• Title/Summary/Keyword: Organic waste

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Syntheses and Characterization of UV-curable Polyurethane Acrylates with Eco-friendly Polyols (친환경 폴리올을 이용한 광경화형 폴리우레탄 아크릴레이트의 합성)

  • Lee, Bong;Kim, Yeong Woo;Lee, Won-Ki
    • Journal of Adhesion and Interface
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    • v.20 no.4
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    • pp.140-145
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    • 2019
  • In view of environmental considerations, the control of carbon dioxide (CO2) and volatile organic compounds (VOCs) is one of important issues in the film and coating industries. Therefore, UV-curable system has been developed due to minimize emissions of VOCs and reduce CO2 emission due to low energy consumption from fast curing. Also, biodegradable polymers economically are attractive because of environmental and economic concerns associated with huge waste plastics. In this study, UV-curable polyurethane acrylates with different compositions of biodegradable polylactide (PLA) diol and poly(ethylene glycol) as diols were synthesized and curing reaction of their end-capped acrylates was performed by UV exposure. Tensile strength, elongation, and Tg of the UV-cured polyurethane acrylates increased with PLA diol content in the diol while their hydrophilicity and thermal stability increased with the PEG content. These results indicated a property of UV-cured polyurethane acrylates could be controlled by environment-friendly diols.

Development of Alternative External Carbon Source from Wasting Carbonaceous Organic Resource and Full Scale Application (유기폐자원을 이용한 고도하수처리 대체탄소원 개발 및 실플랜트 적용)

  • Jung In Chul;Kim Ho Young;Kang Dong Hyo;Jung Joung Soon;Lee Sang Won;Lim Keun Taek;Kim Chang Won
    • Journal of Environmental Science International
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    • v.13 no.10
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    • pp.911-919
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    • 2004
  • The purpose of this research was evaluated economical effect to apply alternative external carbon source. Conventional activated sludge process in municipal wastewater treatment plant was adapted and introduced to Biological nutrient removal processes to meet the newly enforced effluent quality standard for nutrient removal in Korea. Low $COD/NH_4^+-N$ ratio and higher nutrient concentration of influent characteristics force to inject external carbon source for denitrifying recycled nitrate. In the most case, methanol was used as external carbon source. But Methanol is expensive and very dangerous in handling. So we could find cheaper and safer external carbon source substituted methanol in last study. This alternative external carbon source is named RCS(recoverd carbon source) and a by-product of fine chemical product at chemical plant. When RCS was applied real municipal wastewater treatment plant, average $55\~65\%$ of T-N removal efficiency, 8.8mg/l of effluent T-N concentration, 11.3mg/l of effleunt COD concentration were obtained without effluent COD increase as against used methanol. To apply RCS in municipal wastewater treatment plant obtain approximately $\74.5%$ expenditure cost reduction in comparison with methanol dosage cost.

The Assessment for Environmental Stabilization in Open Dumping Landfill Site from Physical Composition and Gas Analysis - A Case Study of Noeun Landfill - (비위생 매립지의 물리적 조성 및 가스 분석을 통한 안정화 평가 - 노은 매립지 사례 연구 -)

  • Lee, Min-Hee;Jang, Byoung-In;Yun, Cheol;Yeon, Ik-Jun;Kim, Kwang-Yul
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.4
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    • pp.27-35
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    • 2005
  • A case study of the assessment for environmental stabilization in open dumping landfill site was carried out physical composition, total solid, moisture, and landfill gas(LFG) analysis in landfill site. The result of physical ratio were represented combustibles 23.64% and incombustibles 76.36%, TS 77.69%, VS 74.24%, FS 25.75%. The biodegradable organic matters were almost degraded and the result of the landfill gas showed that the $CH_4$ gas were measured as 4.5%. As the result of the assessment on the open dumping landfill it appears that this landfill is stabled for the maturation phase and formation $CO_2$ concentration lower than 15%.

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The Continuous Pyrolysis of Waste Polystyrene using Wetted-Wall Type Reactor (Wetted-Wall Column 형 반응기를 이용한 폐 EPS 연속 열분해반응)

  • Han, Myung Sook;Han, Myung Wan;Yoon, Byung Tae;Kim, Seong Bo;Choi, Myoung Jae
    • Korean Chemical Engineering Research
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    • v.45 no.4
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    • pp.396-399
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    • 2007
  • Organic residue and carbonized solid producing from the thermal degradation gave a influence on oil conversion, formation of styrene and side products such as ${\alpha}-methyl$ styrene, ethyl benzene, dimer. Thus, new reaction system using wetted-wall type reactor was proposed and examined on influence of various parameters such as reaction temperature, feeding rate and removal velocity of formed vapor. Optimum condition were obtained from continuous thermal degradation using wetted-wall type reactor and styrene was continuously obtained as the yield up 65%.

