• Title/Summary/Keyword: Oxidation efficiency

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The Sediment Transport Pattern from a Large Industrial Complex to an Enclosed Bay

  • Kwon, Young-Tack;Lee, Chan-Won
    • Environmental Engineering Research
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    • v.13 no.2
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    • pp.69-72
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    • 2008
  • The movement of sediments in the stream crossing a large industrial complex to the mouth of Masan Bay was monitored for eight years. Sediment samples were seasonally collected in the period of $1992{\sim}1997$ and $2001{\sim}2002$. The heavy metal content of sediment was found to be higher at dry season with the peak on February and significantly decreased at rainy season. Metals content in stream sediments were rapidly decreased by large precipitation events in rainy season because the contaminants in the upstream sediments were transported to the dredged area of Masan Bay where is a typical enclosed bay in Korea. The increasing and decreasing tendency of heavy metals in sediment was repeatedly observed for six consecutive years. The heavy metals assessment of stream sediment provide us the information about the pollutant source, transport pattern and control strategy along the industrial complex. It was strongly suggested that the transportable stream sediments of an industrial area should be controlled as one of the important strategies to restore and manage the enclosed bay. Combined wastewaters have been collected and treated in a publicly owned treatment works (POTW) after industrial wastewater treatment at each location of industries since 1994. A field study was conducted to investigate the pollutant removal efficiency and performance of contact oxidation system installed and operated in two locations in the stream. The stream sediment quality was improved since then, and as a consequence the habitat of the estuary has been restored.

Process Optimization for the Laser Cutting of Cold Rolled STS Sheet (냉연 스테인리스강판의 레이저 절단 특성)

  • 이기호;김기철
    • Journal of Welding and Joining
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    • v.14 no.5
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    • pp.59-68
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    • 1996
  • This study was aimed to characterize the laser cutting process for the cold rolled stainless steel sheet. The principal process parameters of the cutting process were applied to both the continuous wave form and the pulsed wave form for the laser output mode. The laser-oxygen cutting process and the laser-nitrogen cutting process were also considered to characterize the quality and efficiency of the cutting process. The laser-oxygen cutting process revealed the better productivity than the laser-nitrogen cutting process, since the laser energy and the exothermic oxidation energy exerted on the laser-oxygen cutting process simultaneously during the entire cutting process. However, the straightness of the cutting section, which was considered as the most important factors, was inferior to that of the laser-nitrogen cutting process due to the formation of chromum oxide on the cutting surface. Frequency and duration of the pulsed wave form act as the main factors for the better quality, When the frequency increased from 100 Hz to 200 Hz and the duty increased from 20% to 40%, the quality factors such as the height of dross and the surface roughness were improved remarkably. The increase in the frequency from 200 Hz to 300 Hz, on the other hand, revealed the less effective in the cutting quality.

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Development of an Environmentally Friendly Sewage Disposal Model for Agricultural and Fishing Village Areas (자연친화형 농어촌 하수처리장 모델개발)

  • Chung, Dong-Yang
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.2 no.1
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    • pp.10-19
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    • 1999
  • In 1991, the ministry of Gov't. Administration and Home Affairs set up a minimum of one sewage disposal plant in each province. By 1995, 264 models of the capillary infiltration method were set up in 331(78%) villages and the contact oxidation method was set up in 52 places. Since the Gov't. sent a letter to each responsible officer across the country stating their disapproval of the capillary infiltration method, the environmentally friendly sewage disposal system has not been diffused. The current model(mechanical sewage disposal) being used, in agricultural and fishing villages, costs too much for maintenance and operation(\50,000 per capita per year). In particular, because of the difference in sewage characteristics of agricultural and fishing villages from urban sewage, the efficiency of the disposal system is very low. Also, because of the growing need for more disposal plants, the Gov't. is looking for cheaper alternatives. This study has analyzed 2 kinds of sewage disposal. The first is used widely in agricultural and fishing villages in Germany. The second is used widely in similar areas of Korea. It has intended to analyze the characteristics, merits and defects of the sewage disposal water plants and pebbles model which is used widely in Germany and developed compatibly for Korea.

