• 전기학회논문지P
• /
• 제50권3호
• /
• pp.125-129
• /
• 2001

ln this paper, a ozone generator using superimposition of silent discharge has been designed and manufactured. This type ozone generator is equipped with three electrodes and two gaps. Ozone is generated by superimposition of silent discharge, which is respectively come from two gaps. The maximum values of ozone concentration, ozone generation flow and ozone energy field were obtained 4,750[ppm], 2.37[g/h], 102.3[g/kWh]. Also, the result of reaction of 1,8921ppm] ozone and the sampling water from the lake, the water quality was improved from IV grade to In grade, and obtained 100[%] sterilization rate of Escherichia coli within 5.0(min).

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제49권8호
• /
• pp.468-476
• /
• 2000

Nowadays, ozone is mainly utilized for water treatment and home equipments. Although the demand for ozone is increasing, the ozone yield of silent discharge type ozonizer is low. Therefore, it is expected to improve the energy efficiency and ozone yield of an ozonizer. In this paper, a new ozone generation system is proposed. The 60[Hz] three-phase voltage is applied to three-phase superposed discharge type ozonizer(3PSDO) which has three electrodes(central, internal and external electrodes). There is no discharge pause time when three-phase voltage is applied due to 120-degree phase difference of applied voltage. The synergy effect of the three-phase superposed discharge type ozonizer is investigated by comparing with the three sort of single-phase discharge type ozonizer(1PDO). So, three-phase superposed discharge type ozonizer is able to obtain high ozone yield, and optimize discharge space, because this can increase the discharge power at low applied voltage.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2000년도 하계학술대회 논문집 C
• /
• pp.2147-2149
• /
• 2000

The silent discharge is known to be one of the most effective methods for ozone generation. In this paper. in order to improve ozone concentration and energy yield, some kind of silent discharge-type reactors with different dielectric materials were prepared. Some silent discharge characteristics of these reactors were studied and discussed.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제48권12호
• /
• pp.791-797
• /
• 1999

Recently the ozone generation system is well used for cleaning the contaminated water by using the strong oxidization effects of ozone. In this paper the concentration, yield and generation quantity of the ozone by the Surface-Silent Discharge According to the Length of Coaxial Electrode is described. The electrodes composed of 3 electrodes-2 gaps are coaxial type and the ozone generation tube were designed and fabricated from the point of view of the energy efficiency, stability and easy control. To investigate the ozone generation dependency on electrode length, a few discharge tubes with different lengths were fabricated. The experimental equipments were provided with cooling system and dehumidifier for the many testing conditions. The main results show that the concentration, yield and generation quantity of ozone are improved by decreasing gas temperatures and increasing electrode lengths.

• 조명전기설비학회논문지
• /
• 제20권7호
• /
• pp.58-64
• /
• 2006

최근 탈취, 탈색, 정수처리 및 배연가스의 정화에 많이 이용되고 있는 오존의 효과적인 발생에 많은 관심이 모아지고 있다. 전기 방전에 의한 오존 발생 방법 중 유전체 배리어 방전이 보다 낮은 전력을 소모하며, 또한 저전압 동작이 가능하여 가장 효과적인 것으로 생각되고 있다. 본 연구에서는 오존발생농도 및 에너지효율을 개선하기 위하여 알루미나 유전체 및 알루미나 유전체와 알루미나 비드를 충진한 무성방전관을 제작하여 무성방전특성을 연구하였다. 또한 오존발생특성을 무성방전특성과 연관하여 논하였으며, 특히 방전시 유전체에 축적되는 벽전하 및 소비전력특성의 관점에서 논하였다. 결과, 비드를 가진 방전관의 경우 축적되는 벽전하량은 비드가 없는 방전관에 비하여 약 2.5배 정도였으며, 발생되는 오존농도 및 에너지 수율 또한 개선되었다.

• 한국조명전기설비학회:학술대회논문집
• /
• 한국조명전기설비학회 1999년도 학술대회논문집-국제 전기방전 및 플라즈마 심포지엄 Proceedings of 1999 KIIEE Annual Conference-International Symposium of Electrical Discharge and Plasma
• /
• pp.11-16
• /
• 1999

Discharge characteristics research for high voltage and large current electric machinery design, the development of ozonizer with high yield and efficiency for environment improvement, generation of plasma & laser and EMI EMC are research fields of Enersy & Environment Electromagnetic Laboratory(EEEL) in the school of electrical & electronic engineering of Yeungnam University. On this paper, we would like to introduce the discharge and ozone generation characteristics of ozonizers designed and manufactured by EEEL. After starting research for fluid gas discharge characteristics early in the 1980's, high voltage nozzle(HVN) type ozonizer, neon lamp(Nelamp) type ozonizer, ozone lamp(Olamp) type ozonizer and multi-discharge type ozonizer(MDO) have been investigated since 1990.

