
    • Journal of the Korean association of regional geographers
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    • v.21 no.4
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    • pp.751-763
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    • 2015
  • Both the selection of indicators and weights for them are critical issues in the vulnerability assessment. This study is to assess the air pollution vulnerability focused on ozone for 249 local jurisdictions using weights calculated by the entropy methodology and then examine the applicability of the methodology. We selected indicators for air pollution vulnerability assessment and standardized them. Subsequently, we calculated weights of each indicator using the entropy method and then integrated them into the vulnerability index. The exposure indicators consider meteorological and air pollution factors and the sensitivity of the local jurisdiction include variables on vulnerable areas and environments. The adaptive capacity contains socio-economic characteristics, health care capacities and air pollution managemental factors. The results show that Hwaseong-si, Gwangjin-gu, Gimpo-si, Gwangju-si, Gunpo-si are among the highest vulnerabilities based on the simple aggregation of indicators. And vulnerability-resilience (VRI) aggregation results indicates the similar spatial pattern with the simple aggregation outcomes. This article extends current climate change vulnerability assessment studies by adopting the entropy method to evaluate relative usefulness of data. In addition, the results can be used for developing customized adaptation policies for each jurisdiction reflecting vulnerable aspects.

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