• Title/Summary/Keyword: Oxygen atmosphere

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MAGNETISM OF NANOPHASE IRON PARTICLES LASER EVAPORATED IN A CONTROLLED OXYGEN ATMOSPHERE

  • Turkki, T.;Jonsson, B.J.;Strom, V.;Medelius, H.;El-Shall, M.S.;Rao, K.V.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.745-748
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    • 1995
  • Magnetic nanoparticles of iron and iron oxide have been prepared in a modified upward thermal diffusion cloud chamber using pulsed laser evaporation. SEM/TEM studies of these particles reveal a size distribution with a mean diameter of about $60\;{\AA}$. FTIR spectrum measurements are used to investigate the difference in oxidation level between nanoparticles prepared at different partial oxygen pressures. The complex magnetic behaviour of these particles was studied using DC- and AC-susceptibility measurements. All samples exhibit superparamagnetism with blocking temperatures ranging from 50 K to above room temperature. The coercivity fields as well as the dependence of the blocking temperature on measuring frequency have been studied. magnetic anisotropy constants are found to be one order of magnitude higher than is known for the bulk values. The mean particle size estimated from the magnetic data is found to be in perfect agreement with the TEM observations.

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Effects of Plasma Treatment on the Reliability of a-IGZO TFT

  • Xin, Dongxu;Cui, Ziyang;Kim, Taeyong;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.2
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    • pp.85-89
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    • 2021
  • High reliability thin film transistors are important factors for next-generation displays. The reliability of transparent a-IGZO semiconductors is being actively studied for display applications. A plasma treatment can fill the oxygen vacancies in the channel layer and the channel layer/insulating layer interface so that the device can work stably under a bias voltage. This paper studies the effect of plasma treatment on the performance of a-IGZO TFT devices. The influence of different plasma gases on the electrical parameters of device and its working reliability are reviewed. The article mentions argon, fluorine, hydrogen and several ways of processing in the atmosphere. Among these methods, F (fluorine) plasma treatment can maximize equipment reliability. It is expected that the presented results will form a basis for further research to improve the reliability of a-IGZO TFT.

Correction Measures That Take Humidity into Account in Insulating Oil Test Measurement Results (습도를 고려한 절연유 시험 결과의 보정 방안 연구)

  • Wansu Kim;Jae-pil Roh;Seock-gu Kang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.5
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    • pp.541-546
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    • 2024
  • Climate conditions, especially transport and storage, are a very important factor in the process of sampling and testing insulation oil in the field. The samples of insulating oil exposed to the atmosphere affect the dielectric strength, total acid number and moisture test value by oxygen and high humidity environment and may also affect the results according to the criteria specified in each test. Therefore, reliable test values for insulating oil testing require consideration of the atmospheric environment of the test site, including oxygen and humidity. In this paper, each test was conducted on insulating oil exposed to various time and humidity environments, and the effect of the atmospheric environment on the test results was analyzed by comparing and analyzing with the first insulating oil.

MOLECULAR FORMATION IN SUNSPOTS

  • Lee, H.M.;Kim, D.W.;Yun, H.S.;Beebe, R.;Davis, R.
    • Journal of The Korean Astronomical Society
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    • v.14 no.1
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    • pp.19-35
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    • 1981
  • Calculations of molecular number densities as a function of optical depth in selected umbral, penumbral and photospheric models predict penumbral enhancement of diatomic molecules containing carbon atoms, strong umbral enhancement of oxides, and moderate umbral enhancement of hydrides. The role of CO formation in an oxygen rich atmosphere is discussed.

