• Title/Summary/Keyword: Oxygen atmosphere

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Li2O and Li2CO3 Thin Film Growth by LPMOCVD (LPMOCVD에 의한 Li2O 및 Li2CO3 박막의 증착)

  • Jung, Sang-Chul;Ahn, Ho-Geun;Imaishi, Nobuyuki
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.225-230
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    • 1999
  • Low pressure metal organic chemical vapor deposition (LPMOCVD) of $Li_2O$ solid thin films from Li(DPM) in nitrogen-oxygen or argon-oxygen atmosphere was experimentally investigated by using a small hot wall tubular type reactor. XRD and ESCA analysis revealed that $Li_2CO_3$ film grew in nitrogen-oxygen atmosphere and $Li_2O$ grew in argon-oxygen atmosphere. The grown lithium oxide or carbonate reacted with silicon or silica base materials to produce silicates. The CVD model analysis by means of the well-known micro trench method and Monte Carlo simulation was not fully successful, but a set of data on gas phase reaction rate constant and surface reaction constant was obtained.

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Daytime and Nighttime Photochemical Reactions of the Pure Oxygen System (순수 산소계의 주간 및 야간 광화학반응)

  • Kwnag Sik Yun
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.249-261
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    • 1969
  • Studies of photochemical reactions of the pure oxygen atmosphere are made using reaction rate constants and atmospheric data available in the latest literature. The daytime and nighttime variations in atomic oxygen and ozone are computed, based on three different conditions: 1) photochemical equilibrium, 2) direct integrations of the rate equations with modifications and approximation to the equations, and 3) by numerical integrations. The departure from the photochemical equilibrium concentrations during day and nighttime are discussed by comparing the results obtaind from the three conditions.

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Modeling Fresh Produce Respiration and Designing Modified Atmosphere Package

  • Lee, Dong-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.13 no.3_4
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    • pp.113-120
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    • 2007
  • The method to characterize the fresh produce respiration was presented with possible application of modified atmosphere package design. Particularly the respiration model based on enzyme kinetics was introduced as function of oxygen and carbon dioxide concentrations. The method to estimate the equilibrated package atmosphere for any package conditions was presented by incorporation of $O_2$ and $CO_2$ permeabilities of the packaging film. Temperature dependences for fresh produce respiration and gas permeation were given by Arrhenius equation and then used to analyze the effect of temperature on the package atmosphere. An example analysis was presented for better understanding of the concept.

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RF-Sputted Vanadium Oxide Thin Films:Effect of Oxygen Partial Pressure on Structural and Electrochemical Properties

  • Park, Yong Jun;Park, Nam Gyu;Ryu, Gwang Seon;Jang, Sun Ho;Park, Sin Jong;Yun, Seon Mi;Kim, Dong Guk
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.1015-1018
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    • 2001
  • Vanadium oxide thin films with thickness of about 2000 $\AA$ have been prepared by radio frequency sputter deposition using a V2O5 target in a mixed argon and oxygen atmosphere with different Ar/O2 ratio ranging from 99/1 to 90/10. X-ray diffraction and X-ray absorption near edge structure spectroscopic studies show that the oxygen content higher than 5% crystallizes a stoichiometric V2O5 phase, while oxygen deficient phase is formed in the lower oxygen content. The oxygen content in the mixed Ar + O2 has a significant influence on electrochemical lithium insertion/deinsertion property. The discharge-charge capacity of vanadium oxide film increases with increasing the reactive oxygen content. The V2O5 film deposited at the Ar/O2 ratio of 90/10 exhibits high discharge capacity of 100 ${\mu}Ah/cm2-{\mu}m$ along with good cycle performance.

Effects of High Temperature Heat Treatment on the Microstructure and Superconducting Property of HTS Coated Conductor (Coated Conductor의 특성 및 미세조직에 미치는 고온열처리 영향)

  • Doh, Min-Ho;Hong, Gye-Won;Lee, Hee-Gyoun
    • Progress in Superconductivity
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    • v.11 no.1
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    • pp.1-7
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    • 2009
  • HTS coated conductor was heat treated at high temperatures below the melting points of silver and YBCO at different oxygen partial pressures. Current carrying capacity and microstructure were varied depending on the presence of silver protection layer. Critical current of coated conductor without silver protection layer was not changed when heat treatment was performed at $850^{\circ}C$ for 2 hr in an oxygen atmosphere. However, coated conductor with silver protection layer revealed abrupt drop of $I_c$ from 140A to 8A when heat treatment was performed at $800^{\circ}C$ for 2 hr in an oxygen atmosphere. Coated conductor with silver protection layer retained $70{\sim}80$ percent of its original $I_c$ when heat treatment was performed at $800^{\circ}C$ for 2 hr in an argon atmosphere containing 1000ppm oxygen. SEM and XRD observations showed the presence of interaction between YBCO and silver depending on the atmosphere of heat treatment. The reaction between YBCO superconductor and silver was accelerated at high oxygen partial pressure and resulted in the change in microstructure and decrease of critical current density even by the heat treatment performed at temperature much lower than the melting points of silver and YBCO.

