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Opto-Electrochemical Sensing Device Based on Long-Period Grating Coated with Boron-Doped Diamond Thin Film

  • Bogdanowicz, Robert;Sobaszek, Michał;Ficek, Mateusz;Gnyba, Marcin;Ryl, Jacek;Siuzdak, Katarzyna;Bock, Wojtek J.;Smietana, Mateusz
    • Journal of the Optical Society of Korea
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    • v.19 no.6
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    • pp.705-710
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    • 2015
  • The fabrication process of thin boron-doped nanocrystalline diamond (B-NCD) microelectrodes on fused silica single mode optical fiber cladding has been investigated. The B-NCD films were deposited on the fibers using Microwave Plasma Assisted Chemical Vapor Deposition (MW PA CVD) at glass substrate temperature of 475 ℃. We have obtained homogenous, continuous and polycrystalline surface morphology with high sp3 content in B-NCD films and mean grain size in the range of 100-250 nm. The films deposited on the glass reference samples exhibit high refractive index (n=2.05 at λ=550 nm) and low extinction coefficient. Furthermore, cyclic voltammograms (CV) were recorded to determine the electrochemical window and reaction reversibility at the B-NCD fiber-based electrode. CV measurements in aqueous media consisting of 5 mM K3[Fe(CN)6] in 0.5 M Na2SO4 demonstrated a width of the electrochemical window up to 1.03 V and relatively fast kinetics expressed by a redox peak splitting below 500 mV. Moreover, thanks to high-n B-NCD overlay, the coated fibers can be also used for enhancing the sensitivity of long-period gratings (LPGs) induced in the fiber. The LPG is capable of measuring variations in refractive index of the surrounding liquid by tracing the shift in resonance appearing in the transmitted spectrum. Possible combined CV and LPG-based measurements are discussed in this work.

Synthesis and Characterization of Porous Poly(ε-caprolactone)/Silica Nanocomposites (다공성 폴리(ε-카프로락톤)/실리카 복합체의 제조 및 특성평가)

  • Son, Siwon;Choi, Ji-Eun;Cho, Hun;Kang, DaeJun;Lee, Deuk Yong;Kim, Jin-Tae;Jang, Ju-Woong
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.323-328
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    • 2015
  • Poly(${\varepsilon}$-caprolactone) (PCL) nanofibers and PCL/silica membranes were synthesized by sol-gel derived electrospinning and casting, respectively. Smooth PCL nanofibers were obtained from the precursor containing N,N-dimethylformamide (DMF). PCL/silica membranes were prepared by varying the tetraethyl orthosilicate (TEOS) contents from 0 to 40 vol% to investigate the effect of silica addition on mechanical properties and cytotoxicity of the membranes. Although the strength of the membranes decreased from 12 to 8 MPa with increasing the silica content, the strength remained almost constant 7 weeks after dipping in phosphate buffered saline solution (PBS). The strength reduction was attributed to the presence of a patterned surface pores and micro-pores present in the walls between pores. The crystal structure of the membranes was orthorhombic and the crystallite size decreased from 57 to 18 nm with increasing the silica content. From the agar overlay test, the PCL/silica membranes exhibited neither deformation and discoloration nor lysis of L-929 fibroblast cells.

The Evaluation of Architectural Density on Urban District using Airborne Laser Scanning Data (항공레이저측량 자료를 이용한 시가지 건축밀도 평가에 관한 연구)

  • Lee, Geun-Sang;Koh, Deuk-Koo;Cho, Gi-Sung
    • Journal of the Korean Association of Geographic Information Studies
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    • v.6 no.3
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    • pp.95-106
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    • 2003
  • This study evaluated the architectural density of urban district using airborne laser scanning(ALS) that is a method used in urban planning, water resources and disaster prevention with high interest recently. First, digital elevation model(DEM) and digital surface model(DSM) was constructed from Light detection and ranging(LiDAR). For getting the height of building, ZONALMEAN filter was used in DEM and ZONALMAJORITY filter was used in DSM. This study compared the floor from filtering with the floor from survey and got standard error, which is ${\pm}0.199$ floor. Also, through the overlay and statistical analysis of total-area layer and zone layer, we could present floor area ratio by zone. As a result of comparison with floor area ratio between airborne laser scanning data and survey data, the standard error of floor area ratio shows ${\pm}2.68%$. Therefore, we expect that airborne laser scanning data can be a very efficient source to decision makers who set up landuse plan in near future.

