• Title/Summary/Keyword: Organic removal

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Preparation and Characteristics of Catalyst Coated Cordierite Filter (촉매 처리된 코디어라이트 필터의 제조 및 그 특성)

  • Kim, Yeong-Bae;Jo, Eul-Hun;Jang, Yun-Yeong;Sin, Min-Cheol;Lee, Hui-Su;Choe, Deok-Gyun
    • Korean Journal of Materials Research
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    • v.12 no.2
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    • pp.129-134
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    • 2002
  • The optimum condition for fabricating cordierite disc type filter element was deduced. Cordierite monolith was used as starting material for filter element because it has many advantages such as high thermal shock resistance and good catalytic activity compared with $TiO_2$and SiC. The contents of organic additives and foaming agent were optimized to control the porosity and mechanical strength of cordierite filter. Among the required properties to be adopted as filter elements, the pressure drop and NOx removal efficiency were investigated depending on processing variables. It was found that pressure drop depends on particle size distribution of cordierite monolith and organic additives added as forming agent. The pressure drop at 5cm/sec of face velocity was in the range of 15~655mm$H_2O$ at room temperature. The NOx removal efficiency of catalytic filter with $V_2O_5$ as catalyst was over 85% at $450^{\circ}C$.

Comparison of Phosphorus and Nitrogen Removal Characteristics between A2/O and Modified Phostrip Processes (A2/O공정과 수정 Phostrip공정과의 질소 및 인제거 특성비교)

  • Kim, Kwang-Soo;Kim, I-Tai
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.664-668
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    • 2005
  • An experimental study for the comparison of nitrogen and phosphorus removal efficiencies between $A^2/O$ and modified Phostrip (M-Phostrip process) were carried out with bench-scale reactors. In case of nitrogen removal efficiencies both of processes showed similar ones when influent organic loadings were high. However, M-phostrip process was more effective than $A^2/O$ at low organic loadings. This is why M-phostrip process consumes the whole mass of influent organics as a carbon sources for denitrification in anoxic reactor but the anoxic reactor of $A^2/O$ process utilizes the residual carbon followed by consumming a part of influent carbon for phosphorus release in anaerobic reactor. $A^2/O$ process required the influent COD/T-P and COD/TKN ratios were more than 56 and 10, respectively, to take place the phosphorus release in anaerobic process and phosphorus uptake in oxic process. However, the luxury uptake of phosphorus in M-phostrip process was not affected by influent COD/T-P and COD/TKN ratios and the adverse effect of nitrate in return sludge introduced to the p-stripper from the 2nd clarifier was not significant due to the configurational advantage of the p-stripper.

The Characteristics of SBR Treatment with Different Types of Piggery Wastewater (축산폐수성상에 따른 SBR 처리특성)

  • Jun, Byong-Hee;Poo, Kyung-Min;Kim, Yang-Hoon;Im, Jeong-Hoon;Kim, Chang-Won
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.435-440
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    • 2002
  • A pilot scale SBR (effective volume, $20m^3$) for the treatment of piggery wastewater treatment was performed with three different kinds of wastewater; fermenter effluent, scraper type and slurry type. The react phase in SBR was performed by sub-cycle operation consisting of repeated short cycle of anoxic-aerobic step. The fermenter effluent was characterized by the rapid nitrification and $NO_X-N$ accumulation due to depletion of organic matter in wastewater. The scraper type wastewater showed appropriate nitrogen removal efficiency, however, a poor response capacity for high loading rate often resulted in increased nitrogen concentration in effluent. Moreover, severe P release was the most serious problem in scraper type wastewater. SBR treated slurry type wastewater with high nitrogen removal efficiency to satisfy effluent quality requirement. It was thought that high concentration of organic matter in slurry made it possible to uptake P during SBR operation, where P concentration of 140mgP/l was decreased to 8mgP/l. As results, SBR was suitable to treat slurry type wastewater which has been discharged to the ocean till now.

