• Title/Summary/Keyword: Oxidation/reduction potential(ORP)

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Study on the Sediment Quality in Bottom Water (I) (수 저층의 저질 조사 (I) - 저질 조사의 중요성과 분석에 관하여 -)

  • Kim, Do-Hee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.1 s.28
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    • pp.93-102
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    • 2007
  • Particle materials sink in bottom and dissolved inorganic substances release from sediment and many kinds of materials continuously exchange in sediment and water column as well as transfer and transformation in sediment. The study of sediment quality means the state of sediment pollution relation of the water quality, sediment biota, materials fluxes between sediment and water column, transformation of materials in sediment is being important in recent. The state of sediment quality imply that the history of water pollution for long time, because the sediment quality does not change temporally. The sediment quality of bottom water can be used as a good indicator of pollution at present and in future. The major index of sediment qualities are the content of nutrients and hazard materials such as metals, Ignition Loss (IL), Total Sulfur (TS), Oxidation Reduction Potential (ORP), sediment COD, color, odor and the release of nutrients from sediment. However, there are some arguments between researchers about compare to estimation of sediment quality and sampling and analysis of sediment. In this study, I will introduce the method of sediment sampling, analyzing and estimating of the sediment pollution.

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Preparation of Ni-doped Gamma Alumina from Gibbsite and Its Characteristics (깁사이트로부터 니켈피착 감마알루미나의 제조 및 특성)

  • Lee, Hyun;Chung, In-Sung;Park, Hee-Chan
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1158-1164
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    • 1998
  • Aluminium sulfate solution was prepared by sulfuric acid treatment from gibbsite. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was precipitated from aluminium sulfate solution by adding it into ethylalcohol. From XRD analysis as-prepared $Al_2(SO_4)_3$ · $nH_2O$ was confirmed to have mixed-crystalization water(n=18, 16, 12, 6). The average water of crystalization calculated from thermogravimetry(TG) was 14.7. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was thermally decomposed and converted to $Al_2(SO_4)_3$ at $800^{\circ}C$, $\gamma-Al_2O_3$ at $900-1000^{\circ}C$, and $\alpha-Al_2O_3$ at $1200^{\circ}C$. Ni-doped $\gamma-Al_2O_3$, was synthesized from the slurry of as-prepared $\gamma-Al_2O_3$, with the ratio of [Ni]/[Al]=0.5. The reaction conditions of synthesis were determined as initial pH 9.0 and temperature $80^{\circ}C$ The basicity(pH) of slurry was controlled by using urea and $NH_4OH$ solution. Urea was also used for deposition-precipitation. For determining termination of reaction, the data acquisition was performed by oxidation reduction potential(ORP), conductivity and pH value in the process of reaction. Termination of the reaction was decided by observing the reaction steps and rapid decrease in conductivity. On the other hand, BET(Brunauer, Emmett and Teller) and thermal diffusity of Ni- doped $\gamma-Al_2O_3$, with various content of Ni were measured and compared. Thermal stability of Ni- doped $\gamma-Al_2O_3$ at $1250^{\circ}C$ was confirmed from BET and XRD analysis. The surface state of Ni-doped $\gamma-Al_2O_3$ was investigated by X-ray photoelectron spectroscopy(XPS). The binding energy at $Ni2P_{3/2}$ increased with increasing the formation of $NiAl_2O_4$ phase.

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Effect of Immersion Liquids on Quality Characteristics of Peeled Taro during Storage (박피 토란의 저장중 품질특성에 미치는 침지액의 영향)

  • Park, Kee-Jai;Lee, Ho-Joon;Kim, Jong-Hoon;Kwon, Ki-Hyun;Jeong, Jin-Woong
    • Korean Journal of Food Science and Technology
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    • v.38 no.6
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    • pp.742-750
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    • 2006
  • This study was carried out to investigate the efficacy of two kinds of electrolyzed water with added 0.5% (v/v) citron juice, SAEW-CJ[Strong Acidic Electrolyzed Water with added Citron Juice, pH 2.57, ORP (oxidation-reduction potential) 1,122 mV, HClO 23.05ppm] and LAEW-CJ (Low Alkaline Electrolyzed Water with added Citron Juice, pH 4.67, ORP 997mV, HClO 42.55mV) as storing liquid for peeled taro. During storage at $5^{\circ}C$ until 30 days, SAEW-CJ and LAEW-CJ inhibited the growth of microorganisms more effectively than 0.2% (w/v) APS (aluminium potassium sulfate) and 0.85% (w/v) NaCl did. Total phenolic contents, PRO (polyphenol oxidase) activity, color differences value (${\Delta}E$) and vitamin C contents of peeled taro stored in SAEW-CJ and LAEW-CJ were lower than those stored in 0.2% APS and 0.85% NaCl. The hardness decrement of peeled taro stored in LAEW-CJ was lower than that of the others. In addition, the contents of moisture, crude protein, crude ash, total sugars, and reducing sugars were gradually decreased during storage. However, no difference by peeling methods or immersion liquid was found.

