• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.173-182
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• 2022

Dongsuak crater, located in the mid-mountainous region of Jeju Island, is located at an altitude of about 700 m, and the newly discovered Dongsuak spinel peridotites was enclosed in Dongsuak alkaline basalt. The Dongsuak spinel peridotites are composed of olivine, orthopyroxene, clinopyroxene, and spinel with porphyroclastic texture under the an equilibrium state. The variations of mineral major and trace compositions indicates that the Dongsuak spinel peridotites originate at depth from 66 to 88 km under an equilibrium temperature of about 960℃~1068℃. The Dongsuak spinel peridotites have been undergone about 1~3% fractional melting. The LREE-enriched characteristics indicate that the Dongsuak spinel peridotites have been undergone cryptic metasomatism by silicate melt without new minerals.

• Korean Journal of Mineralogy and Petrology
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• v.36 no.4
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• pp.365-376
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• 2023

Songaksan, formed about 3800 year ago, is one of the tuff rings in the Jeju Island. Mantle xenoliths, spinel peridotites, are enclosed in the Songaksan Trachybasalt. The spinel peridotites are less than 2 cm in size and are composed of olivine, orthopyroxene, clinopyroxene, and spinel. The uniform compositions of the minerals from core to rim indicate that equilibrium was reached in the spinel peridotites before these were enclosed in the host magma. The spinel peridotites originated at depths between 55 and 60 km with equilibrium temperatures ranging from 915 to 968℃. The spinel peridotites from Songaksan reveal porphyroclastic texture with a lot of neoblast minerals. Olivines display strong kink banding, indicating that the upper mantle of Songaksan has been deformed. The spinel peridotites from Songaksan have undergone about 5~7% fractional melting, and cryptic metasomatism by an silicate melt. The period of entrainment and transport of the spinel peridotites in the host magma is about 15 days.

• The Journal of the Petrological Society of Korea
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• v.13 no.1
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• pp.34-45
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• 2004

This paper describes the textural relations of mantle xenoliths and fluid inclusions in mantle-derived rocks found in alkaline basalts from Jeju Island which contain abundant ultramafic, felsic, and cumulate xenoliths. Most of the ultramafic xenoliths are spinel-lherzolites, composed of olivine, orthopyroxene, clinopyroxene and spinel. The felsic xenoliths considered as partially molten buchites consist of quartz and plagioclase with black veinlets, which are the product of ultrahigh-temperature metamorphism of lower crustal materials. The cumulate xenoliths, clinopyroxene-rich or clinopyroxene megacrysts, are also present. Textural examination of these xenoliths reveals that the xenoliths are typically coarse grained with metamorphic characteristics, testifying to a complex history of evolution of the lower crust/upper mantle source region. The ultramafic xenoliths contain protogranular, porphyroclastic and equigranular textures with annealing features, indicating the presence of shear regime in upper mantle of the Island. The preferential associations of spinel and olivine with large orthopyroxenes suggest a previous high temperature equilibrium in the high-Al field and the original rock-type was a Al-rich orthopyroxene-bearing peridotite without garnet. Three types of fluid inclusions trapped in mantle-derived xenoliths include CO$_2$-rich fluid (Type I), multiphase silicate melt (glass ${\pm}$ devitrified crystals ${\pm}$ one or more daughter crystals ＋ one or more vapor bubbles) (Type II), and sulfide (melt) inclusions (Type III). C$_2$-rich inclusions are the most abundant volatile species in mantle xenoliths, supporting the presence of a separate CO$_2$-rich phase. These CO$_2$-rich inclusions are spatially associated with silicate and sulfide melts, suggesting immiscibility between them. Most multiphase silicate melt inclusions contain considerable amount of silicic glass. reflecting the formation of silicic melts in the lower crust/upper mantle. Combining fluid and melt inclusion data with conventional petrological and geochemical information will help to constrain the fluid regime, fluid-melt-mineral interaction processes in the mantle of the Korean Peninsula and pressure-temperature history of the host xenoliths in future studies.