Experimental Evaluation Method of Mass Transfer Coefficient on Biotrickling Filtration for Air Pollution Control (대기오염제어를 위한 생물살수여과법에서 물질전달계수 실험평가방법에 관한 연구)

  • Won, Yang-Soo;Jo, Wan-Keun
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.482-488
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    • 2015
  • Biological treatment is promising alternative to conventional air pollution control method. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing volatile organic compounds and odor. The studies of mass transfer in biotrickling filters for air pollution control were of importance in order to control and optimize the purification process. The objectives of this study were to develop the experimental methodologies to evaluate the mass transfer coefficients of gas/liquid(trickling liquid), gas/solid(biomass) and liquid/solid in three phase biotrickling filtration. Also, this study characterized the influence factors on mass transfer such as dynamic holdup volume, gas/liquid flow rate ratio, biomass weight in reactor and recirculation rate of trickling medium for each phase of biotrickling filter.

Characterization of Microbial Community Changes in Process Affected by Physicochemical Parameters During Liquid Fertilization of Swine Waste

  • Shin, Mi-Na;Kim, Jin-Won;Shim, Jaehong;Koo, Heung-Hoe;Lee, Jai-Young;Cho, Min;Oh, Byung-Taek
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.3
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    • pp.173-181
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    • 2013
  • Livestock wastes are considered as major environmental pollutants because they contain high concentration of organic materials. In 2001, The Environmental Department reported that stock farmers were increasing as 5.1%/year, which resulted in a gradual increase in livestock wastes generation. The direct disposal of livestock wastes create several environmental problems. Thus, several countries banned the disposal of livestock wastes in environment including aquatic systems. Recently, aeration-based liquid fertilization was considered as potential way for the disposal of livestock wastes. In this study, next generation sequencing (NGS) analysis was used to understand the microbial community changes during liquid fertilization of livestock wastes. Microbial community was compared with liquid fertilizer physicochemical analysis such as $BOD_5$, $COD_{Mn}$ pH, N (Nitrogen), P (Phosphorus), K (Potassium) etc. The physicochemical parameters and bacterial community results pave the way for producing effective livestock-based fertilizer. By comparing the physical characteristics of the manure with microbial community changes, it is possible to optimize the conditions for producing effective fertilizer.

Mulberry Paper Bag μ-Solid Phase Extraction for the Analysis of Five Spice Flavors by Gas Chromatography-Mass Spectrometry

  • Yoon, Ok-Kyung;Lee, Dong-Sun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.35-42
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    • 2009
  • Headspace micro solid phase extraction using mulberry paper bag (HS-MPB-$\mu$-SPE) has been developed and validated for the analysis of volatile flavor compounds from five spice by gas chromatography-mass spectrometry (GC/MS). HS-MPB-$\mu$-SPE was performed with adsorbent particles enclosed inside a mulberry paper bag. Four different kinds of adsorbents such as Tenax TA, Porapack Q, dimethylpolysiloxane and polyethylene glycol were tested. The extraction solvents compared were petroleum ether, methylene chloride, and chloroform. Better results were obtained when Tenax TA and petroleum ether were used. The limit of detection (LOD) and the limit of quantitation (LOQ) were in the range of 1.3 ng/mL and 4.3 ng/mL, respectively, for o-cymene as a model compound of monoterpene. Proposed method showed good reproducibility (3.3%, RSD) and good recoveries (94.0%). The HS-MPB- μ-SPE is very simple to use, inexpensive, rapid, requires small sample amounts and solvent consumption. Because the solvent for extraction is reduced to only a very small volume (0.6 mL), there is minimal waste or exposure to toxic organic solvent and no further concentration step. This method allows successful characterization of the headspace in contact with the five spice sample. Strong trans-anethole from star anise or fennel is a characteristic flavor of five spice powders. HS-MPB-$\mu$-SPE combined with GC/MS can be a promising technique for the broad spectrum measurement of volatile aroma compounds from solid spices.

