• Applied Chemistry for Engineering
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• v.24 no.6
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• pp.599-604
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• 2013

In this study, Ti added Mn-Cu mixed oxide catalysts were prepared by a co-precipitation method and used for the low temperature (< $200^{\circ}C$) selective catalytic reduction (SCR) of NOx with $NH_3$. Physicochemical properties of these catalysts were characterized by BET, XRD, XPS, and TPD. Mn-Cu mixed oxide catalysts were found to be amorphous with a large surface and they showed high SCR activity. Experimental results showed that the addition of $TiO_2$ to Mn-Cu oxide enhanced the SCR activity and $N_2$ selectivity. Ti addition led to the chemically adsorbed oxygen species that promoted the oxidation of NO to $NO_2$ and increased the number of $NH_3$ adsorbed-sites such as $Mn^{3+}$.

• Journal of Korean Society on Water Environment
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• v.32 no.5
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• pp.403-409
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• 2016

In this study, a TiO₂ nanotube was grown on a titanium plate by using anodic oxidation method for the evaluation of TiO₂ nanotube morphology. The TiO₂ nanotube was grown in an electrolyte containing ethylene glycol, 0.2 wt% of NH₄F and 2 vol% of H₂O. Applied voltage varied from 30 to 70 V and the morphology of the TiO₂ nanotube was observed. After anodization, a TiO₂ nanotube plate was immersed in 35℃ ethanol for 24 hours. Anatase and rutile crystal forms of TiO₂ nanoutbe were observed after annealing. 4-chrolobenzoic acid, a probe compound for OH radicals, was dissolved in H₂O in order to measure the OH radical. Liquid chromatography was used to check the concentration of the 4-chrolobenzoic acid. The OH radical generation by TiO₂ nanotube plate was proportionate to the length of the TiO₂ nanotube. Furthermore, when the number of TiO₂ nanotube plate increased, the OH radical generation increased as well.

• Journal of the Korean Society of Propulsion Engineers
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• v.6 no.1
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• pp.21-29
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• 2002

Hybrid propulsion systems provide many advantages in terms of stable operation and safety. However, classical hybrid rocket motors have lower fuel regression rate and combustion efficiency compared to solid propellant rocket motor. The recent research efforts are focused on the improvement of volume limitation and regression rate in the hybrid rocket engine. The present study has numerically investigated the combustion processes in the hybrid rocket engine. The turbulent combustion is represented by the eddy breakup model and Hiroyasu and Nagle and Strickland-Constable model are used for soot formation and soot oxidation. Radiative heat transfer is modeled by finite volume method. To reduce the uncertainties for convective heat transfer near solid fuel surface having strong blowing effect, the Low Reynolds number $\kappa-\varepsilon$ turbulent model is employed. Based on numerical results, the detailed discussion has been made for the turbulent combustion processes in the vortex hybrid rocket engine.

• Journal of the Korean Society of Food Science and Nutrition
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• v.12 no.2
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• pp.62-65
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• 1983

As a new practical method for preserving freshness of fish, partially frozen storage has been reported to be useful in terms of K-value, TBA value, sensory evaluation etc. In order to develop a storage procedure to be used in place of cooled or frozen storage for the preservation of precooked fish food, partial freezing for up to two to three weeks was examined using baked mackerel. The criteria for evaluation were made according to the changes in volatile basic nitrogen (VBN), thiobarbituric acid (TBA) value, viable bacterial number, pH, color difference and sensory evaluation in fish muscle. The changes in TBA value of baked muscle during storage at $-3^{\circ}C$ differed slightly from those obserbed during cooled ($5^{\circ}C$) and frozen storage ($-20^{\circ}C$). Partial frozen storage ($-3^{\circ}C$) was effective in prolong an induction period of lipid oxidation during early storage. VBN of baked muscle tends to increase slowly while pH value was decrease during storage and there was no observed significant differences among three different storage condition. Viable bacterial number of the baked mackerel muscle stored at $-3^{\circ}C$ showed significantly less than that stored at $5^{\circ}C$, and similar to that stored at $-20^{\circ}C$ (the levels of $10^2/g$). Judging from the results of sensory evaluation and experimental data, partial frozen storage at $-3^{\circ}C$ seems to be effective as means of short-period preserving baked mackerel.

