• 제목/요약/키워드: Organic pollutant

검색결과 308건 처리시간 0.028초

자란만 표층 퇴적물 중 유기물과 중금속 농도분포 (Distributions of Organic Matter and Heavy Metals in the Surface Sediment of Jaran Bay, Korea)

  • 황현진;황동운;이가람;김형철;권정노
    • 해양환경안전학회지
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    • 제24권1호
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    • pp.78-91
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    • 2018
  • 자란만 퇴적물 중 유기물과 중금속의 농도분포와 오염현황을 파악하기 위하여 2014년 11월 15개 정점에서 표층 퇴적물을 채취하여 입도, 총유기탄소(TOC), 총질소(TN) 및 중금속(As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Zn)을 분석하였다. 평균입도(Mz)는 8.6-9.8Ø($9.3{\pm}0.3$Ø) 사이였으며, 니(Mud)와 점토(Clay)의 세립한 퇴적물로 구성되어 있었다. TOC와 TN은 각각 1.51-2.39 %($1.74{\pm}0.22%$), 0.20-0.33 %($0.23{\pm}0.03%$)의 범위로 전반적으로 공간적인 농도차이를 보이지 않았다. 모든 퇴적물에서 C/N 비 값은 5-10 사이를 보여 자란만 표층 퇴적물 중 유기물은 주로 해역 내에서 발생한 해양기원성 유기물인 것으로 파악되었다. 중금속 중 Cr, Fe, Mn은 만의 입구 쪽에서 높고 그 외 중금속(As, Cd, Cu, Hg, Pb, Zn)은 자란만의 안쪽에서 높은 농도를 보였다. 한편, 퇴적물 기준(SQGs), 농축계수(EF), 농집지수($I_{geo}$), 오염부하량지수(PLI), 생태계위해도지수(ERI) 등 다양한 평가기법을 이용하여 자란만 표층 퇴적물의 중금속에 대한 오염정도를 살펴본 결과, Cd, Cr, Cu, Hg, Pb, Zn은 오염되지 않은 상태이거나 일부해역에서 오염된 상태를 보였지만 As는 전 해역에서 높은 오염도를 보였다. 또한, 분석된 모든 중금속 농도를 고려한 전체적인 오염도를 살펴본 결과, 모든 해역에서 중금속에 대하여 오염되었고 특히, 일부 해역에서는 저서생물에 위해성을 줄 수 있는 상태인 것으로 파악되었다. 따라서, 자란만 내 양식 수산물의 안전성 확보와 지속적인 어장 생산성 유지를 위해서 자란만 퇴적물 내 유기물과 중금속의 오염원에 대한 체계적인 관리가 필요하다.

Feeding and Management System to Reduce Environmental Pollution in Swine Production - Review -

  • Han, In K.;Lee, J.H.;Piao, X.S.;Li, Defa
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권3호
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    • pp.432-444
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    • 2001
  • In this manuscript, several effective feeding and management systems to reduce environmental pollution in swine production have been briefly introduced. It is logical that reducing the excretion of nutrients in manure should be the first step to reduce the environmental impact of pig production. it is evident that the excretion of nitrogen and phosphorus can be reduced when more digestible or available feedstuffs are used. Also, it is well known that proper feed processing can reduce anti nutritional factors (ANF) and improve nutrient digestibilities. Supplementation of effective feed additives can reduce excretion of nitrogen and phosphorus due to efficient feed utilization. These include enzymes (e.g., phytase), antibiotics, probiotics, organic acids and growth hormones ($\beta$-agonists and porcine somatotropin). One of the most effective ways to reduce pollutants from swine manure is to use synthetic amino acids in feed manufacturing. Many studies showed that reduction of 2 to 4% unit (U) of dietary protein with supplemental amino acid (AA) could dramatically reduce (15 to 20%) nitrogen excretion. Regarding feeding strategies, it has been recognized that phase feeding regimen could be used to reduce nitrogen and phosphorous excretion by feeding pigs in better agreement with age and physiological state. Feeding barrows and gilts separately, known as split sex feeding, can also decrease excretion of nitrogen and phosphorus. With the increasing concerns on the negative impact of animal production systems on the environment, animal nutritionists and producers should be aware that sustainability of animal agriculture is as important as high production performance. Therefore, some feeding and management strategies described in this manuscript will help to reduce environmental pollution in swine production. Proper combination of feeding regimen and environment-friendly diet formulation through nutritional approach will be more effective to reduce nutrient excretion in swine production system compared to single approach to do so.