Sulfur Dioxide, Mineral Contents and Physicochemical Properties Generated during Manufacture of Bamboo Salt (죽염 제조공정에 따른 이산화황, 미네랄 함량 및 이화학적 특성)

  • Kim, Hag-Lyeol;Lee, Seong-Jae;Lee, Jung-Hee;Kim, In-Cheol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.8
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    • pp.1248-1256
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    • 2014
  • The purpose of this study was to investigate the mechanisms of behind $SO_2$ formation and elevated cause of reducing power in purple bamboo salt (PBS) along with an analysis of physicochemical properties, content of sulfur compounds, oxidation reduction potential (ORP), mineral contents of salt type (MSS, mudflat solar salt; BS, bamboo salt), and addition of raw bamboo (RB). $SO_2$ content of 630 ppm was detected in PBS. $SO_2$ was not detected in MSS, BS, or RB, whereas $SO_2$ (782 ppm) from $K_2SO_4$ was detected after heating a NaCl, KCl, $MgCl_2$, $MgSO_4$, MgO, $CaCl_2$, $K_2SO_4$, and $FeSO_4$ with RB. $SO_2$ content of BS increased with baking time, and it originated from BSRB1 (13.88 ppm) to BSRB4 (109.13 ppm). $SO_3{^{2-}}$ originated only from MSSRB4 and BSRB2~BSRB4. Sulfate ion content decreased along with increasing $SO_2$ and sulfite ion contents. ORP increased with baking time of MSS and BS, and it was present at higher levels in BSRB4 (-211.40 mV) of BS than MSS. Insoluble content was higher in BS than MSS. Further, Ca, K, and Mg ion contents decreased in MSS and increased in BS with baking time. BSRB4 had 1.4 fold higher levels of Ca, 1.5 fold higher levels of Mg, and 1.8 fold higher levels of K than BS. Li, Al, Mn, Fe, and Sr in MSS as well as Al, Fe, and Ni in BS increased with baking time. Anions (Cl, $NO_3$, and Br) and heavy metals (Pb, Cd, Hg, and As) between MSS and BS were not significantly different. These results suggest that the reducing power of BS was due to $SO_2$ and sulfite ion. To increase the amounts of these compounds and reducing power, higher melting temperature and longer baking time are necessary along with BS, which is created by the addition of RB to roasted salt.

Bactericidal Activity of Strongly Acidic Electrolyzed Water on Various Vegetables and Kitchen Apparatus (채소 및 주방기구에 대한 강산성전해수의 살균효과)

  • Kim, Yun-Jung;Choi, Kyoo-Duck;Shin, Il-Shik
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.5
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    • pp.776-781
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    • 2010
  • The properties and bactericidal activities of strongly acidic electrolyzed water (SEW) against food-borne pathogenic bacteria, vegetables and kitchen apparatuses were investigated. The available chlorine concentration, pH and oxidation reduction potential (ORP) of SEW were $35{\pm}1.2\;ppm$, $2.3{\pm}0.2$, and $1,140{\pm}20.4\;mV$, respectively. Five strains of food-borne bacteria with initial cell number of 7.00 log CFU/mL were not detected except Bacillus cereus after treatment with SEW for 60 sec. The numbers of Bacillus cereus were reduced to 2.08{\pm}1.00 log CFU/mL at the same condition. In vegetables, SEW treatment after washing strongly in alkalic electrolyzed water (AEW) showed better bactericidal effects than SEW only. The viable cell on stainless steel bowl ($3.86{\pm}2.49\;\log\;CFU/100\;cm^2$) and cup for water ($2.40{\pm}1.80\;\log\;CFU/100\;cm^2$) were not detected by SEW treatment (35 ppm of available chlorine concentration) for 30 sec, but survival of more than 1.00 log CFU/$100\;cm^2$ of viable cell was shown by washing of sodium hypochlorite solution at the same condition. On the other hand, the coliform group bacteria ($5.08{\pm}4.00\;CFU/100\;cm^2$) were detected on rubber globe only, and more than 2.00 log CFU/$100\;cm^2$ of viable cell and coliform group bacteria on it survived, though it was washed with flowing SEW for 30 sec.

