• 제목/요약/키워드: Oxide additive

검색결과 219건 처리시간 0.029초

Removal of Cu(II) ions by Alginate/Carbon Nanotube/Maghemite Composite Magnetic Beads

  • Jeon, Son-Yeo;Yun, Ju-Mi;Lee, Young-Seak;Kim, Hyung-Il
    • Carbon letters
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    • 제11권2호
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    • pp.117-121
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    • 2010
  • The composites of alginate, carbon nanotube, and iron(III) oxide were prepared for the removal of heavy metal in aqueous pollutant. Both alginate and carbon nanotube were used as an adsorbent material and iron oxide was introduced for the easy recovery after removal of heavy metal to eliminate the secondary pollution. The morphology of composites was investigated by FE-SEM showing the carbon nanotubes coated with alginate and the iron oxide dispersed in the alginate matrix. The ferromagnetic properties of composites were shown by including iron(III) oxide additive. The copper ion removal was investigated with ICP AES. The copper ion removal efficiency increased greatly over 60% by using alginate-carbon nanotube composites.

가압소결한 질화규소의 산화거동에 미치는 소결 첨가제의 영향 (Effect of Sintering Additives on the Oxidation Behavior of Hot Pressed Silicon Nitride)

  • 최헌진;김영욱;이준근
    • 한국세라믹학회지
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    • 제31권7호
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    • pp.777-783
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    • 1994
  • Oxidation behavior of hot-pressed silicon nitride ceramics with various sintering additives has been investigated. The weight gain of each specimens has shown in the range of 0.11 mg/$\textrm{cm}^2$ ~3.4 mg/$\textrm{cm}^2$ at 140$0^{\circ}C$ for 192 h and eleven compositions have shown good oxidation resistance with the weight gain below 0.5 mg/$\textrm{cm}^2$. The oxidation rate has been shown to obey the parabolic rate law and the oxidized surface has consisted of $\alpha$-cristobalite and M2Si2O7 or MSiO3 (M=rare earth or transition metals) phase. The oxidation rate of each specimens has related to the eutectic temperature between additive oxide and SiO2, and ionic radius of additive oxides, respectively. From the above results, it could be concluded that the oxidation behavior of hot pressed silicon nitride is dominated by the high temperature properties of grain boundary glassy phase and the high temperature properties of grain boundary glassy phase are affected by the ionic radius of additive oxides.

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Geometry variation for as-grown carbon coils under the minimized sulfur additive condition

  • Lee, Seok-Hee;Kim, Sung-Hoon
    • 한국결정성장학회지
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    • 제22권5호
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    • pp.213-217
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    • 2012
  • Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ additive in cyclic modulation manner, the dominant formation of the nanosized carbon coils could be achieved with maintaining the minimized sulfur additive amount. The geometry variation of the as-grown carbon coils, such as linear type, microsized coil type, wavelike nanosized coil type, and nanosized coil type, were investigated according to the different cyclic modulation manner of $SF_6$ flow. $SF_6$ gas incorporation develops the coil-type geometry. Furthermore, the higher flow rate of $SF_6$ gas increased the amount of the nanosized carbon coils. The slightly increased etching ability by $SF_6$ addition seems to be the cause for these results.

Praseodymium계 ZnO 바리스터의 제조 및 미세구조 연구 (Zinc Oxide Varistors with Praseodymium Oxide)

  • 소진중;한세원;김형식;조한구;김인성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1342-1344
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    • 1997
  • Zinc oxide varistors which contain rare earth metal oxides have been developed. These Varistors are widely used for low voltage surge-protection devices and high voltage arresters for electric power stations. The characteristics of varistors with praseodymium oxide as a principal additive are discussed. A two-phase microstructure with an intergranular phase between the ZnO grains.

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Ti-6Al-4V 합금 기지 위에 FGM 방식으로 적층제조 된 Inconel 718의 접합 특성 분석 (Joint Properties of Inconel 718 Additive Manufactured on Ti-6Al-4V by FGM method)

  • 박찬웅;박진웅;정기채;이세환;김성훈;김정한
    • 한국분말재료학회지
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    • 제28권5호
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    • pp.417-422
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    • 2021
  • In the present work, Inconel 718 alloy is additively manufactured on the Ti-6Al-4V alloy, and a functionally graded material is built between Inconel 718 and Ti-6Al-4V alloys. The vanadium interlayer is applied to prevent the formation of detrimental intermetallic compounds between Ti-6Al-4V and Inconel 718 by direct joining. The additive manufacturing of Inconel 718 alloy is performed by changing the laser power and scan speed. The microstructures of the joint interface are characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and micro X-ray diffraction. Additive manufacturing is successfully performed by changing the energy input. The micro Vickers hardness of the additive manufactured Inconel 718 dramatically increased owing to the presence of the Cr-oxide phase, which is formed by the difference in energy input.