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Study for Building Ecological Network in East-North Asia (동북아 생태네트워크 구축을 위한 방안 고찰)

  • Jeon, Seong-Woo;Lee, Moung-Jin;Kang, Byung-Jin;Shin, Ji-Young
    • Journal of Environmental Policy
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    • v.8 no.3
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    • pp.1-26
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    • 2009
  • In the 1990s, when the viewpoint that an ecosystem is a single network within a specific region was adopted, the preservation and management of natural ecosystems was proposed. With regard to Northeast Asia, the expansion of trans-boundary pollution due to rapid development and the swift destruction of the natural environment emphasize the necessity for environmental cooperation. The Northeast Asia region made up of South Korea, North Korea, three northeastern prefectures in China, the Russian far-east, and parts of Mongolia were selected to be analyzed for an ecological network. The significance of this study lies in the development of a methodology for building a Northeast Asian ecological network through the use of satellite images. Regarding the methods of analysis, stable habitats for four priority species were selected to be performed using overlay analysis. The result of the analysis of the ecological networks in the whole Northeast Asia region showed that there were key areas partly dispersed in the Korean Peninsula, but whether the key areas would be maintained in the long term is unknown. As for China, key areas were concentrated in the border areas around the Tumen River and in parts of the three northeastern prefectures. Russia had wide-ranging areas that could function as stable habitats for most species. As a result of the actual conditions of the ecological networks, most of the Northeast Asia region, including the Korean Peninsula, was in poor condition, requiring appropriate measures and their operation as soon as possible. Also, it was revealed that further investigation and research was necessary for border areas that were identified to be key areas.

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Analysis of the Emergency Medical Service Area Using GIS: the Case of Seoul (GIS를 이용한 응급의료 진료권 분석: 서울시를 사례로 하여)

  • 이희연;박미영
    • Spatial Information Research
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    • v.12 no.2
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    • pp.193-209
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    • 2004
  • The purpose of this study is to analyze the service area of emergency medical centers using GIS-based spatial analysis methods in Seoul, focusing on the behaviour of patients on the choosing of emergency centers. For this analysis, six emergency centers were selected to collect data for the information on the addresses of patients from September to November hi 2003. Analysis on the service area, which was carried out by measuring the distribution of patients in terms of distance from emergency medical centers, clearly reveals that the majority of patients was located within or adjacent districts at the emergency medical center. However, the size of the primary service area f3r six emergency medical centers was much different, implying that the decision to visit specific emergency medical center by patients was closely related to the size, perception, and preference of the emergency medical center. Based on the results of the spatial characteristics of emergency medical service area, this research tries to construct the surface map of the emergency medical service level supplied by 32 regional emergency medical centers located in Seoul. Considering the levels of infrastructure for emergency medical centers, the coverage for the degree of supply of emergency medical service by each emergency medical center was constructed in terms of a distance decaying in the distribution of patients from emergency medical center imposing different weights on distance bands. Spatial overlay utilizing map algebra function was performed in order to calculate total supply level of emergency service. The results clearly show that spatial inequality exists in the supply levels of the emergency medical service among local areas of Seoul.