A Study on the Characteristics and Social Values of Vegan Fashion in H&M and Zara

  • Seo, Kyoungah;Suh, Seunghee
    • Journal of Fashion Business
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    • v.23 no.6
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    • pp.86-100
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    • 2019
  • This study analyzed the characteristics of vegan fashion produced by H&M and ZARA with respect to materials, design, development, production, and marketing to create social value. The results of this study are significant because they can be used as a reference to develop a vegan fashion market. Regarding the research method, this study assessed the concept and status of veganism through a literature review and examined vegan fashion case studies by analyzing official websites and media content. The study's scope covers the period from 2005, when H&M was the first SPA brand to create a vegan product line, until 2019. The characteristics of Global SPA's vegan fashion were as follows. Regarding materials, alternative materials were developed and an expanded use of organic materials was implemented. Regarding design, development was achieved through design collaboration and upcycling. In terms of production, an animal welfare policy was adopted and a sustainable supply chain was established. Marketing employed a campaign aimed at encouraging increased consumer participation. The findings regarding the social value of H&M and Zara's vegan fashion were as follows. First, a cyclical economy was realized through circular recycling in the entire process of resource selection, production, and waste disposal. Second, because product consumption indicated the importance of ethical consumption and sustainable consumer participation, corporate financial activities were created based on shared values to accomplish the social outcome. Third, collaborations with luxury brands or vegan fashion designers built a collaborative ecosystem in which vegan fashions were released and consumer participation campaigns were implemented.

Isolation and Characterization of a New Hydrogen Sulfide-Oxidizing Bacterium Thiobacillus Sp. (황화수소 산화세균인 새로운 Thiobacillus sp.의 분리 및 특성)

  • Cha, Jin-Myeong;Lee, In-Hwa
    • Korean Journal of Microbiology
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    • v.32 no.4
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    • pp.252-257
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    • 1994
  • A new hydrogen sulfide-oxidation bacterium, Thiobacillus sp. was isolated from waste coal mine water around Hawsun in Chunnam province. The isolate was motile gram-negative rod shape, formed spore and grew up to be aerobically facultative chemolithotroph by using energy released from the oxidation of reduced inorganic sulfur compounds. It could assimilate various kinds of organic compounds and grew well upon thiosulfate-supplemented basal medium. To the lelvel of 32 mM in thiosulfate concentration, thiosulfate in itself was utilized as energy source for growth. However, from those of the higher concentration than 32 mM, thiosulfate functioned specifically as the substrate inhibitor rather than as the energy source. It was found that the optimum thiosulfate concentration for growth was 32 mM. The G+C content of the DNA was 65.0 mol%. The isolate had 16 : 1 + 17$_{cyc}$, 16 : 0 as their major non-hydroxylated cellular fatty acids, 3-OH 12 : 0 as a hydroxylated fatty acid and also contained unidentified $C_{18}$ branched fatty acid. The ubiquinone system in the respiratory chain was Q-9. Based on the physiological and biochemical characteristics, the isolate was assigned to a novel species of the genus Thiobacillus sp. iw.

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Nitrogen Removal from Synthetic Domestic Wastewater Using the Soil Column (토양컬럼을 이용한 합성하수 중의 질소제거)

  • Cheong, Kyung-Hoon;Lim, Byung-Gab;Choi, Hyung-Il;Park, Sang-Ill;Moon, Ok-Ran
    • Journal of Environmental Science International
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    • v.16 no.6
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    • pp.707-714
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    • 2007
  • A laboratory experiment was performed to investigate nitrogen removal by the soil column. The addition of 20% waste oyster shell to the soil accelerated nitrification in soil column. The $NO_3^--N$ concentration in the effluent decreased with the decrease of HRT(Hydraulic Retention Time). When methanol and glucose added as carbon sources, the average removal rates of T-N(Total Nitrogen) were 82% and 77.9%, respectively. The $NO_3^--N$ removal by methanol supplementation in soil column can likely be attributed to denitrification. In continuous removal of nitrogen using the soil column, the COD(Chemical Oxygen Demand) and $NH_4^+-N$ removed simultaneously in organic matter decomposing column. The greater part of $NH_4^+-N$ was nitrified by the percolated through nitrification column, and the little $NH_4^+-N$ was found in the effluent. The T-N of 87.4% removed at HRT of 36 hrs in denitrfication column. Because of nitrified effluents from nitrification column are low in carbonaceous matter, an external source of carbon is required.