• 조명전기설비학회논문지
• /
• 제30권2호
• /
• pp.71-77
• /
• 2016

The dielectric barrier discharge (DBD) has low efficiency due to about 70% input power is consumed as thermal energy in the discharge space. However, because of the usage of DBD ozone generator is easier than other methods. The DBD ozone generator has been widely applied for high concentration ozone generation in the industrial application. But, the low-capacity compact DBD ozone generator is not applied so far. Therefore, the DBD ozone generator is necessary to improve ozone production efficiency and reduce the capacity. In this paper, the stainless steel pipe inner electrode was designed with hall type and screw type to improve the ozone production yield. The manufactured two inner electrodes were experimented with normal type for comparison of the discharge characteristics and the ozone generating characteristics. As the experimental results, the discharge current effective value of designed inner electrodes with hall type and screw type are higher than the normal type, due to unequal electric field is formed at the boundary. However, the difference of designed and original electrodes is less than 0.1mA that has no effect on the discharge characteristic. On the other hand, the screw type inner electrode increased higher than original model about 7 times when the flow rate of the oxygen source gas was increased from $0.6{\ell}/min$ to $1.0{\ell}/min$ The reason was assumed by the flow rate of the raw gas through the inner electrode was became fast that has a cooling effect. The designed hall type and screw type inner electrodes have shown good performances in ozone generation and ozone production that better than normal type in the same electrode surface area.

• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1998년도 가을 학술발표회 프로그램
• /
• pp.1-1
• /
• 1998

Advanced (Chemical) oxidation processes (AOP) differ from most conventional ones in that hydroxyl radical(OH.) is considered to be the primary oxidant. Hydroxyl radicalcan react non-selectively with a great number of organic and inorganic chemicals. The typical rate constants of true hydroxyl radical reactions are in the range of between 109 to 1012 sec-1. Many processes are possible to generate hydroxyl radical. These include physical and chemical methods and their combinations. Physical means involves the use of high energy radiation such as gamma ray, electron beam, and acoustic wave. Under an applied high energy radiation, water molecules can be decomposed to yield hydroxyl radicals or aqueous electrons. Chemical means include the use of conventional oxidants such as hydrogen peroxide and ozone, two of the most efficient oxidants in the presence of promoter or catalyst. Hydrogen peroxide in the presence of a catalyst such as divalent iron ions can readily produce hydroxyl radicals. Ozone in the presence of specific chemical species such as OH- or hydrogen peroxide, can also generate hydroxyl radicals. Finally the combination of chemical and physical means can also yield hydroxyl radicals. Hydrogen peroxide in the presence of acoustic wave or ultra violet beam can generate hydroxyl radicals. The principles for hydroxyl radical generation will be discussed. Recent case studied of AOP for water treatment and other environmental of applications will be presented. These include the treatment of contaminated soils using electro-Fenton, lechate treatment with conventional Ponton, treatment of coal for sulfur removal using sonochemical and the treatment of groundwater with enhanced sonochemical processes.

• 대한환경공학회지
• /
• 제28권4호
• /
• pp.362-367
• /
• 2006

도시 하수처리장에서 수집되는 폐활성 슬러지는 유기성 물질을 다량 함유하고 있는 바이오매스이다. 하지만, 대부분의 연구 결과 폐활성 슬러지를 이용한 생물학적 수소생산율은 매우 낮다고 보고되고 있다. 본 연구에서는 폐활성 슬러지를 산, 알카리 처리, 기계적 처리, 열처리, 오존 처리, 초음파 처리 등의 전처리에 대한 효과를 살펴보았다. 전처리 실험결과, 폐활성 슬러지 내의 유기물질들은 가용화되었으며 $SCOD_{Cr}$값으로 약 14.6배의 증가를 보였다. 열처리된 혐기성 슬러지를 이용하여 폐활성 슬러지로부터 최적의 생물학적 수소생산을 위한 실험은 전처리 방법에 대한 효과 및 완충용액의 효과, 수소분압, 그리고 염소이온의 농도 등에 대하여 회분식 조건에서 살펴보았다. 실험결과 효과적인 전처리 방법 및 완충용액의 첨가, gas sparging 등의 방법에 의한 낮은 수소분압인 경우에 수소생산율이 0.52 mmol $H_2/g$-DS(Dried Solids)로 크게 증가함을 확인하였다.

• 분석과학
• /
• 제13권6호
• /
• pp.751-758
• /
• 2000

사용후핵연료에 미량 함유되어 있는 요오드를 정량하기 위하여 분리 및 회수를 위한 최적조건을 실험하였다. 사용후핵연료의 용해를 위하여 모의 사용후핵연료를 이용하였으며 용해과정에서 요오드가 휘발되지 않는 혼합산(질산:염산)의 최적 혼합비는 80:20 mol%이었으며 비휘발성 요오드의 생성을 촉진시키기 위하여 오존을 사용하였을 때 요오드의 회수율이 6회 평균 측정값이 9.6% 증가를 나타내었다. 사염화탄소에 의한 요오드 추출과정에서 ${IO_3}^-$를 $I_2$으로 환원시키기 위하여 $NH_2OH{\cdot}HCl$을 사용하였으며 요오드 환원에 적합한 용해용액의 산도는 2.5 M 그리고 $NH_2OH{\cdot}HCl$의 양은 $1.5{\times}10^{-3}mole$ 이상이었다. 분리된 요오드는 이온 크로마토그래피로 정량하였으며 이때 회수율은 $82.8{\pm}4.1%$로서 $^{131}I$를 추적자로 사용하여 보정하였다.