• Title/Summary/Keyword: Oxidation of carbon

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Transparent carbon nanotube field emission devices for field emission display and lamp

  • Cho, You-Suk;Lee, Se-Min;Park, Hee-Yong;Lee, Sun-Hee;An, Myung-Chan;Jeong, Se-Young;Kim, Do-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1233-1234
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    • 2006
  • A simple new method to fabricate transparent carbon nanotube field emission devices was developed. The highly graphitized single wall carbon nanotubes were attached on Sn/ITO glass by arc discharge method. Post heat treatments below the deformation temperature of soda-lime glass guaranteed a good mechanical adhesion and electrical contact of the nanotubes. The Sn layer was oxidized below $400^{\circ}C$ and became transparent. As increasing the oxidation temperatures, the emission properties became stable and life time of emitter has been increased.

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A Study on the Catalytic Oxidation Reaction of Carbon Monoxide with Nickel Oxide (NiO 촉매에 의한 CO 산화반응에 관한 연구)

  • Jae Shi Choi;Keu Hong Kim
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.241-247
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    • 1969
  • The catalytic reaction between carbon monoxide and oxygen was investigated with the various nickel oxide catalysts at different partial pressures of carbon monoxide and oxygen and at reaction temperatures in the region of 120$^{circ}$to 250$^{circ}C$. The reaction has the highest rate with the nickel oxide catalyst which is sintered at low temperature. A reaction mechanism to explain the data is derived. From the Arrhenius equation, the activation energies in the region of experimental temperatures are found to be from 5.49 to 9.15 kcal/mole. The concentration of excess oxygen in the nickel oxide seems to vary according to the sintering temperatures and periods and is the controlling factor in determining the type of kinetics followed by the catalytic reaction.

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Thermal Oxidative Purification of Detonation Nanodiamond in a Gas-Solid Fluidized Bed Reactor

  • Lee, Jae Hoon;Youn, Yong Suk;Lee, Dong Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.738-751
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    • 2018
  • The effect of the reaction temperature and reaction time on the thermal oxidative purification quality of detonation nanodiamond (NDsoot) was investigated in a gas-solid fluidized bed reactor of a $0.10m-ID{\times}1.0m$-high stainless steel column with zirconia beads ($d_{SV}=99.2{\mu}m$). The carbon conversion increased with increasing the reaction temperature; however, when the reaction temperature was greater than 773 K, the carbon conversion did not increase. The content of $sp^3$-hybridized carbon at the reaction temperature of 703 K barely changed when the reaction time was more than 30 minutes, but at 773 K, the content decreased as preferred. At 703 K, the purification quality increased with the increasing reaction time; however, at 773 K, the purification quality increased up to 30 minutes and then decreased rapidly.

The utilization of acetate for the growth and the respiration in Dunaliella tertiolecta.―Enzymes of the tricarboxylic acid cycle and glyoxylate pathway (Dunaliella tertiolecta에 의한 acetate의 이용 -TCA cycle과 glyoxylate pathway의 활성 조사-)

  • 권영명
    • Journal of Plant Biology
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    • v.16 no.1_2
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    • pp.6-11
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    • 1973
  • The utilization of acetate by Dunaliella tertiolecta was examined, and the detections and assays of the enzymes of the tricarboxylic acid cycle and the glyoxylate pathway were described. Acetate could not be utilized as a sole carbon source for the growth. The carboxyl carbon of acetate was incorporated more rapidly into CO2 than the methyl carbon. It was identified that malate, succinate, citrate and etc., were accumulated whne [U-14C] acetate was supplied to the cell free homogenate. The following enzyme activities were measured; acetothiokinase, isocitrate dehydrogenase, fumarase, malate dehydrogenase and aconitase. Though isocitratase, malate synthetase, succinate dehydrogenase and oxoglutarate dehydrogenase could not be detected, 14C from succinate was easily contributed to CO2 and cell component. The evidence suggested that the glyoxylate pathway was not operative and showed that the TCA cycle was the all important pathway in the oxidation of acetate to CO2 in Dunaliella.

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Detection of Toxic Heavy Metal, Co(II) Trace via Voltammetry with Semiconductor Microelectrodes

  • Ly, Suw Young;Lee, Chang Hyun;Koo, Jae Mo
    • Toxicological Research
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    • v.33 no.2
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    • pp.135-140
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    • 2017
  • The cobalt (Co(II)) ion is a main component of alloys and considered to be carcinogenic, especially due to the carcinogenic and toxicological effects in the aquatic environment. The toxic trace of the Co(II) detection was conducted using the infrared photodiode electrode (IPDE) using a working electrode, via the cyclic and square-wave anodic stripping voltammetry. The results indicated a sensitive oxidation peak current of Co(II) on the IPDE. Under the optimal conditions, the common-type glassy carbon, the metal platinum, the carbon paste, and the carbon fiber microelectrode were compared with the IPDE in the electrolyte using the standard Co(II). The IPDE was found to be far superior to the others.

