• Title/Summary/Keyword: Oxygen Isotope

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The Applicability of Stable Isotope Analyses on Sediments to Reconstruct Korean Paleoclimate (우리나라의 고기후 복원을 위한 습지 퇴적물의 안정동위원소 분석 가능성 연구)

  • Park, Jung-Jae
    • Journal of the Korean Geographical Society
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    • v.43 no.4
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    • pp.477-494
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    • 2008
  • Stable isotope analyses on lake or wetland sediments are useful to reconstruct paleoclimate. Organic and inorganic carbonates obtained from lake sediment are isotopically analyzed to get oxygen and carbon isotopic ratios. Oxygen isotope ratios can be used to quantitatively and qualitatively reconstruct paleo-temperature or humidity while carbon isotope ratios be used to reveal environmental changes around the lake or human impacts on the area. Peat mosses in peat bogs are nice samples for the carbon isotope analysis, which derives paleo-temperature and paleo-atmospheric $CO_2$ changes. In coastal area, the reconstruction of past sea-level is possible because terrestrial originated organic matter is carbon isotopically different from marine originated organic matter. Also, scientists can do research on Asian Monsoon based on the fact that $\delta^{13}C$ of C3 plants and C4 plants are consistently different each other and that they are distributed differently with respect to salinity. In Korea, paleoenvironmental studies using stable isotopes are not popular yet because of low academic interests on the methodology and difficulties of obtaining proper sediment samples. Interesting results can be produced to answer paleoenvironmental questions of Korea if scientists isotopically analyze sediment cores from a paleo-lake such as Hanon in Jeju island, peat bogs such as Mujechi-Neup and Yong-Neup, and coastal wetlands.

Sulfur Isotope Study on the Wolf River Batholith, Wisconsin in U.S.A. (미국 위스콘신주의 올프리버 저반에 대한 황동위원소 연구)

  • Sun-Joon Kim;Yuch-Ning Shieh
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.134-143
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    • 1995
  • Sulfur isotope compositions have been determined for the granitic and related rocks from the Wolf River Batholith, Wisconsin in U.S.A. Sulfur content and isotope composition of granitic rocks of the Wolf River Ratholith range from 30 to 140 ppm and from 1.1 to 6.5 permil respectively, and are considered to be magmatic. Sulfur content and isotope composition of the Penokean plutonic rocks, surrounding country rocks, range from 31to 381 ppm and from -1.7 to 7.2 permil respectively. The positive correlation observed between sulfur and oxygen isotope data of granitic rocks and the Penokean plutonic rocks may be due to the assimilation of the Penokean plutonic rocks by a primary magma of deep-crustal origin, or to mixing at depth, of a primary magma with another magma having higher ${\delta}^{18}O$ and ${\delta}^{34}S$.

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A Study on the Recharge Characteristics of Groundwater in the Jeju Samdasoo Watershed Using Stable Water Isotope Data (안정동위원소를 이용한 제주삼다수 유역의 지하수 함양 특성 연구)

  • Shin, Youngsung;Kim, Taehyeong;Moon, Suhyung;Yun, Seong-Taek;Moon, Dukchul;Han, Heejoo;Kang, Kyounggu
    • Journal of Soil and Groundwater Environment
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    • v.26 no.3
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    • pp.25-36
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    • 2021
  • This study evaluated monthly, seasonal and altitudinal changes of oxygen and hydrogen isotope compositions of wet precipitation samples (n = 238) that were collected for last four years from 7 altitudes (from 265 to 1,500 m above sea level) in the Jeju Samdasoo watershed at the southeastern part of Jeju island, in order to examine the recharge characteristics of groundwater that is pumped out for the production of the Samdasoo drinking mineral water. Precipitation samples showed a clear seasonal change of O-H isotopic composition as follow, due to the different air masses and relative humidity: 𝛿D = 7.3𝛿18O + 11.3 (R2 = 0.76) in the wet season (June to September), while 𝛿D = 7.9𝛿18O + 9.5 (R2 = 0.91) in the dry season (October to May). In contrast, the stable isotope compositions of groundwater were nearly constant throughout the year and did not show a distinct monthly or seasonal change, implying the well-mixing of infiltrated water during and after its recharge. An altitudinal effect of the oxygen isotope compositions of precipitation was also remarkable with the decrease of -0.19‰ (R2 = 0.91) with the elevation increase by 100 m. Based on the observed altitudinal change, the minimum altitude of groundwater recharge was estimated as 1,200 m above the sea level in the Jeju Samdasoo watershed.

