• Title/Summary/Keyword: Oxidizing gas

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The Effects of CIF$_3$and F$_2$on the Flammability Limit of H$_2$ (H$_2$의 연소한계에 미치는 F$_2$와 CIF$_3$의 영향)

  • ;H.Ohtani;Y.Uehara
    • Journal of the Korean Society of Safety
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    • v.9 no.3
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    • pp.53-59
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    • 1994
  • Hydrogen(H$_2$) is used in the semiconductor industries, and some oxidizing gases such as fluoride(F$_2$) and chlorine trifluoride(CIF$_3$) are also used. As F$_2$and CIF$_3$are highly oxidizing gases, it were supposed to react vigorously with H$_2$. In this study, the flammability limit of F$_2$/$H_2$/Ar and CIF$_3$/$H_2$/Ar mixtures were investigated experimentally. As a result, it was found that the diluted F$_2$gas could be spontaneously ignited as compared to CIF$_3$mixture gas while being mixed with the diluted H$_2$gas. However, CIF$_3$diluted gas was not able to ignite spontaneously except for an electric spark. And the combustion characteristics and reaction kinetics were shown at the different diluted gases by the flammability diagram analyses between the F$_2$/$H_2$/Ar and CIF$_3$/$H_2$/Ar.

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Evaluation of Oxidation Stability for Diesel Engine Oil by Hot-Tube Oxidation Test (Hot-Tube Oxidation Test에 의한 디젤엔진오일의 산화안정성 평가)

  • 정근우;조원오;김영운;서인옥;임수진
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.175-180
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    • 1998
  • This paper describes evaluation of oxidation stability for diesel engine oils by Hot-tube oxidation tester at high temperature. Evaluation was rated by visual inspection of lacquer in capillary glass tube and TAN determination of used oil. Air, NO$_2$-air and SO$_2$-air mixed gases were used as oxidizing gas. One oil which has low oxidation stability is selected and reformulated by addition of some additives such as antioxidant, detergent and disperant to improve oxidation stability. As a results of reformulation, antioxidant and detergent was effective for improvement of high temperture oxidation stability on diesel engine oil.

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Effects of Combustion Characteristics of the Burners for Non-Oxidizing Direct Fired Furnaces on the Oxidization of the Surface of Steel Plate (무산화 직화로 버너의 연소특성이 강재표면의 산화에 미치는 영향)

  • Park, Heung Soo;Riu, Kap Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.3
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    • pp.330-341
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    • 1999
  • An experimental study for the two types of burners used in the non-oxidizing direct fired furnaces of the heat treatment process for the cold rolled plate has been carried out to investigate the combustion characteristics and the oxidization of the surface of steel plate. A steep temperature gradient and entrainment of residual oxygen were found near the heating surface in the flame of the nozzle mixing burner which has strong swirl velocity component. It was concluded that the elimination of the residual oxygen and the increase of the temperature of combustion gas on the heating surface are needed to enhance the performance of the burners for application to the non-oxidizing direct fired furnaces.

Isolation and Characteristics of Novel Ammonia Oxidizing Bacteria Brevundimonas diminuta (암모니아산화세균 Brevundimonas diminuta의 분리 및 암모니아 산화 특성)

  • Kwon, Hyuk-Ku;Jung, Joon-Oh
    • Journal of Environmental Health Sciences
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    • v.33 no.4
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    • pp.293-298
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    • 2007
  • The microorganism for ammonia gas removal was isolated from composting product. This was identified as Brevundimonas diminuta by morphological, biochemical characteristics study and 16S rDNA sequence analysis. Optimal incubation temperature for cell growth and oxidizing ability of $NH_4-N$ was $30^{\circ}C$ and optimal initial pH was 7. Glucose affected the growth of cell and the removal of $NH4^+$. The growth rate of the isolates were increased when grown in the presence of 0.05-1%(w/v) glucose in the selective medium and lurker increases in glucose concentration to 2% caused significant decreases in the cell growth and oxidizing ability of $NH4^+$.

The Study on Synthesis Gas Characteristics Following Different Injection Condition of Oxidizing Agent Through Simulation of Underground Coal Gasification (지중 석탄가스화 공정 시뮬레이션을 통한 산화제 주입조건에 따른 합성가스 특성에 대한 연구)

  • Jang, Dong-Ha;Yoon, Sang-Phil;Kim, Hyung-Taek;Kim, Jeong-Gyoo;Cho, Won-Jun;Ju, Woo-Sung;Lee, Jin-Wook;Lee, Chan
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.28-36
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    • 2013
  • The underground coal which is buried in the ground will have a lot of attention to overcome energy crisis as an energy resources standpoint. Many studies of underground coal gasification have been also conducted because of its advantage which does not require mining. In this study, the simulation of underground coal gasification process was carried out with Aspen Plus. This study was executed by Rock Mountain 1 Underground Coal Gasification project in the United States in the late 1980s as a reference. Sensitivity analysis proceeded to investigate synthesis gas characteristics following different injection condition of oxidizing agent. The underground coal gasification model has been implemented. That is divided into drying, pyrolysis, char gasification and the simulation results was confirmed by the production gas flow, yield of synthesis gas and amount of gasified carbon from results of the actual experimental data.