Treatment Efficiency of Complex Wastewater by Fenton's Oxidation Condition (펜톤산화에 따른 복합폐수의 처리효율연구)

  • Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.32 no.5 s.92
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    • pp.446-450
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    • 2006
  • In order to treat the wastewater containing organic compound, pre-treatment system connected with MSP(molecular separation process) was investigated. With the aim of selecting an optimum process of Fenton's oxidation, removal efficiency of each process in the optimum reaction condition was recommended. The $Fe/H_{2}O_{2}$(ferric sulfate to hydrogen peroxide)reagent is referred to as the Fenton's regent, which produces hydroxyl radicals by the interaction of Fe with $H_{2}O_{2}$. The powerful oxidizing ability and extreme kinetic reactively of the hydroxyl radical was well established. Increasing dosage of $Fe/H_{2}O_{2}$ increased removal efficiency as molar ratio of $Fe/H_{2}O_{2}$ between 0.2 and 2.5. Optimum dosage of molar ratio was 1. The removal efficiency for reaction condition was increased as pH decreased when the molar ratio of $Fe/H_{2}O_{2}$ was 1.7. Fenton's oxidation was most efficient in the reaction time 35 min for complex wastewater. Also, coagulation aid experiments using kaolin resulted in 3% of kaolin dosage.

Excitation Light Source Dependence of Photo-catalytic Efficiency for Benzene Removal (벤젠제거에 대한 광촉매 효율의 여기광원 의존성)

  • Choi, Yong-Seok;Kim, Seong-Jin;Han, Young-Heon;Yu, Soon-Jae;Lee, Eun-Ah;Kim, Hak-Soo;Kim, Song-Gang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.510-514
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    • 2005
  • We have investigated the excitation-light source dependence of photo-catalytic efficiency for the benzene removal. The photo-catalytic module for the benzene removal is fabricated by a combination of GaN-based ultraviolet light-emitting diode (UV GaN-LED) and $TiO_2$ thin film coated on an aluminum plate. The benzene reduction rates of 365 nm and 375 nm modules at 60 mA junction current are approximately $8.95\;\%/Hr$ and $9.2\;\%/Hr$, respectively, which indicates that 365 nm GaN-LED is more effective than 375 nm GaN-LED. The benzene reduction efficiency is also noticeably dependent on the excitation wavelength and excitation-light power, as well as it is increased with the shorter wavelength and higher excitation power. This result exhibits that UV GaN-LED is useful to remove the volatile organic compounds (VOCs) existing in the environment.

Analysis of 4-year experimental data from water quality improvement of inflow stream in estuary using wetland (인공습지를 이용한 하구담수호 유입하천수의 4년간 실험결과 분석)

  • Kim, Hyung-Chul;Yoon, Chun-Gyeong;Han, Jung-Yoon;Lee, Sae-Bom;Shin, Hyun-Bhum
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.557-562
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    • 2005
  • The field scale experiment was performed to examine the effect of plant coverage on the constructed wetland performance and recommend the optimum development and management of macrophyte communities. Four sets(each set of 0.88ha) of wetland (0.8ha) and pond(0.08ha) systems were used. Water flowing into the Seokmoon estuarine reservoir from the Dangjin stream was pumped into wetland system. Water depth was maintained at $0.3{\sim}0.5m$ and hydraulic retention time was managed to about $2{\sim}5$ days; emergent plants were allowed to grow in the wetlands. After three growing seasons of the construction of wetlands, plant coverage was about 95%, even with no plantation, from bare soil surfaces at the initial stage. Dead vegetation affected nitrogen removal during winter because it is a source of organic carbon which is an essential parameter in denitrification. Biomass harvesting is not a realistic management option for most constructed wetland systems because it could only slightly increase the removal rate and provide a minor nitrogen removal pathway due to lack of organic carbon.