• The Journal of the Petrological Society of Korea
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• v.8 no.3
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• pp.183-202
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• 1999

The Sobeaksan Gneiss Complex in the Punggi area is composed of mainly mignatitic gneiss, porphyroblastic gneiss, garnet granitic gneiss and biotitie granitic gneiss. Metamorphic grade increase gradually from the amphibolite facies of northwestern part to the granulite facies of southwestern part in the study area. Representative mineral assemblage in the amphibolite facies is biotite-muscovite-K-feldspar-plagioclase$\pm$garnet$\pm$epidote, needle shape or fibrous sillimanite occur in transitional zone from the amphibolite facies to the granulite facies. In the granulite facies, the garnet-Opx granulite shows garnet-orthopyroxene-biotite-plagioclase, the metabasite shows clinopyroxene-plagioclase$\pm$hornblende$\pm$orthopyroxene$\pm$garnet and the migmatitic gneiss shows garnet-biotite-sillimanite-cordierite$\pm$spinel as representative mineral assemblage. Retrograde metamorphism after the granulite facies metamorphism made corindum and andalusite in the migmatitic gneiss and the thin layer garnet between clinopyroxene and plagioclase in the metabasites. The peak P-T conditions of the migmatitic gneiss and the garnet-Opx granulite are $916^{\circ}C$/6.6 kb and $826^{\circ}C$/6.3 kb, respectively. The P-T condition of biotite and plagioclase inclusion, which indicates the progressive condition of the granulie facies, within garnet is $866^{\circ}C$/7.5 kb and that of rim composition of garnet and biotite is $726^{\circ}C$/4.6 kb, which infer the clockwise P-T path of the granulite facies metamorphism. The temperatures caculated by the rim composition of garnet and biotite in the migmatitic gneiss and garnet granitic gneiss have a wide range of $556-741^{\circ}C$, which indicate that the retrograde metamorphism after the granulite facies metamorphism has effected differently. It is difficult to determine the P-T condition of the biotite granitic gneiss because less occurrence and higher spessartine content of garnet. The P-T condition of the thin layered garnet between clinopytoxene and plagioclase in the metabasite is $635-707^{\circ}C$/4.1-5.3 kb. This texture indicates the isobaric cooling(IBC) condition of the retrogressive metamorphism. As a result, the metamorphic evolution of the Punggi area has undergone the isobaric cooling after the granulite facies metamorphism which has undergone the clockwise P-T path.

• The Journal of the Petrological Society of Korea
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• v.18 no.3
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• pp.223-236
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• 2009

Ultramafic xenoliths from southeastern part of Jeju Island can be grouped into two types: Type I and Type II. Type I xenoliths are magnesian and olivine-rich peridotite (mg#=89-91), which are commonly found at the outcrop. Most previous works have been focused on Type I xenoliths. Type II xenoliths, consisting of olivine, orthopyroxene and clinopyroxene with higher Fe and Ti components (mg#=77-83) and lower Mg, Ni, Cr, are reported in this study. They are less common with a more extensive compositional range. The studied Type II xenoliths are wehrlite, olivine-clinopyroxenite, olivine websterite, and websterite. They sometimes show ophitic textures in outcrops indicating cumulate natures. The textural characteristics, such as kink banding and more straight grain boundaries with triple junctions, are interpreted as the result of recrystallization and annealing. Large pyroxene grains have exsolution textures and show almost the same major compositions as small exsolution-free pyroxenes. Although the exsolution texture indicates a previous high-temperature history, all mineral phases are completely reequilibrated to some lower temperature. Orthopyroxenes replacing clinopyroxene margin or olivine indicate an orthopyroxene enrichment event. Mineral phases of Type II are compared with Type I xenoliths, gabbroic xenoliths, and the host basalts. Those from Type II xenoliths show a distinct discontinuity with those from Type I mantle xenoliths, whereas they show a continuous or overlapping relation with those from gabbroic xenoliths and the host basalts. Our petrographic and geochemical results suggest that the studied type II xenoliths appear to be cumulates derived from the host magma-related system, being formed by early fractional crystallization, although these xenoliths may not be directly linked to the host basalt.