• Journal of the Society of Disaster Information
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• v.18 no.3
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• pp.574-580
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• 2022

Purpose: As corn oil is semi-drying oil, it has more double bonds than non-drying oil and is easier to combine with oxygen. In addition, among the causes of spontaneous ignition, accidents caused by oil-soaked cloths due to oxidative heat are gradually increasing. Therefore, the purpose of this study is to understand the characteristics of spontaneous combustion according to the number of towels and the amount of corn oil at 65℃. Method: After setting the test temperature to 65℃, 25ml, 50ml, 75ml of corn oil per towel was sprayed. The central temperature of the sample rises above the set temperature. It was determined, and when the central temperature of the sample became similar to the set temperature, it was determined as non-igniting. Result: After evenly distributing 25ml of corn oil per towel, as a result of the experiment, 5 towels did not ignite, and 10 and 15 towels ignited. Also, as a result of an experiment using 50ml and 75ml of corn oil per towel, spontaneous ignition occurred when the number of towels was 5, 10, or 15 sheets. Conclusion: Even a small amount can cause a fire if the conditions for spontaneous ignition are met.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.49 no.3
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• pp.231-245
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• 2023

In the cosmetics industry, it is important to develop new materials for functional cosmetics such as whitening, wrinkles, anti-oxidation, and anti-aging, as well as technology to increase absorption when applied to the skin. Therefore, in this study, we tried to optimize the nanoemulsion formulation by utilizing response surface methodology (RSM), an experimental design method. A nanoemulsion was prepared by a high-pressure emulsification method using Glabridin as an active ingredient, and finally, the optimized skin absorption rate of the nanoemulsion was evaluated. Nanoemulsions were prepared by varying the surfactant content, cholesterol content, oil content, polyol content, high-pressure homogenization pressure, and cycling number of high-pressure homogenization as RSM factors. Among them, surfactant content, oil content, high-pressure homogenization pressure, and cycling number of high-pressure homogenization, which are factors that have the greatest influence on particle size, were used as independent variables, and particle size and skin absorption rate of nanoemulsion were used as response variables. A total of 29 experiments were conducted at random, including 5 repetitions of the center point, and the particle size and skin absorption of the prepared nanoemulsion were measured. Based on the results, the formulation with the minimum particle size and maximum skin absorption was optimized, and the surfactant content of 5.0 wt%, oil content of 2.0 wt%, high-pressure homogenization pressure of 1,000 bar, and the cycling number of high-pressure homogenization of 4 pass were derived as the optimal conditions. As the physical properties of the nanoemulsion prepared under optimal conditions, the particle size was 111.6 ± 0.2 nm, the PDI was 0.247 ± 0.014, and the zeta potential was -56.7 ± 1.2 mV. The skin absorption rate of the nanoemulsion was compared with emulsion as a control. As a result of the nanoemulsion and general emulsion skin absorption test, the cumulative absorption of the nanoemulsion was 79.53 ± 0.23%, and the cumulative absorption of the emulsion as a control was 66.54 ± 1.45% after 24 h, which was 13% higher than the emulsion.

• Journal of the Korean Society for Nondestructive Testing
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• v.32 no.4
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• pp.393-400
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• 2012

In recent years, nano-structured thin film systems are often applied in industries such as MEMS/NEMS device, optical coating, semiconductor or like this. Thin films are used for many and varied purpose to provide resistance to abrasion, erosion, corrosion, or high temperature oxidation and also to provide special magnetic or dielectric properties. Quite a number of articles to evaluate the characterization of thin film structure such as film density, film grain size, film elastic properties, and film/substrate interface condition were reported. Among them, the evaluation of film adhesive to substrate has been of great interest. In this study, we fabricated the polymeric thin film system with different adhesive conditions to evaluate the adhesive condition of the thin film. The nano-structured thin film system was fabricated by spin coating method. And then V(z) curve technique was applied to evaluate adhesive condition of the interface by measuring the surface acoustic wave(SAW) velocity by scanning acoustic microscope(SAM). Furthermore, a nano-scratch technique was applied to the systems to obtain correlations between the velocity of the SAW propagating within the system including the interface and the shear adhesive force. The results show a good correlation between the SAW velocities measured by acoustic spectroscope and the critical load measured by the nano-scratch test. Consequently, V(z) curve method showed potentials for characterizing the adhesive conditions at the interface by acoustic microscope.

• Herbal Formula Science
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• v.18 no.1
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• pp.57-77
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• 2010