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Removal of low concentration organic matter by reverse osmosis membranes in ultrapure water production process (초순수 제조 공정에서 역삼투 막의 저농도 유기물 제거)

  • Lee, Hongju;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.391-396
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    • 2014
  • Ultrapure water (UPW) is water containing nothing but water molecule ($H_2O$). The use of UPW is increasing in many industries such as the thermal and nuclear power plants, petrochemical plants, and semiconductor manufacturers. In order to produce UPW, several unit processes such as ion exchange, reverse osmosis (RO), ultraviolet (UV) oxidation should be efficiently arranged. In particular, RO process should remove not only ions but also low molecular weight (LMW) organic matters in UPW production system. But, the LMW organic matter removal data of RO membranes provided by manufacturers does not seem to be reasonable because they tested the removal in high concentration conditions like 1,000 ppm of isopropyl alcohol (IPA, MW=60.1). In this study, bench-scale experiments were carried out using 4-inches RO modules. IPA was used as a model LMW organic matter with low concentration conditions less than 1 ppm as total organic carbon (TOC). As a result, the IPA removal data by manufacturers turned out to be trustable because the effect of feed concentration on the IPA removal was negligble while the IPA removal efficiency became higher at higher permeate flux.

Effects of Alkali Concentration on Fiber Characteristics of SwBKP during Alkali Treatment in Cosolvent System (알칼리 공용매 팽윤처리 시 알칼리 농도가 SwBKP 섬유 특성에 미치는 영향)

  • Seo, Ji-Hye;Choi, Kyoung-Hwa;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.37-43
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    • 2016
  • Various mechanical and chemical pretreatment methods including alkali treatment, pre-beating, enzyme treatment and oxidation treatment have been used to reduce the production energy of the microfibrillated cellulose (MFC). Among them, alkali swelling can be helpful to reduce the energy consumption because the internal bonding between fibrils could be weakened. In this study, dimethyl sulfoxide (DMSO) was used as a cosolvent to improve alkali pretreatment efficiency and the effects of NaOH concentration during NaOH-DMSO swelling on changes in fiber characteristics of softwood bleached kraft pulp (SwBKP) were elucidated. For alkali treatment in H2O-DMSO solvents, fiber length were decreased with increasing NaOH concentration while fiber width, curl and WRV were increased. WRV began to increase at 8% NaOH solution. In addition, above 8% concentration of NaOH, crystalline structure of pulp fibers converted from cellulose II to cellulose III by DMSO cosolvent. Comparing the previous results with this study, it was shown that DMSO cosolvent could promote swelling of pulp fibers and thus reduce NaOH concentration for the maximum swelling of fibers.

Inductively Coupled Plasma discharge characteristic of Ne, Ar, Kr mixed gas (Ne, Ar, Kr 혼합가스에서의 유도결합형 플라즈마 방전특성)

  • Her, In-Sung;Choi, Yong-Sung;Lee, Chong-Chan;Jeong, Young-Il;Park, Dae-Hee
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.11a
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    • pp.9-12
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    • 2004
  • Recently, the environmental problem has received considerable attention. so, many lamps have been developing for environmental requirement and energy efficiency. also, at glow discharge lamp researchers try to reduce energy spending that is power saving lamp. this kind requirement agree with strong points of electrodeless fluorescent lamp has received to now lighting sauce. At low pressure as mTorr I.C.P make high density plasma easily, is good to maintain discharge, has high ionization and does not have failing lighting and losing ability of electron radiation by oxidation and volatilization of electrodes, because this tape does not have electrodes This point of I.C.P can use at electrodeless fluorescent lamp in this study ICP display elements and Ar, Ne, Kr are researched for optical characteristic. each gas is looked into optical characteristic, also mixed gases is experiment for optical characteristic.

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Heterologous Expression of Lignin Peroxidase H2 in Escherichia coli: In Vitro Refolding and Activation

  • Lee, Dong-Ho;Kim, Dong-Hyun
    • BMB Reports
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    • v.32 no.5
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    • pp.486-491
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    • 1999
  • An engineered cDNA from Phanerochaete chrysosporium encoding both the mature and propeptide-sequence regions of lignin peroxidase H2 (Lip H2) was overexpressed in Escherichia coli BL21 (DE3) to evaluate its catalytic characteristics and potential application as a pollution scavenger. All expressed proteins were aggregated in an inactive inclusion body, which might be due to inherent disulfide bonds. Active enzyme was obtained by refolding with glutathione-mediated oxidation in refolding solution containing $Ca^{2+}$, heme, and urea. Propeptide-sequence region was not processed as evidenced by N-terminal sequence analysis. Recombinant Lip H2 (rLip H2) had the same physical properties of the native protein but differed in the $K_{cat}$. Catalytic efficiency ($k_{cat}/K_m$) of rLip H2 was slightly higher than that of the native enzyme. In order to express an active protein, fusion systems with thioredoxin or Dsb A, which have disulfide isomerase activity, were used. The fused proteins expressed by the Dsb A fusion vector were aggregated, whereas half of the thioredoxin fusion proteins were recovered as a soluble form but still catalytically inactive. These results suggest that Lip H2 may not be expressed as an active enzyme in Escherichia coli although the activity can be recovered by in vitro refolding.