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Effect of Temperature on Removals of Organic Matter, Nitrogen and Phosphorus in MLE and M-Dephanox Processes (온도가 MLE 및 M-Dephanox 공정의 유기물, 질소 및 인 제거 효율에 미치는 영향)

  • Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.7-16
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    • 2006
  • The present study evaluated effect of temperature on removals of organic matter (C), nitrogen (N) and phosphorus (P) in Modified-Dephanox (M-Dephanox) process, which is hybrid system, comparing with those of Modified-Ludzack Ettinger (MLE) under the suspended-growth bacteria, as control. M-Dephanox process was more stable than MLE process in the removal of C, N, P, especially in nitrification, as the temperature was decreased from $25^{\circ}C$ to $16^{\circ}C$. As the temperature was decreased from $25^{\circ}C$ to $16^{\circ}C$, the removal efficiency of $NH_4{^+}-N$ of M-Dephanox process was decreased by 3.8%, but that of MLE process decreased by 25.7%. T-N removal efficiency of M-Dephanox was higher than MLE process by 27.1% and 26.9% at $25^{\circ}C$ and $16^{\circ}C$ of temperature, respectively.

Removal of Heavy Metal in Wastewater with Coffee Grounds (커피 찌꺼기를 이용한 폐수중의 중금속 제거)

  • Shin, Hyun-Gon;Kim, Choong-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.44-49
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    • 2014
  • In order to remove the heavy metals from synthetic wastewater containing Pb, Cr, and Cd, the experiment was conducted with a variety of concentration and pH by using the washed and dried coffee grounds as adsorbent. Almost of the heavy metals were removed in thirty minutes and the removal efficiency was maximized to the 80 percents following the different pH conditions. Furthermore, in the case of Cr, the removal efficiency was declined with the increasing of pH. As a result of this study, coffee grounds is proved to be a very good adsorbent to remove the heavy metals.

Removal of volatile organic compounds from air using activated carbon impregnated cellulose acetate electrospun mats

  • Patil, Kashyap;Jeong, Seonju;Lim, Hankwon;Byun, Hun-Soo;Han, Sangil
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.600-607
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    • 2019
  • Volatile organic compounds (VOCs) are released from various sources and are unsafe for human health. Porous materials are promising candidates for the adsorption of VOCs owing to their increased ratio of surface area to volume. In this study, activated carbon (AC) impregnated cellulose acetate (CA) electrospun mats were synthesized using electrospinning for the removal of VOCs from the air mixture of ACs, and CA solution was electrospun at different proportions (5%, 10%, and 15%) in a single nozzle system. The different AC amounts in the electrospun mats were distributed within the AC fibers. The adsorption capacities were measured for acetone, benzene, and dichloromethane, using quartz crystal microbalance. The results elicited an increasing adsorption capacity trend as a function of the impregnation of ACs in the electrospun mats, while their capacities increased as a function of the AC concentration. Dichloromethane resulted in a faster adsorption process than acetone and benzene owing to its smaller molecular size. VOCs were desorbed with the N2 gas purging, while VOCs were adsorbed at higher temperatures owing to the increased vapor pressures. The adsorption analysis using Dubinin-Astakhov equation showed that dichloromethane is more strongly adsorbed on mats.

Removal of Hydrogen Sulfide by Biofilter Media (담체 종류에 따른 황화수소의 제거특성)

  • Cha, Gyusuk
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.4
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    • pp.41-45
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    • 2007
  • It is very important that selection of packing media with large surface area, high limited back pressure in biofilter. The object of this study is the isolation of sulfur-oxidizing bacteria and the removal of hydrogen sulfide in biofilter by media. This investigation led to the following results: 1) we isolated Thiobacillus sp. IW. at an abandoned coal mine in Hwasun, Jeonnam Province. 2) The inorganic media showed better results than the organic media from experiments looking at removal characteristics and changes in pressure drop using various media. 3) Among the inorganic media, fibril and PU media showed best performance.

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