• Title/Summary/Keyword: Oxygen atmosphere

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Influence of Oxygen Annealing on Temperature Dependent Electrical Characteristics of Ga2O3/4H-SiC Heterojunction Diodes (산소 후열처리가 Ga2O3/4H-SiC 이종접합 다이오드의 온도에 따른 전기적 특성에 미치는 영향 분석)

  • Chung, Seung Hwan;Lee, Hyung Jin;Lee, Hee Jae;Byun, Dong Wook;Koo, Sang Mo
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.138-143
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    • 2022
  • We analyzed the influence of post-annealing on Ga2O3/n-type 4H-SiC heterojunction diode. Gallium oxide (Ga2O3) thin films were deposited by radio frequency (RF) sputtering. Post-deposition annealing at 950℃ in an Oxygen atmosphere was performed. The material properties of Ga2O3 and the electrical properties of the diodes were investigated. Atomic Force Microscopy (AFM), X-Ray Diffraction and Scanning Electron Microscope (SEM) images show a significant increase in the roughness and crystallinity of the O2-annealed films. After Oxygen annealing X-ray Photoelectron Spectroscopy (XPS) shows that the atomic ratio of oxygen increases which is related to a decrease in oxygen vacancy within the Ga2O3 film. The O2-annealed diodes exhibited higher on-current and lower leakage current. Moreover, the ideality factor, barrier height, and thermal activation energy were derived from the current-voltage curve by increasing the temperature from 298 - 434K.

Effect of the Concentration of Oxygen Vacancies on the Structural and Electrical Characteristics of MZO Thin Films (산소공공 농도에 따른 MZO 투명전도성 박막의 구조적 및 전기적 특성)

  • Jong Hyun Lee;Kyu Mann Lee
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.18-22
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    • 2023
  • We have investigated the effect of the concentration of oxygen vacancies on the characteristics of Mo-doped ZnO (MZO) thin films for the TCO (transparent conducting oxide). For this purpose, MZO thin films were deposited by RF magnetron sputtering at different substrate temperature from room temperature to 300℃. The electrical resistivity of the MZO films decreases with increasing substrate temperature up to 100℃ and then gradually increases at higher temperatures. To investigate the influences of the ambient gases, the flow rate of oxygen and hydrogen in argon was varied from 0.1 sccm to 0.5 sccm. The MZO thin films were preferentially oriented to the (002) direction, regardless of the ambient gases used. The electrical resistivity of the MZO thin films increased with increasing O2 flow rates, whereas the electrical resistivity decreased sharply under an Ar+H2 atmosphere and was nearly the same, regardless of the H2 flow rate used. As the oxygen vacancy concentration increases, the resistivity intended to decrease. In conclusion, Oxygen vacancy affects the MZO thin film's electrical characteristics. All the films showed an average transmittance of over 80% in the visible range.

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Effects of Additives and Atmospheres on the Grain Growth of TiO2 Ceramics (분위기와 첨가제가 TiO2 세라믹스의 입자성장에 미치는 영향)

  • 박정현;최헌진;박한수
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.390-398
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    • 1988
  • Effects of atmospheres and adidtives on the grain growth of TiO2 ceramics were investigated. In the range of 1300~140$0^{\circ}C$, grain growth was increased in CO2 as compared with O2 atmosphere and the grain boundary migration activation energy was lower than the diffusion activation energy of oxygen ion in TiO2. Also, in the case of addition of oxides, the grain growth was increased by oxides acting as a acceptor andinhibited by oxides acting as a donor. From the above results, when the oxygen vacancy concentration was increased, the intrinsic grain boundary mobility was increased and the pore drag force was decreased due to the rapid densification. Also it seems that the pore was migrated by the surface diffusion rather than lattice diffusion.

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Field Measurement Methods of Stream Reaeration Coefficient - Modified Gas Tracer Method - (Modified Gas Tracer Method를 이용한 하천의 재폭기계수)

  • 조영준;권순국
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1998.10a
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    • pp.547-551
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    • 1998
  • Reaeration coefficient is the physical absorption of oxygen from the atmosphere by water. It is the most important natural means by which a stream replaces the oxygen consumed in the biodegradation of organic wastes, and the rate constant describing this process is the reaeration coefficient, It. Reaeration coefficient is the dominant parameter affecting the use of water quality model. Therefore accurate estimation of the reaeration coefficient is essential for optimum water quality management. There is several method to estimate stream reaeration coefficient. In this study, it would be concluded that SI-peak method is of practical use when applied to small stream, and CRI method is adequate to large stream.

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A Case of Acute Poisoning with Dry Ice (드라이아이스에 의한 급성 중독 1례)

  • Hwang, Soon-Young;Jung, Jin-Hee;Eo, Eun-Kyung
    • Journal of The Korean Society of Clinical Toxicology
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    • v.5 no.1
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    • pp.43-45
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    • 2007
  • Carbon dioxide is the fourth most abundant gas in the earth's atmosphere, and it is widely used in the chemical industry. Solid carbon dioxide is commonly known as dry ice. At low concentration, carbon dioxide appears to have little toxicological effect. At higher concentrations, however, it can produce an increased respiratory rate, tachycardia, cardiac arrhythmia, loss of consciousness, convulsion, and even death. Management of carbon dioxide poisoning requires the immediate removal of an individual from the toxic environment and administration of oxygen. It is important to know the concentration of carbon dioxide to which a patient has been exposed. We report a case of acute poisoning from solid carbon dioxide in a patient presenting with drowsiness and diminished mental capacity when she arrived in the emergency department. She recovered completely after administration of oxygen with conservative treatment.