Reduction of unburned carbon derived from coal-fired power plant by changing operating conditions (운전조건병경에 의한 미분탄화력의 미연분 저감)

  • Park, Ho-Young;Kim, Young-Ju;Yu, Guen-Sil;Kim, Chun-Kun;Kim, Dong-Hun
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.299-303
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    • 2006
  • From the analysis of fly ash, which contains unburned carbon, collected from the coal-fired Yong Hung power station, most particles are turned out to be hollow cenosphere and agglomerated soot particles. The sooting potential from six coals used in the plant were investigated with CPD model. The results show that the higher potential presented to Peabody, Arthur, Shenhua coals rather than other coals. It is necessary to measure the coal flow rates at each coal feeding pipe for four burner levels since they affect the extent of mixing of soot with oxidant, in turn, the oxidation rate of soot particles. The unbalance in coal flow rate was found in several coal pipes. We successfully reduced unburned carbon in ash by increasing the excess air and changing the SOFA yaw angle.

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Noncovalent Titania Wrapping of Single-Walled Carbon Nanotubes for Environmentally Stable Transparent Conductive Thin Films (환경신뢰성이 확보된 투명전도성 필름을 위한 비공유 걸합에 의한 단일벽 탄소나노튜브의 $TiO_2$ 코팅)

  • Han, Joong-Tark;Kim, Jun-Suk;Jeong, Hae-Deuk;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.20-20
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    • 2010
  • We present a simple process for the fabrication of high performance transparent conducting films that contain single-walled carbon nanotubes (SWCNTs) noncovalently coated with an ultrathin titania layer. The hydrophobic interactions between nanotube surfaces and the acetylacetone (acac) ligands used to stabilize the $TiO_2$ precursor provide an interesting alternative method for noncovalently coating the SWCNTs with a titania layer. The ultrathin titania layer on SWCNTs prevented the oxidation of functionalized SWCNTs at high temperatures, and protected against water molecule absorption.

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Noncovalent Titania Wrapping of Single-Walled Carbon Nanotubes for Environmentally Stable Transparent Conductive Thin Films (환경신뢰성이 확보된 투명전도성 필름을 위한 비공유 결합에 의한 단일벽 탄소나노튜브의 $TiO_2$ 코팅)

  • Han, Joong-Tark;Kim, Jun-Suk;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.279-279
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    • 2010
  • We present a simple process for the fabrication of high performance transparent conducting films that contain single-walled carbon nanotubes (SWCNTs) noncovalently coated with an ultrathin titania layer. The hydrophobic interactions between nanotube surfaces and the acetylacetone (acac) ligands used to stabilize the $TiO_2$ precursor provide an interesting alternative method for noncovalently coating the SWCNTs with a titania layer. The ultrathin titania layer on SWCNTs prevented the oxidation of functionalized SWCNTs at high temperatures, and protected against water molecule absorption.

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Radiolabeled 2D graphitic nanomaterials and their possibility for molecular imaging applications

  • Kang, Seok Min;Kim, Chul Hee;Kim, Dong Wook
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.4 no.2
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    • pp.115-120
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    • 2018
  • In recent years, many researchers have attempted to make use of 2D nanoparticles as molecular imaging probes since extensive investigations proved that 2D nanoparticles in the body tends to accumulate certain lesions by enhanced permeability and retention (EPR) effect. For example, graphene and carbon nitride which have high surface area and modifiable properties showed good biocompatibility and targetability when it used as imaging probes. However, poor dispersibility in physiological mediums and its uncontrolled size limited its usage in bio-application. Therefore, oxidation process and mechanical exfoliation have been developed for overcoming these problems. In this paper, we highlight the several major methods to synthesize biocompatible 2D nanomaterials like graphene and carbon nitride especially for molecular imaging study including positron emission tomography (PET).

Densification of Cf/SiC Composite Using PIP with Adding of Cyclohexene (Cyclohexene을 첨가한 PIP 공정 사용 Cf/SiC 복합재의 고밀도화)

  • Bae, Jin-Cheol;Cho, Kwang-Youn;Kim, Jun-Il;Im, Dong-Won;Park, Jong-Kyu;Lee, Man-Young;Lee, Jae-Yeol
    • Composites Research
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    • v.26 no.5
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    • pp.322-327
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    • 2013
  • Carbon fiber-reinforced SiC matrix composites have good oxidation resistance and thermal shock resistance. These properties have allowed the composites to be applied to high-temperature structures. In this study, $C_f/SiC$ composites were fabricated via precursor infiltration and pyrolysis (PIP) process, including liquid phase infiltration and chemical vapor curing using cyclohexene. The final $C_f/SiC$ composites, which have gone through the PIP process five times, showed a density of $1.79g/cm^3$, as compared to a density of $0.43g/cm^3$ for pre-densified bare carbon fiber preform. As for the oxidation resistance characteristics, the weight of $C_f/SiC$ composite was maintained at 81% at $1400^{\circ}C$ in air for 6 hours. Chemical vapor curing (CVC) using cyclohexene has shown to be an effective method to achieve high densification, leading to increased oxidation resistance.