Mn - Zn 페라이트의 전.자기적 물성에 미치는 공정변수의 영향 고찰 (The Study on the Effect of Processing Parameters on the Electromagnetic Properties of Mn-Zn Ferrites)

  • 황진현;신명승;한영호
    • 한국자기학회지
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    • 제7권2호
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    • pp.69-75
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    • 1997
  • Mn-Zn 페라이트의 소결에 영향을 주는 산화물 첨가제와 자기이방성 상수( $K_{1}$)값이 zero가 되는 온도, $T_{spm}$를 결정해주는 산소분압을 변화시켜가며 전력손실, 미세구조, 초기투자율, 소결밀도, 온도에 따른 초기투자율의 변화를 관찰하였다. 산화물 첨가계는 초기투자율과 소결밀도를 증가시켰으며 동시에 낮은 전력손실을 나타내었다. 이러한 첨가제들은 입계에 석출되는 것으로 $T_{spm}$$T_{c}$(큐리온도)와 같은 자기적 성질을 변화시키지 않았다. 온도에 따른 초기투자율 변화는 냉각시 산소분압이 증가함에 따라 $T_{spm}$이 높은 온도로 이동함이 관찰되었다. 또한 냉각시 산소분압조절 만으로는 승온과 소결시 결정된 페라이트의 치밀화가 완전히 보정되지 못함도 확인되었다.확인되었다.

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인 흡착용 마그네타이트 합성 시 알칼리 종류 및 농도가 공침 입자크기에 미치는 영향 (Effects of alkali species and concentration on the size distribution of the co-precipitated magnetite particles used for phosphate adsorption)

  • 이민형;;남해욱;김윤중;최영균
    • 상하수도학회지
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    • 제30권4호
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    • pp.409-415
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    • 2016
  • Magnetite particles were synthesized by co-precipitation of water-soluble 밀 스케일-derived precursor by various concentrations of (0.5, 0.67, 1, 2 N) NaOH and (0.6, 0.8, 1.2, 2.4 N) $NH_4OH$. It is theoretically known that as the concentration of the alkaline additive used in iron oxide synthesis increases, the particle size distribution of that iron oxide decreases. This trend was observed in both kind of alkaline additive used, NaOH and $NH_4OH$. In addition, the magnetite synthesized in NaOH showed a relatively smaller particle size distribution than magnetite synthesized in $NH_4OH$. Crystalline phase of the synthesized magnetite were determined by X-ray diffraction spectroscopy(XRD). The particles were then used as an adsorbent for phosphate(P) removal. Phosphorus adsorption was found to be more efficient in NaOH-based synthesized magnetite than the $NH_4OH$-based magnetite.

2차원 층상구조를 갖는 소결조제와 이를 활용한 세륨산화물 소결성 향상 (Sintering agents with 2-dimensional layered structure and the enhancement of sinterability of cerium oxide using them)

  • 박지영;오재명;박희정
    • 한국결정성장학회지
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    • 제29권1호
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    • pp.1-5
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    • 2019
  • 산화물을 포함한 세라믹 재료의 물성은 소재 치밀도에 크게 영향을 받는다. 따라서 소재 치밀도를 높이기 위한 다양한 노력들이 진행되어왔다. 이중 많이 사용되는 전략으로 재료 소결 시 소결조제를 첨가하는 것이다. 기존의 소결조제는 3차원 구조를 갖는 구형의 분말이었다. 본 연구에서는 차별화 전략으로 세륨산화물의 소결 밀도를 높이기 위해 2차원 층상구조를 갖는 소결조제를 첨가하였다. 실제로 2차원 층상구조의 조결조제에 의해 소결밀도가 증가되는 것을 확인할 수 있었다. 2차원 층상구조 소재로 초나노 두께(~1 nm)를 갖는 $TiO_x$$MnO_x$ 나노쉬트가 이용되었다.

Stabilizing Li2O-based Cathode/Electrolyte Interfaces through Succinonitrile Addition

  • Myeong Jun Joo;Yong Joon Park
    • Journal of Electrochemical Science and Technology
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    • 제14권3호
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    • pp.231-242
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    • 2023
  • Li2O-based cathodes utilizing oxide-peroxide conversion are innovative next-generation cathodes that have the potential to surpass the capacity of current commercial cathodes. However, these cathodes are exposed to severe cathode-electrolyte side reactions owing to the formation of highly reactive superoxides (Ox-, 1 ≤ x < 2) from O2- ions in the Li2O structure during charging. Succinonitrile (SN) has been used as a stabilizer at the cathode/electrolyte interface to mitigate cathode-electrolyte side reactions. SN forms a protective layer through decomposition during cycling, potentially reducing unwanted side reactions at the interface. In this study, a composite of Li2O and Ni-embedded reduced graphene oxide (LNGO) was used as the Li2O-based cathode. The addition of SN effectively thinned the interfacial layer formed during cycling. The presence of a N-derived layer resulting from the decomposition of SN was observed after cycling, potentially suppressing the formation of undesirable reaction products and the growth of the interfacial layer. The cell with the SN additive exhibited an enhanced electrochemical performance, including increased usable capacity and improved cyclic performance. The results confirm that incorporating the SN additive effectively stabilizes the cathode-electrolyte interface in Li2O-based cathodes.