Three-dimensional porous graphene materials for environmental applications

  • Rethinasabapathy, Muruganantham;Kang, Sung-Min;Jang, Sung-Chan;Huh, Yun Suk
    • Carbon letters
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    • 제22권
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    • pp.1-13
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    • 2017
  • Porous materials play a vital role in science and technology. The ability to control their pore structures at the atomic, molecular, and nanometer scales enable interactions with atoms, ions and molecules to occur throughout the bulk of the material, for practical applications. Three-dimensional (3D) porous carbon-based materials (e.g., graphene aerogels/hydrogels, sponges and foams) made of graphene or graphene oxide-based networks have attracted considerable attention because they offer low density, high porosity, large surface area, excellent electrical conductivity and stable mechanical properties. Water pollution and associated environmental issues have become a hot topic in recent years. Rapid industrialization has led to a massive increase in the amount of wastewater that industries discharge into the environment. Water pollution is caused by oil spills, heavy metals, dyes, and organic compounds released by industry, as well as via unpredictable accidents. In addition, water pollution is also caused by radionuclides released by nuclear disasters or leakage. This review presents an overview of the state-of-the-art synthesis methodologies of 3D porous graphene materials and highlights their synthesis for environmental applications. The various synthetic methods used to prepare these 3D materials are discussed, particularly template-free self-assembly methods, and template-directed methods. Some key results are summarized, where 3D graphene materials have been used for the adsorption of dyes, heavy metals, and radioactive materials from polluted environments.

산업단지 및 주거지역에 대한 환경대기 중 주요 악취물질의 농도특성에 관한 연구 - 안산시 반월공단을 중심으로 - (Odorous Pollutant Concentration Levels in the Ban-Wall Industrial Area and Its Surrounding Regions)

  • 최여진;김기현;전의찬
    • 한국지구과학회지
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    • 제27권2호
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    • pp.209-220
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    • 2006
  • 본 연구에서는 악취민원이 빈발한 경기도 안산시에 위치한 반월공단의 주거지역과 공단지역 등을 중심으로 주요 관리대상으로 설정된 악취성분들에 대한 환경대기 중 농도분포 특성을 2년여 기간동안 6차례에 걸쳐 조사하였다. 이들의 거동을 이해하기 위해, 시간적(오전과 오후) 및 공간적(공단 내외부의 위치) 기준으로 분포특성에 대한 비교를 시도하였다. 그 결과, 오전시간대에 비해 오후시간대에 고농도 분포가 현저하게 높은 것으로 나타났다. 이와 유사하게 공간적인 기준으로 비교한 결과도 공단 내부에서 관측한 결과에서 대부분의 성분들이 고농도를 유지하는 것을 확인할 수 있었다. 본 연구의 결과는 안산시 주변 및 공단지역의 환경대기 중에 존재하는 악취성분들이 시간적 및 공간적 기준으로 다양한 분포특성을 취한다는 것을 보여주었다.

A Study on the Discharge of Volatile Organic Compounds in Indoor Air of Newly-constructed Apartment Houses

  • Ryu, Jung-Min;Jang, Seong-Ki;Yang, Won-Ho;Cho, Tae-Jin;Son, Bu-Soon
    • 한국환경과학회지
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    • 제18권5호
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    • pp.479-487
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    • 2009
  • Because of the building is made airtight, Indoor Air Quality(IAQ) is go from bad to worse. There are many source of indoor pollution in any home. These include irritation of the eyes, nose, and throat, headaches, dizziness, and fatigue. Such immediate effects are usually short-term and treatable. In this study was measured and analyzed VOCs exposure levels and characteristic of Indoor air pollutant from new apartments in Korea. VOCs were measured indoor pre-residential and residential in new apartment and analyzed GC/MS. The concentration levels of indoor respirable TVOC were found to be higher than those of outdoor TVOC for new apartments. Before occupation, the average indoor and outdoor concentrations were 1498.61 $ug/m^3$ and 468.38 $ug/m^3$, respectively. After being occupied, the average indoor and outdoor concentration were 847.04 $ug/m^3$ and 102.84, respectively. The concentrations of TVOC in new apartments before occupation were shown in the order of Toluene(328.12 $ug/m^3$) > m,p-Xylene(163.67 $ug/m^3$) > Ethy1benzene(80.70 $ug/m^3$>o-XYlene (67.04$ug/m^3$). In addition, the TVOCs concentrations after occupation were also found in the order of Toluene (272.28 $ug/m^3$) > m.p-Xylene(121.79 $ug/m^3$) > Ethylbenzene(53.92 $ug/m^3$)>O-Xylene(24.94 $ug/m^3$). As a result, the concentrations of VOCs in new apartment houses were shown to be affected by indoor environment according activity patterns. So new apartments need to be controled in indoor air quality so that the residents can have more comfortable and healthier living environment.