Objective : This study reviews the recent trend of oriental medical prescription research. The data examined are the articles published in the Korean Journal of Oriental Medical Prescription from 1990 to 2009. Method : The data are retrieved through the internet database Oriental Medicine Advanced Searching Integrated System (OASIS) and the collection of the Korean Journal of Oriental Medical Prescription. The number of articles examined is 385, published in 25 volumes of the journal. This study examines the nature of the articles, research methods, subjects, and author information. Research subjects are sorted out by the OASIS key words for the articles published before 1999, and by key word indexes cited in the abstracts for the articles published sinceafter. Results : Among the 385 articles collected, 206 are research articles, 143 philological articles, 35 case studies, and 1 special contribution. A majority of research articles are experimental studies (199 articles or 96.6%), while clinical reports (5 articles or 2.43%), and others studies (2 articles) occupy a small portion. Most of experimental studies (183 articles or 91%) examine the effectiveness of certain prescriptions or treatments. Among the effectiveness studies, 114 articles (62.3%) employ in vivo experiment design, 52 articles (28.42%) in vitro experiments, and 17 articles (9.29%) both in vivo and in vitro experiments. In terms of research subject, the most frequently indexed key words are hepatotoxicity among diseases (9 articles), Bojungikgitang (Bu-Zhong-Yi-Qi-Tang) among prescriptions (10 articles), Buja (Acontii Tuber) among meteria medica (4 articles), immunity and anti-oxidation among efficacy terminology (6 articles each), and Donguibogam(東醫寶鑑) among references in the key words (25 articles). Universities are the main affiliation of authors (76.42%), followed by university hospitals (6.71%), non-academic research institutes (5.55%), local clinics (4.67), academic research institutes (2.81%), hospitals (2.38%), and others (1.44%). The most affiliated institute of the first and correspondent authors is Wonkwang University. In terms of authorship, co-authorship outnumbers sole-authorship by 82.08% to 17.92%. The proportion of authors of a single article is 63.54% which is near the author productivity distribution described by Lotka's law.

• The Journal of Korean Academy of Prosthodontics
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• v.36 no.6
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• pp.858-866
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• 1998

Soldering is the usual method used to correct an unstable fixed partial denture framework at patient's try-in; However, presoldering base metal alloys is technique-sensitve and results are unstable because it is difficult to maintain uniform heat distribution and to prevent oxidation of an alloy. A cast-joining technique has been developed by Weiss and Munyon for repair, correction and addition to base metal framework. This joining technique eliminates the problem with presoldering of non-precious frameworks. The object of this study was to 1) compare the relative flexure strength and the joining effectiveness of Ni-Cr-Be cast in two pieces and 'pre-soldered' versus in two pieces and 'cast-joined'. 2) determine the effect of increasing the number of retentive grooves on the face of the cast and 3) determine the effect of the relative matched position of groove patterns on flexure strength. The joining effectiveness can be expressed by the ratio of the mean flexure stress of soldered or cast-joined specimens to that of one-piece cast. Resin rods 3mm in diameter were used as pattern of specimens for one-piece casted, presoldered, and cast-joined groups. Cast-joined specimens had two different patterns of retentive grooves on the joined faces. Type A had cross-shaped grooves 1mm in depth. 0.6mm in width. Type B was the same except for the addition of one more retentive groove. In the experiment connecting cast-joined specimens, half of specimens with type A pattern had their patterns on the faces of paired casts matched with each other as mirror image. With the rest pairs, it was proceeded that one of paired casts turned 45 degrees so that the patterns crossed. Half of specimens with type B pattern also had the patterns matched as mirror image; However, here, one of paired casts turned 90 degrees with the other pairs. Retentive groove in this study lacked the intentional undercuts, in contrast with the suggestion of Weiss and Munyon. The specimens were subjected to four-point flexural loading in an Instron testing machine. The midspan flexural stress was calculated at the point of initial plastic strain as determined from a strip-chart recorder or at the point of failure if this occured at a lower stress level. Within the scope of this study, the following results were obtained. 1. The presoldered group showed flexural strength at least 2 times higher than the cast-joined groups. Its joining effectiveness was 82%. 2. In cast-joined groups, the flexural strength of joints with type B patterns exhibited 1.5 times that of joints with type A patterns. Joining effectivenesses were 38% for type B patterns, 25-26% for type A patterns. 3. The relative matched position of groove patterns did not have any significant effect on flexural strength of the cast-joined specimens with either type A patterns or type B patterns(p>.05).

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.692-699
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• 2013

In this study, isothermal (350, 375, 400, 425, 450, 500, $850^{\circ}C$) experiments were carried out using a custom-made thermobalance to analyze the thermal decomposition properties of refuse plastic fuel (RPF), which is to be used as a cofiring fuel with a sub-bituminous coal at commercial circulating fluidized bed (CFB) boiler in Korea. In isothermal pyrolysis results, no change in the reaction model was observed in the temperature range of $375{\sim}450^{\circ}C$ and it was revealed that the first order chemical reaction (F1) is the most suitable among 12 reaction models. The activation energy shows similar results irrespective of application of reaction model in that the activation energy was 39.44 kcal/mol and 36.96 kcal/mol when using Arrhenius equation and iso-conversional method ($0.5{\leq}X{\leq}0.9$) respectively. Mean-while, the devolatilization time ($t_{dev}$) according to particle size (d) of RPF could be expressed as $t_{dev}=10.38d^{2.88}$ at $850^{\circ}C$, operation temperature of CFB and for even distribution and oxidation of RPF in CFB boiler, we found that the relationship of average dispersion distance (x) and particle size was $x{\leq}1.58d^{1.44}$.