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Catalytic Breakdown of Graphene by Gold

  • Lee, Gyeong-Jae;Yang, Mi-Hyeon;Im, Gyu-Uk;Gang, Tae-Hui;Jeong, Seok-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.214-214
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    • 2012
  • It was reported that oxidative etching of graphene occurs at about $450-550^{\circ}C$ under oxygen atmosphere. We found catalytic breakdown of graphene by Au on the SiOx surface. This catalytic process was investigated using x-ray photoelectron spectroscopy and absorption spectroscopy at 4D PES beamline in PAL. Spectrosopic results suggest that the destruction of graphene is initiated by catalytic interaction between the oxidized gold and carbons in vacancy defects of graphene.

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Effects of Sputtering Conditions on Properties of $CaTiO_3 : Pr$ Phosphor thin Films (Sputtering 조건이 $CaTiO_3 : Pr$ 형광체 박막의 물성에 미치는 영향)

  • 정승묵;김영진;강승구;이기강
    • Korean Journal of Crystallography
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    • v.11 no.3
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    • pp.167-172
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    • 2000
  • CaTiO₃:Pr phosphor thin films were prepared on Si(100), ZnO/glass, Corning glass and ITO/glass by rf magnetron reactive sputtering. The effects of deposition parameters such as oxygen partial pressure, substrate temperature, and annealing conditions on crystallinity and compositional variation of the films were investigated. PL spectra of CaTiO₃:Pr phosphor thin films exhibited red regime peaking at 613 nm and enhanced PL intensity was observed for the film annealed in vacuum atmosphere as compared to the deposit annealed in N₂ environment.

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Oxidation Behavior of $\beta$-Sialon ($\beta$-Sialon 소결체의 산화 거동)

  • 박용갑;장병국
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.341-346
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    • 1989
  • In order to evaluate the oxidation behavior of $\beta$-Sialon, $\beta$-Sialon ceramics was prepared from Si3N4, Al2O3, AlN and Y2O3 system. The specimens were oxidized in an oxygen atmosphere at 1, 20$0^{\circ}C$ for 9days. Oxidation behavior was evaluated by weight gain oxidation process, surface roughness. Microscopy, EDX and X-ray diffraction analysis were also used for the evaluation. The weight and surface roughness ofoxidized specimens were increased with increasing the oxidation time. Oxidized products were mullite, $\alpha$-cristobalite, yttrium aluminum oxide and yttrium silicate oxide.

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Effect of Gas Atmosphere on In Vitro Development of Bovine Embryos Derived from In Vitro Fertilization (배양기내 GAS 분압의 조성이 소 체외수정란의 체외발육에 미치는 영향에 대한 연구)

  • 이원유;신태영;이병천;황우석
    • Journal of Embryo Transfer
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    • v.10 no.2
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    • pp.121-129
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    • 1995
  • To examine the critical effect of oxygen concentration on embryonic development, in vitro fertilized embryos were cultured in media(TCM199 vs. SOF) supplemented sera(1O% FCS vs. 10% HS) with and without bovine oviduct epithelial cells under two gas atmosphere (5% $CO_2$ in air vs. 5% $CO_2$, 5% $O_2$, 90% $N_2$). Oocytes, obtained from abattoir ovaries, were matured in EGF containing TCM199 medium co-cultured with BOEC for 24 hours, followed by exposure to frozen-thawed, heparin4reated spermatozoa in TALP for 30 hours. And then early embryos(1~2 cell) were cultured in both TCM199 and SOF supplemented with 10% FCS or 10% RS under 5% $CO_2$ in air or 5% COi, 5% $O_2$, 90% $N_2$. Development to morulae and blastocysts was recorded on days 7, after the start of in vitro fertilization. The developmental rates of in vitro fertilized embryos to morulae and blastocysts cultured in SOF with BOEC under 5% $CO_2$, 5% $O_2$, 90% $N_2$(24.4%) were significantly(p<0.05) higher than cultured in SOF with BOEC under 5% $CO_2$ in air(14.1%) at seven days after in vitro fertilization. When early bovine embryos were cultured in TCM 199 and SOF under two different gas atmosphere, there were no significant differences in the developmental rates to morulae and blastocysts between supplements of 10% FCS and 10% HS. The rates of development to morulae and blastocysts were significantly(p<0.01) higher in TCM 199 with BOEC(24.7%) than TCM199 without BOEC(10.9%) under 5% $CO_2$ in air, otherwise SOF without BOEC(36.4%) were significantly (p<0.05) higher than in SOF with BOEC (24.4%) under 5% $CO_2$, 5% $O_2$, 90% $N_2$. In summary, these experiments have proved that the culture system in SOF supplemented 10% ES is effective on in vitro development of early bovine embryos under 5% $CO_2$, 5% $O_2$, 90% $N_2$. In addition, it is effective to development of bovine embryos that TCM 199 should be co-cultured with BOEC and SOF should be cultured without somatic cells under two different gas atmosphere.