흡연시 발암성 물질의 체내 잔존율에 대한 연구 - 주요 휘발성 유기화합물을 중심으로 (Studies on the body - retaining rate of smoking-related carcinogens using some important volatile organic compounds (VOC))

  • 김기현;최여진;홍윤정;양혜순;이진홍;이용기
    • 분석과학
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    • 제17권5호
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    • pp.410-415
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    • 2004
  • 본 연구에서는 담배 흡연과 관련된 유해성분들의 발생특성을 비교하기 위하여, BTEX를 위시한 주요 방향족 VOC 성분과 포름알데하이드와 아세트알데하이드를 포함하는 카보닐 화합물의 분포특성을 다각도로 비교하고자 하였다. 이를 위해, 직접흡연에 해당하는 exhaled mainstream smoke (EMS)와 간접흡연에 해당하는 side-stream smoke (SS) 시료 등을 분석하고, 이들의 농도분포를 비교하였다. 필터를 제거한 상태에서 흡입되는 담배 연기의 경우, 유해한 성분들이 수 백 ppm 수준의 고농도로 존재한다는 것을 확인하였다. 반면, 흡연자가 비흡연시에도 날숨을 통해 이들 성분을 수 십에서 수 백 ppb의 농도로 배출하는 것을 확인할 수 있었다. 이러한 분석결과와 날숨과 들숨의 관계로부터 주요 흡연성분들의 체내 잔류율 등을 유추해 보았다. 이러한 추정에 의하면, 방향족 및 카르보닐 성분들의 대부분이 99% 이상 체내에 잔류할 수 있다는 것을 확인하였다.

Effects of Benzene, Phenol and Hydroquinone on Proliferation, Differentiation and Migration of Human Eosinophilic EoL-1 Cells

  • Moon, So-Hee;Yang, Eun-Ju;Song, Bo-Bae;Kim, Bo-Mi;Lee, Ji-Sook;Kim, In-Sik
    • 대한의생명과학회지
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    • 제16권3호
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    • pp.179-185
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    • 2010
  • Benzene is known as a ubiquitous air pollutant and has a carcinogenic influence on the human body. Benzene is also metabolized to other volatile organic compounds (VOCs) in the body such as phenol and hydroquinone (HQ). The metabolites are accumulated and further oxidized by myeloperoxidase in bone marrow. They act as toxic agents and cause a variety of diseases, including cancer, atopic dermatitis and asthma. In this study, we examined the effects of benzene and its metabolites on proliferation, differentiation and chemotaxis of EoL-1 cells, the human eosinophilic leukemia cell line. These chemicals had no effect on the proliferation of EoL-1 cells. Benzene decreased the differentiation of EoL-1 cells induced by butyric acid. HQ was induced the cell death during butyric acid-induced EoL-1 cell differentiation. In a chemotaxis experiment, benzene, phenol and HQ enhanced the cell migration induced by Lkn-1 but not by MCP-1, eotaxin, MIP-$1{\alpha}$ and RANTES. These findings provide the effect of VOCs on the regulation of eosinophil-involved immune response.

에어로졸의 준실시간 관측에 의한 여름철 도시지역 시정 감쇄 현상의 광ㆍ화학적인 특성 분석 (Opto-Chemical Characteristics of Visibility Impairment Using Semi-Continuous Aerosol Monitoring in an Urban Area during Summertime)