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Degradation of oxytetracycline by nano zero valent iron under UV-A irradiation: Chemical mechanism and kinetic

  • Hassanzadeh, Parisa;Ganjidoust, Hossein;Ayati, Bita
    • Advances in environmental research
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    • v.3 no.1
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    • pp.29-43
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    • 2014
  • Pharmaceutical wastewater effluents are well known for their difficult elimination by traditional biotreatment methods and their important contribution to environmental pollution due to its fluctuating and recalcitrant nature. OTC is one of the nonbiodegradable antibiotics that makes antibiotic-resistant, so it can make be high risk for environment. NZVI can be a good choice for removal of OTC in aqueous solution. Response surface methodology (RSM) was used to optimize the amounts of NZVI and OTC to be used at pH 3 and under 200 W, UV-A irradiation. The responses were removal percent of absorption at 290 and 348 nm, TOC and COD of OTC. In the optimum condition, Linear model was performed 155 ppm of OTC were removed by 1000 ppm NZVI after 6.5 hours and the removal efficiency of absorption at 290 and 348 nm, TOC and COD were 87, 95, 85 and 89 percent, respectively. In the similar process, there is no organic compound after 14 hours. The parameters ORP, DO and pH were investigated for 6:30 hours to study the type of NZVI reaction in process. In the beginning of reaction, oxidation was the dominant reaction after 3 hours, photocatalytic reaction was remarkable. The mechanism of OTC degradation is proposed by HPLC/ESI-MS and four by products were found. Also the rate constants (first order kinetic chain reaction model) were 0.0099, 0.0021, 0.0010, 0.0049 and $0.0074min^{-1}$, respectively.

Synthesis of Nickel Nanoparticle-adsorbed Aluminum Powders for Energetic Applications (니켈 나노입자가 흡착된 에너제틱용 고반응성 알루미늄 분말 합성)

  • Kim, Dong Won;Kwon, Gu Hyun;Kim, Kyung Tae
    • Journal of Powder Materials
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    • v.24 no.3
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    • pp.242-247
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    • 2017
  • In this study, the electroless nickel plating method has been investigated for the coating of Ni nanoparticles onto fine Al powder as promising energetic materials. The adsorption of nickel nanoparticles onto the surface of Al powders has been studied by varying various process parameters, namely, the amounts of reducing agent, complexing agent, and pH-controller. The size of nickel nanoparticles synthesized in the process has been optimized to approximately 200 nm and they have been adsorbed on the Al powder. TGA results clearly show that the temperature at which oxidation of Al mainly occurs is lowered as the amount of Ni nanoparticles on the Al surface increases. Furthermore, the Ni-plated Al powders prepared for all conditions show improved exothermic reaction due to the self-propagating high-temperature synthesis (SHS) between Ni and Al. Therefore, Al powders fully coated by Ni nanoparticles show the highest exothermic reactivity: this demonstrates the efficiency of Ni coating in improving the energetic properties of Al powders.

Optimization of the Phosphorus Doped BSF Doping Profile and Formation Method for N-type Bifacial Solar Cells

  • Cui, Jian;Ahn, Shihyun;Balaji, Nagarajan;Park, Cheolmin;Yi, Junsin
    • Current Photovoltaic Research
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    • v.4 no.2
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    • pp.31-41
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    • 2016
  • n-type PERT (passivated emitter, rear totally diffused) bifacial solar cells with boron and phosphorus diffusion as p+ emitter and n+ BSF (back surface field) have attracted significant research interest recently. In this work, the influences of wafer thickness, bulk lifetime, emitter, BSF on the photovoltaic characteristics of solar cells are discussed. The performance of the solar cell is determined by using one-dimensional solar cell simulation software PC1D. The simulation results show that the key role of the BSF is to decrease the surface doping concentration reducing the recombination and thus, increasing the cell efficiency. A lightly phosphorus doped BSF (LD BSF) was experimentally optimized to get low surface dopant concentration for n type bifacial solar cells. Pre-oxidation combined with a multi-plateau drive-in, using limited source diffusion was carried out before pre-deposition. It could reduce the surface dopant concentration with minimal impact on the sheet resistance.