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A study on the c-axis orientation of ZnO thin film deposited on glass substrates (유리기판에 제작한 ZnO 박막의 c축 배향성에 관한 연구)

  • 고상춘;이종덕;송준태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.9-13
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    • 1995
  • In this paper, Zinc Oxide films, with a high degree of c-axis orientation, have been grown on glass substrates by a rf magnetron sputtering. The maximum crystal orientation was found to occur with substrate temperature 150$^{\circ}C$, input power 190W, oxygen rate 50%, target-substrate distance 55mm. It is proposed to achieve high-resistivity ZnO films by increasing the annealing temperature. The piezoelectric layers, preferred oriented with (002) perpendicular to the layer with 4.9$^{\circ}$, could be obtained by the annealing temperature 300$^{\circ}C$ in oxygen atmosphere. It is indicated that the relative permittivity is range from 8.9 to 9.8 in the frequency ranging from 10KHz to 5MHz.

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superconducting properties of Bi-2223 tapes with various heat treatment condition (열처리 온도 및 분위기 변화에 따른 Bi-2223 초전도 선재에서의 특성변화)

  • 하동우;이동훈;하홍수;오상수;김홍대;양주생;윤진국;최정규;권영길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.527-530
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    • 2002
  • A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. In this paper, initial annealing of Bi-2223/Ag wire to transform Bi-2212 orthorhombic from Bi-2212 tetragonal Precursor was investigated. This initial annealing step at low oxygen partial pressure were to transform Bi-2212 orthorhombic structure and to reduce the formation of second phases at superconducting wire. However Bi-2223 Phases were appeared at higher annealing temperature. Critical currents(Je) of Bi-2223/Ag tapes were sintered at low oxygen Partial pressure were higher than that of the wires sintered at atmosphere condition. In order to investigate the effect of rolling reduction ratio, Bi-2223/Ag HTS tapes were rolled with different reduction ratio. There were no clear difference of Je and filaments shape with various rolling reduction ratio.

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A Study on the Relationship between Oxidation and Sliding Wear Behavior of Ordered Fe-Al Intermetallic Alloys (규칙화된 Fe-Al 계 금속간 화합물의 산화특성과 미끄럼 마모거동과의 관계에 대한 연구)

  • 김용석
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.144-148
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    • 1999
  • The relationship between oxidation and sliding wear behavior of Fe-28 at%. Al alloys with B2 ordered structure has been investigated. Sliding wear tests of the alloys have been carried out under various environmental conditions using a pin-on-disk wear tester. The wear rate of the ordered alloys in an oxygen atmoshpere was found to be much lower than in an oxygen atmosphere showed that Fe2O oxides formed on the wearing surface. The oxide layer prevented direct contact of the two mating materials and therefore improved wear resistance of the Fe-Al intermetallic alloy. It was found that the surface Al2O3 oxide layer which provides good oxidation resistance and improved mechanical properties broke down easily and didnot function properly as an oxidation barrier.

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The Fabrication of Low Cost High Temperature Superconducting Tape (저비용 고온초전도 선재 제조 연구)

  • 한상철;성태현;한영희;이준성;이영우;정년호;김상준
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2000.02a
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    • pp.85-88
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    • 2000
  • Cu-free Bi-Sr-Ca-O powder mixtures were screen-printed on Cu tapes and heat-treated at 850-$870^{\circ}C$ for several minutes in air, oxygen, nitrogen and low oxygen pressure. Cu-free precursors were composed of Bi_{x}$SrCaO_{y}$ (x=1.2-2). In order to obtain the optimum heat-treatment condition, we studied on an effect of the precursor composition, the printing thickness and the heat-treatment atmosphere on the superconducting properties of Bi2212 films and the reaction mechanism of their rapid formation. Microstructures and phases of thick films were analyzed by optical microscope and XRD. The electric properties of superconducting films were examined by the four probe method. At heat-treatment temperature, the thick films were in a partially molten state by liquid reaction between CuO in the oxidized copper tape and the precursors which were printed on Cu tapes.

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A Study On The Influence of Atmospheres in Frictional Machining (摩찰加工 에 있어서의 분위기 영향 에 관한 硏究 제3보)

  • 손명환
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.6 no.3
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    • pp.261-270
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    • 1982
  • In the previously reported Part I and Part II, the experimental results in the frictional machining under liquid atmospheres to obtain the best surface roughness were showed. In the present study the frictional machining was carried out in gas atmospheres such as air, oxygen, dioxide carbon and argon, and in solid lubricant atmosphere of graphite powder. The results were compared with those of Part I and Part II. The material to be tested and machining conditions were made identical with Part I and Part II. The best surface roughness obtained in the above gas and solid lubricant atmospheres was worse than the liquid atmospheres but the contact pressure to minimize the surface roughness was considerably low. The best surface roughness in the present study was obtained in the atmospheres of dioxide carbon and graphite powder and the worst one was in oxygen and argon gas.