The Estimation of Water Mass Mixing Ratio by Oxygen and Hydrogen Isotopes in the Southern Yellow Sea (황해 남부해역 해수에서 산소와 수소동위원소를 이용한 혼합비율 추정)

  • Kim, Kee-Hyun;Han, Jeong-Hee
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.357-362
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    • 2000
  • Stable isotope ratios of oxygen and hydrogen were investigated in southern Yellow Sea in August 1997. Salinity showed good positive correlation with ${\delta}^{18}$O and ${\delta}$. The correlation between ${\delta}^{18}$O and ${\delta}$D is good. From the relationship between these parameters, we obtained two lines of conclusion: 1) seawater of study area I in summer is a mixture of Changjiang Water and modified Kuroshio Water; 2) stable isotopes are very useful tracers in studying property and behavior of water masses in the study area. In case when water masses can not be easily distinguished by T-S analysis, the stable isotopes seem to be powerful tools for this purpose.

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The Impact of Abrupt Climate Change on the Marine Ecosystem in the East Sea

  • Shin, Im-Chul;Yi, Hi-Il;Chung, Hyo-Sang;Kwon, Won-Tae;Chun, Jong-Hwa;Oh, Hyun-Taek
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.1-7
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    • 2003
  • Environmental changes caused by the abrupt climatic change are one of the important issues in the scientific community. In the East Sea, abrupt climatic shift, called Younger Dryas, is identified. The age of the Younger Dryas cold episode occurred at 11.2 ka. Overall, changes in circulation and bottom water conditions occurred during the Younger Dryas cold episode in the study area. Especially, climatic transition from meltwater spike to the Younger Dryas cold episode is characterized by significant shifts of oxygen isotope values, the coiling ratios of Neogloboquadrina pachyderma, and the planktonic foraminifers abundances. The impact of abrupt climate change on the ecosystem is very significant. In the East Sea, the calcium carbonate secreting organism(foraminifers) is replaced by silicon dioxide secreting organisms(diatom, radiolarian) after the abrupt and severe cold climatic event. Based on the Doctrine of Uniformitarianism, at least climate change for the next 100 years would be severely influence on the marine ecosystem.

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Oxygen Isotope Profile and Age Determination of Venus Clam Mercenaria stimpsoni ( Bivalvia : Veneridae ) from the East Sea (동해산 뷔나스백합 ( Mercenaria stimpsoni ) 의 산소동위원소상과 연령추정)

  • Khim, Boo-Keun;Je, Jong-Geel;Han, Sang-Joon;Woo, Kyung-Sik;Park, Yong-Ahn
    • The Korean Journal of Malacology
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    • v.14 no.1
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    • pp.9-17
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    • 1998
  • 동해 연안에서 채취된 뷔나스백합(Mercenaria stimpsoni)의 연령과 성장률을 이매패의 표면에서 확인된 연륜과 이매패 각질에서 분석된 산소동위원소비의 성장에 따른 변화를 이용하여 비교하였다. 뷔나스백합의 산소동위원소상은 일련의 주기적인 변화를 뚜렷하게 보여주며 이러한 변화진폭은 이매패가 성장한 해수의 온도변화에 일차적으로 제어된다. 산소동위원소상의 주기화 연륜의 관계로부터 뷔나스백합의 연륜이 해마다 여름철에 형성됨을 보여준다. 해수 온도의 계절적 변화와 산소동위원소비에서 얻어진 예측 온도와의 비교로부터, 뷔나스백합은 겨울철에 성장이 멈추는 것으로 사료된다. 또한 산소도위원소비는 뷔나스백합의 성장에 따른 전형적인 노화현상을 보여준다. 따라서 이매패가 성장하는 해수의 물리화학적 조건에 의해 제어되는 산소동위원소비는 뷔나스백합의 경우 연령과 성장률을 측정하는 독립적인 시간 척도가 될 수 있다.