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The Sintering Behavior of the Hyperstoichiometric Uranium Dioxide in the Oxidative Atmosphere (약 산화성 분위기 중에서의 과산화성 2산화 우라늄의 소결에 관한 연구)

  • Jang Keu Han;Won Ku Park;Han Su Kim
    • Nuclear Engineering and Technology
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    • v.15 no.3
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    • pp.197-206
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    • 1983
  • The slightly hyperstoichiometric uranium dioxide, i.e. U $O_{2.005}$ and U $O_{2.01}$ within a range of the requirement for the use of a nuclear fuel, were sintered directly in an atmosphere of $CO_2$/CO mixture without any succeeding reduction process. The kinetics of sintering in the late stage were investigated for various O/U ratios. A sintering diagram, which show the relation of Temperature-Time-Density-Grain size, was established for each O/U ratio. Only by controlling the oxygen partial pressure in the sintering atmosphere, U $O_2$ pellet could be sintered very easily at low temperature 1050$^{\circ}$~120$0^{\circ}C$ with a density above 95% T.D. and average grain size above 7${\mu}{\textrm}{m}$. It was found that the rate of grain growth follows D=(Kt)$^{1}$4/ in the late stage of sintering. And the activation energies for grain growth in the final sintering stage were found to be 75, 64 and 62kca1/mo1 for U $O_{2.005}$, U $O_{2.01}$ and U $O_{2.10}$, respectively. Although no significant differences are obtained between the activation energies for different O/U ratios, the sinterability is enhanced considerably with increasing the oxygen partial pressure in the sintering atmosphere.tmosphere.

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Oceanographic Characteristics of the Japan Sea Proper Water I. Oceanographic Conditions of the Japan Sea and the Japan Sea Proper Water in Winter (동해고유수의 해양학적 특성 I. 겨울철 동해의 해황과 동해고유수)

  • 최용규;양성기
    • Journal of Environmental Science International
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    • v.3 no.4
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    • pp.317-332
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    • 1994
  • Based on the Results of Marine Meteorological and Oceanographical Observations (1966 ~ 1987), oceanographic conditions of the Japan Sea in winter was studied in relation to the Japan Sea Proper Water (JSPW). The mean and dispersion of the deep water above 1000 m depth are 0.26$\pm$0.2$^{\circ}C$ in temperature and 5.1$\pm$0.25 ml/h in oxygen. The mean and dispersion of the bottom water below 1000m depth are 0.07$\pm$$0.04^{\circ}C$ in temperature and 5.1$\pm$0.15ml/1 in oxygen. The distributions of the temperature and dissolved oxygen in the deep water above 1000m depth are ranged wider than 각one of the bottom water below 1000m depth in T-S and T-$ extrm{O}_2$ diagrams. The bottom water are showed more homogeneous and smaller variations than the deep water in the characteristics of water mass. The deep water above 1000m depth is active in contact with the atmosphere. The JSPW similar to the above characteristics is showed in the open ocean of the north of $40^{\circ}$30""N, west of $138^{\circ}$E. Therefore, the deep water is formed probably by the open-ocean convection.tion.

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