Metal Corrosion Mechanism by Sulfate-reducing and Iron-oxidizing Bacteria in Saline System and its Optimal Inactivation (염수계 철산화균 및 황환원균에 의한 금속 부식 및 최적 제어 방안)

  • Sung, Eun-Hae;Han, Ji-Sun;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.8
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    • pp.798-807
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    • 2008
  • Due to economic impairment derived from metal corrosion of pumping station installed around coastal area, it was needed for related cause-effect to be investigated for understanding practical corrosion behavior and providing proper control. This research was thus carried out to determine whether the microbe can influence on metal corrosion along with its control in the laboratory. For this study, groundwater was sampled from the underground pump station(i.e. I Gas Station) where corrosion was observed. Microbial diversity on the samples were then obtained by 16S rDNA methods. From this, microbial populations showing corrosion behaviors against metals were reported as Leptothrix sp.(Iron oxidizing) and Desulfovibrio sp.(Sulfur reducing) Iron oxidizing bacteria were dominantly participating in the corrosion of iron, while sulfate reducing bacteria were more preferably producing precipitate of iron. In case of galvanized steel and stainless steel, iron oxidizing bacteria not only enhanced the corrosion, but also generated its scale of precipitate. Sulfate reducing bacteria had zinc steel corroded greater extent than that of iron oxidizing bacteria. In the inactivation test, chlorine or UV exposure could efficiently control bacterial growth. However as the inactivation intensity being increased beyond a threshold level, corrosion rate was unlikely escalated due to augmented chemical effect. It is decided that microbial corrosion could be differently taken place depending upon type of microbes or materials, although they were highly correlated. It could be efficiently retarded by given disinfection practices.

Semiconductor-Type MEMS Gas Sensor for Real-Time Environmental Monitoring Applications

  • Moon, Seung Eon;Choi, Nak-Jin;Lee, Hyung-Kun;Lee, Jaewoo;Yang, Woo Seok
    • ETRI Journal
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    • v.35 no.4
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    • pp.617-624
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    • 2013
  • Low power consuming and highly responsive semiconductor-type microelectromechanical systems (MEMS) gas sensors are fabricated for real-time environmental monitoring applications. This subsystem is developed using a gas sensor module, a Bluetooth module, and a personal digital assistant (PDA) phone. The gas sensor module consists of a $NO_2$ or CO gas sensor and signal processing chips. The MEMS gas sensor is composed of a microheater, a sensing electrode, and sensing material. Metal oxide nanopowder is drop-coated onto a substrate using a microheater and integrated into the gas sensor module. The change in resistance of the metal oxide nanopowder from exposure to oxidizing or deoxidizing gases is utilized as the principle mechanism of this gas sensor operation. The variation detected in the gas sensor module is transferred to the PDA phone by way of the Bluetooth module.

Universal Indicators for Oil and Gas Prospecting Based on Bacterial Communities Shaped by Light-Hydrocarbon Microseepage in China

  • Deng, Chunping;Yu, Xuejian;Yang, Jinshui;Li, Baozhen;Sun, Weilin;Yuan, Hongli
    • Journal of Microbiology and Biotechnology
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    • v.26 no.7
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    • pp.1320-1332
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    • 2016
  • Light hydrocarbons accumulated in subsurface soil by long-term microseepage could favor the anomalous growth of indigenous hydrocarbon-oxidizing microorganisms, which could be crucial indicators of underlying petroleum reservoirs. Here, Illumina MiSeq sequencing of the 16S rRNA gene was conducted to determine the bacterial community structures in soil samples collected from three typical oil and gas fields at different locations in China. Incubation with n-butane at the laboratory scale was performed to confirm the presence of "universal microbes" in light-hydrocarbon microseepage ecosystems. The results indicated significantly higher bacterial diversity in next-to-well samples compared with background samples at two of the three sites, which were notably different to oil-contaminated environments. Variation partitioning analysis showed that the bacterial community structures above the oil and gas fields at the scale of the present study were shaped mainly by environmental parameters, and geographic location was able to explain only 7.05% of the variation independently. The linear discriminant analysis effect size method revealed that the oil and gas fields significantly favored the growth of Mycobacterium, Flavobacterium, and Pseudomonas, as well as other related bacteria. The relative abundance of Mycobacterium and Pseudomonas increased notably after n-butane cultivation, which highlighted their potential as biomarkers of underlying oil deposits. This work contributes to a broader perspective on the bacterial community structures shaped by long-term light-hydrocarbon microseepage and proposes relatively universal indicators, providing an additional resource for the improvement of microbial prospecting of oil and gas.

Synthesis of Ceria Nanosphere by Ultrasonic Spray Pyrolysis

  • Kim, Jong-Young;Kim, Ung-Soo;Cho, Woo-Seok
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.249-252
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    • 2009
  • Nanocrystalline ceria particles were prepared by using the ultrasonic spray pyrolysis method. The prepared ceria particles were found to be spherical and non-agglomerated by the SEM and TEM analyses. It was found that carrier gas influences the size and morphology. It was found that the air stream of carrier gas results in porous agglomerated structure of ceria abrasives, whereas solid nano-sphere can be obtained in a more oxidizing atmosphere.

A Study on the Detection Behavior of Chlorine Dioxide on Metal Oxide Sensors (금속산화물센서의 이산화염소 가스에 대한 감지거동에 관한 연구)

  • Yu, Joon-Boo;Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.29 no.3
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    • pp.211-214
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    • 2020
  • Chlorine dioxide is very effective gas for sterilization or disinfection (in manufacturing), and does not produce harmful by-products after use. However, if its concentration exceeds 10 %, it become explosive and cannot be compressed or stored. Therefore, it is necessary to measure its concentration. In this study, the concentration of chlorine dioxide with a high oxidizing strength was measured using a metal oxide sensor. The sensor was a commercially available TGS series from Figaro. The sensitivity of the sensor was inversely proportional to a low concentration of chlorine dioxide gas below 6 ppm and returned to the initial resistance at about 6 ppm. When the gas concentration reached multiples of 10 ppm, resistance of the sensor increased to several megaohms.