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Talc Mineralization in the Middle Ogcheon Metamorphic Belt (II) : Poongjeon Talc Deposit (중부옥천변성대의 활석광화작용에 관한 연구 (II) : 풍전활석광상을 중심으로)

  • Park, Hee-In;Lee, In Sung;Hur, Soon Do;Shin, Dong Bok
    • Economic and Environmental Geology
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    • v.30 no.6
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    • pp.543-551
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    • 1997
  • Poongjeon talc deposits is emplaced in dolomite and dolomitic limestone of the Cambro-Ordovician Samtaesan Formation. Ore in Poongjeon is low grade talc and the deposit has been known as the contact metasomatic or hydrothermal replacement type related to the intrusion of late Cretaceous granite in this area. X-ray diffraction, electron microprobe analysis, fluid inclusion and stable isotope analysis were utilized to examine the mineralogy of the ore and the origin of the ore fluid. The ore from Poongjeon mine mainly consists of talc and tremolite with minor amount of illite, vermiculite, smectite, and chlorite-vermiculite mixed layer. Occurrence of ore body indicates that the talc-tremolite ore was formed through the replacement by the $SiO_2$-rich hydrothermal fluid along the bedding and dike boundaries, or contact of amphibolite and basic dike with carbonate rocks. The temperature and pressure of the ore forming fluids at the time of the talc mineralization were estimated as $350^{\circ}C$ and 400 bar, respectively, based on the heating and freezing data of the fluid inclusions in quartz from talc-tremolite veins. During the talc-tremolite formation, fluids were divided into $CO_2$-enriched fluid and $CO_2$-poor fluid from $CO_2$ immiscibility (or effervescence). Oxygen isotope values (${\delta}^{18}O$) of the talc-tremolite fall within a range between 12.2 and 12.9‰. Hydrogen isotope values(${\delta}D$) of the ore range from -60 to -85‰ and $H_2O$ contents range from 2.0 to 3.4 wt.%. ${\delta}^{18}O$ and ${\delta}D$ values of talc ore indicate that the hydrothermal fluid involved in talc-tremolite formation was of igneous origin. Oxygen and hydrogen isotopic exchange between talc ore and the surface water was negligible after talc-tremolite ore formation.

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Measurement of oxygen isotope ratio using tunable diode laser absorption spectroscopy (다이오드 레이저 흡수분광법을 이용한 산소 동위원소의 성분비 측정)

  • Park, Sang-Eon;Jung, Do-Young;Kim, Jae-Woo;Ko, Kwang-Hoon;Im, Kwon;Jung, Eui-Chang;Kim, Chul-Joong
    • Korean Journal of Optics and Photonics
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    • v.15 no.1
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    • pp.1-5
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    • 2004
  • Tunable diode laser absorption spectroscopy was performed for analysis of the H$_2$$^{18}$ O/H$_2$$^{16}$ O isotope ratio of a water sample which was enriched by the membrane distillation method. In order to improve the signal-to-noise ratio, the wavelength modulation spectroscopic method was used with a lock-in amplifier. The fringe noise could be suppressed by using the FFT (Fast Fourier Transform) lowpass filter and the optimization of the modulation depth of the laser frequency. The maximum deviation of $\delta$-value was measured to be$\pm$4$\textperthousand$.

Nitrate Contamination of Confined Groundwaters: Application of Nitrogen, Oxygen, and Hydrogen Isotopes (피압대수층 지하수내 질소함유 원인연구: 질소, 산소, 수소동위원소 적용)

  • 추창오;이병대;조병욱;성익환;지세정
    • The Journal of Engineering Geology
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    • v.12 no.3
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    • pp.285-294
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    • 2002
  • The origin of nitrate in confined groundwater was studied using oxygen ($\delta$180), hydrogen ($\delta$D), and nitrogen ($\delta$15N) stable isotopes, along with chemical data of NO3-N. We analyzed groundwaters from more than sixty manufactories producing natural mineral waters around the country During the period of 1998-2001, an average value of nitrate was fair]y low (0.95 mg/$\ell$), however, groundwaters from six sites showed more than 2 mg/$\ell$ of nitrate. The stable isotope data of the groundwaters are -8.3~-11 $\textperthousand$ $\delta$8O, -60~-75 $\textperthousand$ $\delta$D, which lies in an average range of the groundwaters. The nitrogen isotope data with -11.8~-5.1$\textperthousand$ $\delta$15N suggest that manure, organic nitrate, and fertilizers can not be the origin of nitrate in the goundwaters.