Assessment of Adsorption Capacity of Mushroom Compost in AMD Treatment Systems (광산배수 자연정화시설 내 버섯퇴비의 중금속 흡착능력 평가)

  • Yong, Bo-Young;Cho, Dong-Wan;Jeong, Jin-Woong;Lim, Gil-Jae;Ji, Sang-Woo;Ahn, Joo-Sung;Song, Ho-Cheol
    • Economic and Environmental Geology
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    • v.43 no.1
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    • pp.13-20
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    • 2010
  • Acid mine drainage (AMD) from abandoned mine sites typically has low pH and contains high level of various heavy metals, aggravating ground- and surface water qualities and neighboring environments. This study investigated removal of heavy metals in a biological treatment system, mainly focusing on the removal by adsorption on a substrate material. Bench-scale batch experiments were performed with a mushroom compost to evaluate the adsorption characteristics of heavy metals leached out from a mine tailing sample and the role of SRB in the overall removal process. In addition, adsorption experiments were perform using an artificial AMD sample containing $Cd^{2+}$, $Cu^{2+}$, $Pb^{2+}$ and $Zn^{2+}$ to assess adsorption capacity of the mushroom compost. The results indicated Mn leached out from mine tailing was not subject to microbial stabilization or adsorption onto mushroom compost while microbially mediated stabilization played an important role in the removal of Zn. Fe leaching significantly increased in the presence of microbes as compared to autoclaved samples, and this was attributed to dissolution of Fe minerals in the mine tailing in a response to the depletion of $Fe^{3+}$ by iron reduction bacteria. Measurement of oxidation reduction potential (ORP) and pH indicated the reactive mixture maintained reducing condition and moderate pH during the reaction. The results of the adsorption experiments involving artificial AMD sample indicated adsorption removal efficiency was greater than 90% at pH 6 condition, but it decreased at pH 3 condition.

Study on Reduction of Microbial Contamination on Daruma by Combination Treatment of Strong Acidic Hypochlorous Water and Ultrasonic Waves (강산성차아염소산수와 초음파를 병용처리한 조미오징어 반가공품의 미생물 오염도 저감화에 관한 연구)

  • Chung, Won-Hee;Ko, Jun-Soo;Shin, Il-Shik
    • Journal of Food Hygiene and Safety
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    • v.30 no.2
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    • pp.166-172
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    • 2015
  • This study was performed to develop treatment method for reducing microbial contamination on Daruma (a semi-processed product of seasoned and dried squid) by combination of strong acidic hypochlorous water (SAHW) and ultrasonic waves (UW). The available chlorine concentration, oxidation reduction potential (ORP) and pH of SAHW were $69.67{\pm}0.58ppm$, $1071.33{\pm}4.16mV$ and 2.79, respectively. The 1.49 log CFU/g of viable cell count and 1.32 log CFU/g of Staphylococcus aureus was reduced, and Escherichia coli was reduced below detection limit when the Daruma was treated with 20 times (w/v) of sodium hypochlorite solution (SHS) for 120 min. The 3.62 log CFU/g of viable cell count and 3.22 log CFU/g of Staphylococcus aureus was reduced, and Escherichia coli was reduced below detection limit when the Daruma was treated with 20 times (w/v) of SAHW for 120 min. The antibacterial effects of SAHW were stronger than those of SHS at same available chroline concentration. SAHW treatment after washing strongly alkalic electrolyzed water (SAEW) showed better bactericidal effects than SAHW treatment only. The 4.0 log CFU/g of viable cell count was reduced, S. aureus was reduced below regulation limit (Log 2.0 CFU/g), and E. coli was reduced below detection limit when the Daruma was treated with 20 times (w/v) of SAHW for 90 min after washing with 20 times (w/v) of SAEW for 60 min. The viable cell number was reduced below detection limit and S. aureus was reduced below regulation limit when the Daruma was treated with 20 times (w/v) of SAHW for 60 min in ultrasonic washer. E. coli was reduced below detection limit when the Daruma was treated with 20 times (w/v) of SAHW for 10 min in ultrasonic washer. These results suggest that combination of SAHW and UW may be a good technique to reduce the microbial contamination in daruma.