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The Comparison of Water Quality of Daecheong-Dam basin According to the Data Sources of Land Cover Map (토지피복도 자료원에 따른 대청댐유역 수질특성 비교)

  • Lee, Geun Sang;Park, Jin Hyeog;Choi, Yun Woong
    • Spatial Information Research
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    • v.20 no.5
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    • pp.25-35
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    • 2012
  • This study compared the influence of water quality according to the data sources of spatial information. Firstly, land cover map was constructed through image classification of Daecheong-dam basin and the accuracy of image classification from satellite image showed high as 88.76% in comparison with the large-scaled land cover map in Ministry of Environment, to calculate Event Mean Concentration (EMC) by land cover that impact on the evaluation of nonpoint source pollutant loads. Also curve number and direct runoff were calculated by spatial overlay with soil map and land cover map from image classification. And Seokcheon and Daecheong-Dam basin showed high in the analysis of curve number and direct runoff. Samgacheon-Joint and Sokcheon-Downstream basin showed high in the nonpoint source pollutant loads of BOD from direct runoff and EMC. And Samgacheon-Joint and Bonghwangcheon- Downstream basin showed high in the nonpoint source pollutant loads of TN and TP. Nonpoint source pollutant loads from image classification were compared with those by the land cover map from Ministry of Environment to present the effectivity of nonpoint source pollutant loads from satellite image. And Daecheong-Dam Upstream basin showed high as 10.64%, 11.70% and 20.00% respectively in the errors of nonpoint source pollutant loads of BOD, TN, and TP. Therefore, it is desirable that spatial information including with paddy and dry field is applied to the evaluation of nonpoint source pollutant loads in order to simulate water quality of basin effectively.

Confidence Improvement of Serial Cadastral Map Edit Using Ortho Image (정사영상을 이용한 연속지적도 편집의 신뢰성 향상 방안)

  • Kim Kam Lae;Ra Yong Hwa;Ahn Byung Gu;Park Se Jin
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.22 no.3
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    • pp.253-259
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    • 2004
  • The sheetwise cadastral map data needs to become a Serial Cadastral Map (SCM) database for the promotion of the reliability of cadastral surveying, for the efficient operation of the Parcel Based Land Information System, and for the convenient use of land information as well. A large amount of money and time are required for the editing process of producing SCM DB in accordance with the $\ulcorner$Guideline for the Production of Serial Cadastral Maps$\lrcorner$ by the Ministry of Construction & Transportation if any of field surveying techniques is accompanied by. In addition, a boundary line that extends to a neat line does not meet the counterpart of the neighboring map sheet at a point. Such cases frequently occur and are much dependent upon the decisions of individuals in charge of editing or inspecting. The core processes of the research, firstly overlay SCM produced by the edition of the sheetwise cadastral maps with Autodesk Map on orthophoto images, secondly adjust the parcel boundaries which are delineated over more than one map sheet, and lastly compare the original boundary coordinates and areas with the corresponding adjusted ones and calculate root mean square errors (RMSEs). The research aims at promoting the quality of SCM by minimizing the inconsistency of parcel boundaries by means of the comparative analysis of the calculated RMSEs.

An Assessment of Coastal Area Using Geographic Information Systems and Multi-Criteria Analysis (지리정보시스템(GIS)과 다기준 분석법(MCA)을 적용한 연안지역 평가)

  • Choi, Hee-Jung;Park, Jung-Jae;Hwang, Chul-Sue
    • Journal of the Korean association of regional geographers
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    • v.13 no.2
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    • pp.143-155
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    • 2007
  • There are many conflicts or interests among various stakeholders on the development of the coastal area. The integrated methodology, which is reflective of physical conditions, socio-economic circumstances, and people's sense of values, is thus needed to solve the problems. In this study, geographical information systems(GIS) and analytic hierarchy process(AHP) that arc one of multi-criteria analysis methodologies are loosely coupled to develop better analytic procedures for coastal assessment. Socio-economic and environmental parameters of the study area, Hampyung Bay area, are converted to a GIS system-applicable format, while AHP is used to assess the relative importance level of each parameter by calculating weighting factors. After standardizing and rasterizing spatial data from various sources. the weighting factors are applied to produce the layers for each parameter. Map algebra and overlay analyses are used to create the final layer according to the decision making logic or model proposed here. Cell values of that layer could be considered as spatial alternatives. In addition to this finding, the flexibility with the weighing factors enable decision-makers to understand the procedures and alternatives in relevance with selective strategies for coastal management.