  • 김경원;김영준
    • 한국대기환경학회지
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    • 제19권6호
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    • pp.647-661
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    • 2003
  • For continuous monitoring of atmospheric visibility in the city of Kwanaju, Korea, a transmissometer system consisting of a transmitter and a receiver was installed at a distance of 1.91 km across the downtown Kwanaju. At the transmitter site an integrating nephelometer and an aethalometer were also installed to measure the scattering and absorption coefficients of the atmosphere, respectively. At the receiver site. an URG PM$_{2.5}$ cyclone sampler and an URG-VAPS (Versatile Air Pollutant Sampler) with three filter packs and two denuders were used to collect both PM$_{2.5}$ and PM$_{10}$ samples at a 2-hour or 12-hour sampling interval for aerosol chemical analysis. Sulfate, organic mass by carbon (OMC), nitrate, elemental carbon (EC) components of fine aerosol were the major contributors to visibility impairment. Diurnal variation of visibility during best-case days showed rapid improvement in the morning hours, while it was delayed until afternoon during the worst-case days. Aerosol mass concentration of each aerosol component for the worst-case was calculated to be 11.2 times larger than the best-case for (NH$_4$)$_2$SO$_4$(NHSO), 19.0 times for NH$_4$NO$_3$ (NHNO), 2.2 times for OMC, respectively. Also result shows that elemental carbon and fine soil (FS) were 3.7 and 2.2 times more than those of best-case. respectively- Sum of total contributions of wet NHSO and NHNO to light extinction was calculated to be 301 Mm$^{-1}$ for the worst-case. However, sum of contributions by dry NHSO and NHNO was calculated to be 123 Mm$^{-1}$ for the best case. Mass extinction efficiencies of fine and coarse particles were calculated to be 5.8$\pm$0.3 $m^2$/g and 1.8$\pm$0.1 $m^2$/g, respectively.ely.

토양 중 미규제된 유기오염물질 분석연구 (다환방향족탄화수소 16종을 중심으로) (Research on the Analysis of Unregulated Organic Pollutant Compounds in Soil (Focusing on 16 Polycyclic Aromatic Hydrocarbons))

  • 김종향;강종민;이방희;허종수
    • 한국응용과학기술학회지
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    • 제28권1호
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    • pp.64-74
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    • 2011
  • The aim of study was to investigate polluted amounts 16 PAHs in railroad(waste railway ties) area, factory area and land-fill area. All of the samples were analyzed by GC-MSD(SIM mode), and the recovery range, detection limit and standard deviation obtained by this experiment were 73.88 ~ 94.75%, 0.009 ~ 2.252 ${\mu}g$/kg and 1.861 ~ 12.373, respectively. The concentrations of total PAHs(t-PAHs) and total carcinogenic PAHs(t-PAHcarc) in soils of three area were in the range of 12.54 ~ 3274.95 ${\mu}g$/kg on a wet weight basis with a mean value of 499.8 ${\mu}g$/kg and 0 ~122.77 ${\mu}g$/kg with a mean value of 20.16 ${\mu}g$/kg, respectively. The correlation between t-PAHs and t-PAHcarc appeared very high in railroad(waste railway ties) area ($R^2$ = 0.8301), factory area ($R^2$ = 0.9217) except land-fill area($R^2$ = 0.3782), indicated that t-PAHcarc concentration increases in proportion with t-PAHs.

모악 금·은광산에 방치된 폐석이 주변 수계 및 생태계에 미치는 환경적 영향 (Environmental Effects on the Hydrologic and Ecologic System around the Wasted Ore Dump of the Moak Gold-Silver Mine)

  • 나춘기;전서령
    • 자원환경지질
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    • 제28권3호
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    • pp.221-229
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    • 1995
  • The heavy metal contents and their dispersion patterns in stream water, stream sediments, land plants and aquatic larvae collected from the hydrologic system flowing via the wasted ore dump of the Moak Au-Ag mine were investigated systematically in order to evaluate the environmental impacts of the abandoned metal mine. The heavy metal content increases abruptly in the vicinity of the wasted ore dump, then attenuated with increasing distance from the mine area. Attenuating rates were stream water > stream sediments > land plants > aquatic larvae. On the other hand, the cumulative content of heavy metals was stream sediments >aquatic larvae > land plants > stream water. Each element tends to be enriched selectively according to media; Zn > Cu > Cd > Pb in stream water, Zn > Pb > Cu > Cd in stream sediments and land plants, and Zn > Cu > Pb > Cd in aquatic larvae. These results show that the degree of enrichment and dispersion of pollutant extruded from the wasted ore dump are different according to elements and media, and that the circulation system of materials of each medium is different. The heavy metals, especially Cu, Pb and Zn, of polluted downstream sediments occur in high proportions of Fe-Mn oxides and organic bounded forms, which show high potential of a secondary pollution source. The content of heavy metals and their dispersion patterns in stream sediments are different from those of ten years ago; pollution levels of heavy metals were degraded in various ranges. The Zn and Cu-polluted areas were widened whereas Fe and Pb-polluted areas were reduced. In crops collected from the farm lands in downstream area, the pepper was more concentrated in all heavy metal than rice. The pepper showed some contaminated level in Cu(9.7ppm) and Zn(149ppm), and the rice in Zn(90ppm). However, both crops showed no significant level in Cd(<0.2ppm) and Pb(<0.5ppm).

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