Effects of Hydraulic Retention Time and Cycle Time on the Sewage Treatment of Intermittently Aerated Nonwoven Fabric Filter Bioreactor (간헐포기식 부직포 여과막 생물반응조에서 체류시간 및 주기시간이 하수처리에 미치는 영향)

  • Kim, Taek-Su;Bae, Min-Su;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.17-24
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    • 2005
  • This study was carried out to investigate the removal efficiency of an intermittently aerated nonwoven fabric filter bioreactor fed continuously with domestic sewage. The hydraulic retention time(HRT) of the reactor was reduced from 12 hrs to 10 hrs to 8 hrs during an experimental period of 17 months. In order to search an optimum aeration/nonaeration time ratio for the nitrogen removal at each HRT, the cycle times of 3, 2 and 1 hr were tested at the aeration/nonaeration time ratio of 1. Then, the aeration/nonaeration time ratio was changed from 50 min/70 min to 40 min/80 min to 30 min/90 min at the cycle time of 2 hr which showed the best nitrogen removal. During the experimental period, the effluent SS concentration was always below 1.2 mg/L with more than 95% of BOD removal efficiency. The highest nitrogen removal of 90.1% was observed at the aeration/nonaeration time ratio of 40 min/80 min at the HRT of 10 hr. Oxidation-reduction potential could represent the degree of the nitrification and denitrification reaction in the reactor.

Fermentation Characteristics of Low Salted Kochujang Prepared with Mixture of Sub-materials (부원료를 혼합 첨가한 저식염 고추장의 발효 특성)

  • Kim, Dong-Han
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.449-455
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    • 2005
  • To reduce saft content of kochujang, various combinations of sub-materials such as ethanol mustard and chitosan were added to kochujang, and their effects on microbial characteristics, enzyme activities, and physicochemical characteristics of kochujang were investigated after 12 weeks of fermentation. Activities of ${\beta}$-amylase and pretense were low in ethanol-mustard-chitosan-added kochujang, whereas no significant difference was observed in ${\alpha$-amylase activity among all groups. Number of viable yeast cells decreased remarkably in mustard-added kochujang during late aging period, and anaerobic bacterial counts decreased in sub-material-added groups. Consistency of kochujang increased by addition of sub-materials, and oxidation-reduction potential was low in chitosan-added group. Mustard-chitosan-added kochujang showed lowest increase in total color difference(${\Dalta}E$) and decrease in water activity. PH of kochujang wns highest in mustard-chitosan-added kochujang, resulting in significantly increased titratable acidity. Addition of sub-material increased reducing sugar contents of kochujang, whereas ethanol production was significantly repressed in mustard-chitosan-added kochujang. Amino nitrogen content was Highest in mustard-chitosan-added kochujang during late aging period, whereas ammonia nitrogen content was lower in ethanol-mustard-added kochujang. Results of sensory evaluation indicated ethanol-mustard-added kochujang was more acceptable than other groups in taste and overall acceptability.

Optimal Pumping Rate of a Water Well at Imgokri, Sangju City (상주시 임곡리 굴착공의 적정양수량 결정)

  • Cho, Byong-Wook;Yun, Uk;Moon, Sang-Ho;Lee, Byeong-Dae;Cho, Soo-Young;Kim, YongCheol;Hwang, Seho;Shin, Jehyun;Ha, Kyoochul
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.255-265
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    • 2017
  • We have determined the optimal pumping rate of the PW-2 water well (depth=100 m) at Imgokri, Sangju City. Cutting analysis and geophysical logging data reveal water-producing horizons at 26.1-26.5, 28.0-30.0, 33, 58, and 71 m. For pumping rates of 40, 55, 70, 90, and $132m^3/d$ over 70 days, the estimated drawdown from the PW-2 well was 6.48, 11.56, 18.07, 28.99 and 60.26 m, respectively. During a constant-rate pumping test at a rate of $117m^3/d$, the cone of depression intersected an impermeable boundary after 120-150 min of pumping. Therefore, we consider the critical pumping rate for well PW-2 to be $90m^3/d$. After pumping at $90m^3/d$ for 70 days, the calculated drawdown was 28.82-31.27 m. We suggest an optimal pumping rate for well PW-2 of $70-90m^3/d$, as the optimal pumping rate should be similar to the critical pumping rate. Sharp increases in the slope of the time-drawdown relationship, dissolved oxygen concentrations, and oxidation-reduction potential during the constant-rate pumping test indicate the limited development of bedrock aquifers around PW-2.