• Economic and Environmental Geology
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• v.30 no.5
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• pp.477-491
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• 1997

In the Bibong area of the western part of Chungcheongnam-do, ultramafic masses occur as discontinuous isolated lenticular bodies in the Precambrian Kyeonggi gneiss complex. They extend for about 200 m long to NNE directions which are parallel to fault lines in the gneiss complex. The ultramafic masses contact with the adjacent gneiss complex as steeply dipping faults. They are dunites and harzburgites and many of them are partially or completely serpentinized. The ultramafic rocks dominantly show protogranular, equigranular and equigranular-$m{\grave{o}}saic$ textures. They also show porphyroclastic (megacrystic) or recrystallized textures reflecting several stages of metamorphism. They contain varying amounts of olivine $(Fo_{89-92})$, enstatitic to bronzitic orthopyroxene, diopsidic clinopyroxene, tremolitic to pargasitic hornblende, and spinel with serpentine, talc, chlorite, calcite and magnetite. The ultramafic rocks have high magnesium numbers and transitional element contents, low alkali contents and show deplete REE patterns. Comparing with available data, geochemical and mineralogical characteristics shown in the ultramafic rocks of the Bibong area are similar to those of worldwide mantle xenoliths and orogenic related ultramafic rocks. The field evidences, petrographical, geochemical and mineralogical characteristics shown in the ultramafic rocks of the Bibong area are similar to alpine type ultramafic rocks emplaced into the crust by the faulting as mantle slab types. With the petrographical characteristics, these mineralogical compositions suggest that the ultramafic rocks of the Bibong area have experienced several stages of retrogressive metamorphism in a condition ranging from the upper amphibolite facies to greenschist facies.

• The Journal of the Petrological Society of Korea
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• v.5 no.1
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• pp.66-83
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• 1996

We report petrography, mineral chemistry, and major and trace element chemistry for rare tholeiites in Cheju island where alkalic rocks predominate. Available age data indicate that the tholeiitic magmatism was younger than 0.49Ma, possibly younger than 0.17 Ma. The tholeiites are generally fine-grained, porphyritic rock and show intergranular texture with lath-shaped plagioclase ($An_{61-46}$), orthopyroxene (bronzite) and olivine ($Fo_{78-67}$). Characteristically, two kinds of clinopyroxene (pigeonite and augite) occur only in groundmass. The tholeiites have normative quartz and show limited compositional variations ($SiO_2$=51.0-52.5 wt%; Mg＃=54-60). Major and transitional metal element variations of tholeiites are distinct from those of alkaline rocks in MgO diagram, suggestingthat the two rock types cannot be simply related to differentiation process from the same magma. The ratios among $K_2O$, Rb, Ba, Nb and La are similar for both tholeiites and alkali basalts, however the ratios between the elements (P, Y and Yb) having an affinity with garnet and the above elements are higher for tholeiites than for alkali basalts. These trace element ratios suggest that the tholeiites and alkali basalts were produced by different degrees of partial melting from a similar sources material (garnet lherzolite mantle).

• Journal of the Mineralogical Society of Korea
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• v.3 no.1
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• pp.1-6
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• 1990

Clacic amphiboles along the tremolite (Tr)-tschermakite(Ts) joint were synthesized using a piston-cylinder appratus. At 750-85$0^{\circ}C$and 12-2 kb, amphibole+corundum coexist with zoisite($\pm$talc, chlorite, and Mg-staurolite), but with anorthite($\pm$cholorite, spinel, pyroxenes, and sapphirine) at lower P. At 90$0^{\circ}C$, amphibole+corundum+clinopyroxene($\pm$anorthite, forsterite, sapphirine, and garnet) are stable over the P range 12-18 kb. These amphibole-bearing assemblages are replaced at high P by clcinopyroxene+talc+chlorite+zoisite at 650-75$0^{\circ}C$, and at higher temperatures by garnet+clinopyroxene($\pm$zoisite, orthopyroxene, and Mg-staurolite). Synthetic amphiboles with Ts>~45 mol% contain as much as 0.15 excess cations per formula unit(pfu) based on 23 oxygens(anhydrous formula), whereas less tschermakitic ones are deficient in cation occupancy by up to 0.18 pfu. This trend is attributed to the 야/trioctahedral substitution in Ca-amphiboles. Compositions of synthetic amphiboles display systematic changes with P and T governed by coexisting mineral assemblages. The Ts content (=[8-Si-Na]/2) increases with increasing T( Ts/ T=~0.1 nik% K-1) in the range 750-85$0^{\circ}C$, but remains nearly constant at 850-90$0^{\circ}C$. Pressure dramatically affects the Ts content of Ca-amphiboles:it increases with P at 8-12 kb( Ts/ T=2-3 mol% K-1), but significantly decreases at 12-21 kb( Ts/ P=-2.5 mol% Kb-1). Hence, the most tschermakitic amphiboles, containing 60$\pm$5 mol % Ts, or 1.2$\pm$0.1 tetrahedral Al, occur at 12 kb and 850-90$0^{\circ}C$. Compositions of Ca-amphiboles defined by a simple reaction, 3 Tr+2 zoisite+7 corundum+H2O=5 Ts, are reversed and used to estimate thermodynamic parameters of tschermakite assuming ideal mixing of Tr-Ts solid solutions. Predicted standard molal entropy and enthalpy of tschermakite are : S$^{\circ}$of Tr-Ts solid solutions. Predicted standard molal entropy and enthalpy of tschermakite are : S$^{\circ}$=566.9$\pm$13.7 J mol-1K, -1and H$^{\circ}$=-12518.36$\pm$15.17 kJ mol.-1

• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.273-281
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• 2022

Mantle heterogeneity is closely related to the distribution and circulation of volatile components in the Earth's interior, and the behavior of volatiles in the mantle strongly influences the rheological properties of silicate rocks. In mantle xenoliths, these physicochemical properties of the upper mantle can be recorded in the form of microstructures and fluid inclusions. In this paper, I summarized and reviewed the results of previous studies related to the characteristics of microstructures and fluid inclusions from peridotite xenoliths beneath the Rio Grande Rift (RGR) in order to understand the evolution and heterogeneity of upper mantle. In the RGR, the mantle peridotites are mainly reported in the rift axis (EB: Elephant Butte, KB: Kilbourne Hole) and rift flank (AD: Adam's Diggings) regions. In the case of the former (EB and KB peridotites), the type-A lattice preferred orientation (LPO), formed under low-stress and low-water content, was reported. In the case of the latter (AD peridotites), the type-C LPO, formed under low-stress and high-water content, was reported. In particular, in the case of AD peridotites, at least two fluid infiltration events, such as early (type-1: CO₂-N₂) and late (type-2: CO₂-H₂O), have been recorded in orthopyroxene. The upper mantle heterogeneity recorded by these microstructures and fluid inclusions is considered to be due to the interaction between the North American plate and the Farallon plate.

• The Journal of the Petrological Society of Korea
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• v.21 no.2
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• pp.235-247
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• 2012

Peridotite xenoliths hosted by alkali basalts from South Korea occur in Baengnyeong Island, Jeju Island, Boeun, Asan, Pyeongtaek and Ganseong areas. K-Ar whole-rock ages of the basaltic rocks range from 0.1 to 18.9 Ma. The peridotites are dominantly lherzolites and magnesian harzburgites, and the constituent minerals are Fo-rich olivine ($Fo_{88.4-92.0}$), En-rich orthopyroxene, Di-rich clinopyroxene, and Cr-rich spinel (Cr# = 7.8-53.6). Hydrous minerals, such as pargasite and phlogopite, or garnet have not been reported yet. The Korean peridotites are residues after variable degree of partial melting (up to 26%) and melt extraction from fertile MORB mantle. However, some samples (usually refractory harzburgites) exhibit metasomatic enrichment of the highly incompatible elements, such as LREE. Equilibration temperatures estimated using two-pyroxene geothermometry range from ca. 850 to $1050^{\circ}C$. Sr and Nd isotopic compositions in clinopyroxene separates from the Korean peridotites show trends between depleted MORB-like mantle (DMM) and bulk silicate earth (BSE), which can be explained by secondary metasomatic overprinting of a precursor time-integrated depleted mantle. The Korean peridotite clinopyroxenes define mixing trends between DMM and EM2 end members on Sr-Pb and Nd-Pb isotopic correlation diagrams, without any corresponding changes in the basement. This is contrary to what we observe in late Cenozoic intraplate volcanism in East Asia which shows two distinct mantle sources such as a DMM-EM1 array for NE China including Baengnyeong Island and a DMM-EM2 array for Southeast Asia including Jeju Island. This observation suggests the existence of large-scale two distinct mantle domains in the shallow asthenosphere beneath East Asia. The Re-Os model ages on Korean peridotites indicate that they have been isolated from convecting mantle between ca. 1.8 and 1.9 Ga.