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Review of Compositional Evaluation Items for Environmental Conservation Value Assessment Map(ECVAM) of National Land in Korea (국토환경성평가지도 평가항목 구성의 적정성 검토)

  • Jeon, Seong Woo;Lee, Moung Jin;Song, Won Kyong;Sung, Hyun Chan;Park, Wook
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.1
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    • pp.1-13
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    • 2008
  • This study review of Compositional Evaluation Items for Environmental Conservation Value Assessment Map (ECVAM) in Korea. The ECVAM is composed of legal assessment and environmental/ecological assessment items. ECVAM basically adapts an overlay method for environmental/ecological assessment items. The objective of this study is to suggest supplementary items for the ECVAM with the following process : Overlapping rates of the assessment items in the ECVAM are calculated to understand the grade distribution of the environmental conservation value assessment and to analyze the overlapping rates among the assessment items, as a result it is found that various items are overlapped each other. In order to reflect effectively each assessment item to the ECVAM, Analyzed the overlapping degree among assessment items to be applied to this map. On the concrete we gripped results to be assessed by various items, which were overlapped each other. In order to reflect effectively each assessment item to the environmental conservation value assessment map of national land, we analyzed the overlapping degree on environmental/ecological items, and investigated the grade distribution by field survey. In this study we assessed the ECVAM by 5 kinds of method. Method 1 is Grade 1 areas of each administrative district, Method 2 is Comparing overlapping areas of each assessment items Grade 1, 2 and Permission of each assessment items' duplication, Method 3 is Grade 1, 2 areas by only singular assessment items, Method 4 is Only Grade 1 areas of Method 2 and Method 5 is Only Grade 2 areas of Method 2. As results, Method 1 showed Seoul and other metropolitan cities reveal a high proportion of Grade I regions by the legal assessment items. Kangwon-Do, show a high proportion of Grade I regions by the environmental/ecological assessment item. Method 2 showed 93.4% of diameter Grade II(standard for stability), forest diameter item was accounted for 99.9% by Method 3, Method 4 showed 95.7% of forest diameter and forest density was accounted for 66.4% by Method 5. From now on, this study will contribute to reduce the complexity in the process of manufacturing ECVAM of National Land, and to raise the pliability in the process of managing and updating this map.

Autogenous Shrinkage of Very-Early Strength Latex-Modified Concrete with Latex Contents (라텍스함량 변화에 따른 VES-LMC의 자기수축)

  • Park, Won-Il;Choi, Pan-Gil;Yun, Kyong-Ku;Lee, Bong-Hak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.3
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    • pp.1059-1065
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    • 2010
  • Very-early strength latex-modified concrete (VES-LMC) was developed for the purpose of fast-track overlay of a concrete bridge deck under heavy traffic, concentrated on the workability, durability, and strength gain so that it can be opened to the traffic only three hours after its placement. The mixture of VES-LMC might accompany very high heat of hydration at early-age because of its inherent rapid hardening property and could have susceptibility to autogenous shrinkage because of its relatively low water-cement ratio. This study evaluated the effect of the latex-cement ratio(L/C) both of the constant and variable slumps on the autogenous shrinkage of VES-LMC by carrying out simple temperature rise test and early-age shrinkage experiment. Test results are as follows: The latex contributes on the enhancement of the concrete durability but has little effect on its hydration and the accompanied heat of hydration in VES-LMC. Autogenous shrinkage increased with the increase in latex-cement ratio at variable slumps and its pattern followed regularly a logarithmic increase. However, the influence of water-cement ratio and latex-cement ratios for the test specimens at constant slump on early-age autogenous shrinkage property was found to be minor due to the simultaneous effect of the two experimental variables.