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A Study on Stabilization and Mechanical Properties of Polyacrylonitrile-based Fiber with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴계 전구체섬유의 열안정화 및 그 물성에 관한 연구)

  • 신익기;이신희;박수민
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.76-85
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    • 2003
  • In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

Microaerophilies of campylobacters and related organisms

  • Han, Yeong-Hwan
    • The Microorganisms and Industry
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    • v.18 no.3
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    • pp.23-33
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    • 1992
  • The general characteristics of campylobacters and related organisms (e.g., species of the genera Helicobacter and Wolinella, Bacteroides ureolyticus, and Bacteroides gracilis) are as follows: slender, non-sporeforming, gram-negative, vibroid bacteria (helical- or spiral- shpaed; except that B. ureolyticus and B. gracilis are straight-rod), 0.2-0.5 .mu.m in width and 0.5 .mu.m in length. (Smibert, 1984; Penner, 1988). The species of genus Campylobacter and related organisms are chemoorganotrophs; however, they neither oxidize nor ferment carbohydrates and instead obtain energy from amino acids, the salts of tricarboxylic acids (TCA) cycle intermediates, the salts of organic acids, or, in some species, H$\_$2/. With regard to their oxygen responses for growth, they all are microaeophilic i.e., they are capable of oxygen-dependent growth (respiring with oxygen as a terminal electron acceptor) but can not grow in the presence of a level of oxygen equivalent to that present in an air atmosphere (21% oxygen). This review will take interests in how these microorganisms response to oxygen for growth and what repiratory types they have.

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Optimization of Binder Burnout for Reaction Bonded Si3N4 Substrate Fabrication by Tape Casting Method

  • Park, Ji Sook;Lee, Hwa Jun;Ryu, Sung Soo;Lee, Sung Min;Hwang, Hae Jin;Han, Yoon Soo
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.435-440
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    • 2015
  • It is a challenge from an industrial point of view to fabricate silicon nitride substrates with high thermal conductivity and good mechanical properties for power devices from high-purity Si scrap powder by means of thick film processes such as tape casting. We characterize the residual carbon and oxygen content after the binder burnout followed by nitridation as a function of the temperature in the temperature range of $300^{\circ}C-700^{\circ}C$ and the atmosphere in a green tape sample which consists of high-purity Si powder and polymer binders such as polyvinyl butyral and dioctyl phthalate. The optimum condition of binder burnout is suggested in terms of the binder removal temperature and atmosphere. If considering nitridation, the burnout of the organic binder in air compared to that in a nitrogen atmosphere could offer an advantage when fabricating reaction-bonded $Si_3N_4$ substrates for power devices to enable low carbon and oxygen contents in green tape samples.

The Effect of Co-culture and Oxygen Concentration on In Virto Fertilization of Follicular Oocytes in Korean Native Cattle (공배양 및 산소농도가 한우 난포란의 체외발생에 미치는 영향)

  • 이재관;윤준진;황성수;윤종택;김창근;정영채
    • Korean Journal of Animal Reproduction
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    • v.22 no.1
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    • pp.43-50
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    • 1998
  • The effect of oxygen tension on embryonic development in co-culture was evaluated from the standpoint of the reduction of dissolved oxygen concentration by the oxygen consumption of feeder cells. Three co-culture systems using bovine oviductal epitherial cells (BOEC), African green monkey kidney cells (Vero cells) or buffalo rat liver cells (BRLC) have been compared in terms of development of bovine embryos derived from oocytes matured and fertilized in vitro. Among the co-cultured embryo, Vero cells su, pp.rted the highest developmental rate (29%) and the other two showed the similar rates. When the co-cultures were incubated in three different oxygen tension such as 5, 10, 20% oxygen atmosphere, embryos co-cultured with Vero cells at 10%-O2 resulted in the highest percentage of development. From the measurement of oxygen consumption of feeder cells, BRLC consumed 1.38 10-10 mg-O2/min/cell which was higher than 0.94 10-10 and 0.26 10-10mg-O2/min/cell for Vero cells and BOEC, respectively. Based on the oxygen consumption data, the phenomena of optimum oxygen tension required in embryo development in vitro has been analyzed, and we suggested that gas phase oxygen concentration, oxygen consumption rate of feeder cells and the number of feeder cells should be considered for the design of optimal co-culture system for effective fertilization of embryos in vitro.

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The Effect of Seed on Top-seeded Melt-growth (TSMG) Processing of a RE-123 Superconductor

  • O, Yong-Taeg;Sung, Tae-Hyun;Jeong, Nyeon-Ho;Kim, Chan-Joong;Shin, Dong-Chan
    • Progress in Superconductivity
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    • v.9 no.1
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    • pp.115-118
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    • 2007
  • This study investigated the effects of different kinds of seed crystals with miscut angles and pretreatment on the characteristics of a RE-123 superconductor processed by a top-seeded melt-growth (TSMG) method. When the seed crystal was heat-treated in an oxygen atmosphere, the surface structure was cleaned removing hydroxide. When the seed crystal had a miscut angle, in addition, the surface structure showed a well defined hill-and-valley structure after heat-treatment. A better microstructure, with a well-distributed small RE-123 phase, was obtained using a high miscut angle after heat-treatment in an oxygen atmosphere. As a result of the microstructure improvement, the magnetic characteristics also improved. The experimental result can be explained by reduction of nucleation activation energy.

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