• 제목/요약/키워드: Organic monolayer

검색결과 149건 처리시간 0.031초

포화지방산계 LB막의 수평방향에 대한 전기적 특성 비교 (A Comparison to Electrical properties of Fatty Acid System LB Films in Horizontal Direction)

  • 김도균;최용성;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.194-197
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    • 1997
  • The LB technique is one of the most powerful fabricating methods of organic ultra-thin film, which deposits a monolayer films in molecular level on the surface of the substrate. We have investigated the electrical characteristics of Myristic acid, Stearic acid and Arachidic acid LB films for horizontal direction to develop for the gas sensor. The optimum conditions for a film deposition were obtained by measurement of $\pi$-A isotherm. The status of the deposited film was confirmed by measurement of UV absorbance. We could distingished the difference of I-V characteristics for the fatty acid for the horizontal direction. The conductivity of fatty acid LB films for horizontal direction was 10$^{-7}$ ~ 10$^{-9}$ [S/cm] that mean like semiconductor.

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Performance Improvement of Organic Thin Film Transistors with Self-Assembled Monolayer Formed by ALD

  • Kim, Hyun-Suck;Park, Jae-Hoon;Bong, Kang-Wook;Kang, Jong-Mook;Kim, Hye-Min;Choi, Jong-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1166-1169
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    • 2006
  • In this study, the effects of SAMs on the performance of OTFTs have been investigated. ALD technique was applied for the deposition of SAMs, which is an ultra-thin film deposition technique based on sequences of self-limiting surface reactions enabling thickness control on atomic scale. According to our investigation results, it is observed that the surface properties of the gate insulator was changed by SAMs, which allow pentacene molecules to be deposited in the upright direction on the gate insulator and hence the performance of OTFTs could be improved. These results will be discussed

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STM을 이용한 Dipyridinium 유기 단분자막의 모폴로지 관찰 및 전기적 특성 연구 (Study on the Mophology Observation and Electrical Properties of Dipyridinium Organic Monolayer Using STM)

  • 이남석;신훈규;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권2호
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    • pp.51-54
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    • 2005
  • In this work, the attempt has been made to investigate the morphology of self-assembled dipyridinium dithioacetate on Au(111) substrate by Scanning Tunneling Microscopy(STM). Also, we measured electrical properties(I-V) using Scanning Tunneling Spectroscopy(STS). Sample used in this experiment is dipyridinium dithioacetate, which contains thiol functional group, this structure that can be self-assembled easily to Au(111) substrate. The self-assembly procedure was used for two different concentrations, 0.5 mM/ml and 1 mM/ml. Dilute density of sample by 0.5 mM/ml, 1 mM/ml and observed dipyridinium dithioacetate's image by STM after self-assembled on Au(111) substrate. The structure of STM tip-SAMs-Au(111) substrate has been used measurement for electrical properties(I-V) using STS. The current-voltage(I-V) measurement result, observed negative differential resistance(NDR) properties.

SAW 디바이스를 이용한 냄새물질 측정 및 냄새센서 시스템의 연구 (Detection of odorants and study on the odorant sensor system by using SAW device)

  • 장상목;김기영;김종민;최용성;권영수
    • E2M - 전기 전자와 첨단 소재
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    • 제8권1호
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    • pp.48-55
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    • 1995
  • A surface acoustic wave (SAW) sensor for the detection of odorants has been constructed by depositing various phospholipids and fatty acids onto the surface of the SAW device. The characteristics of a SAW device operating at 310 MHz deposited with silicon monoxide were analyzed. Menthone, amylacetate, acetoin, and other organic gases show different affinities to the coated lipids. An explanation is given for different odorant affinities based on the monolayer properties of phospholipids. The identification of odorants depending on the tkpe of lipid used for coating is discussed in terms of the similarity of their normalized resonant frequency shift patterns. Using a number of different lipid-coated SAW devices, odorants can be identified by a computerized pattern recognition algorithm.

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수면상 단분자박의 거동에 의한 변위전류 측정 (Measurement of the displacement current induced by the dynamic behavior of monolayer at the water surface.)

  • 박태곤;박근호;권영수;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 춘계학술대회 논문집
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    • pp.122-125
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    • 1993
  • We investigated the structural changes of the organic molecules of azobenzene-containing long-chain fatty acids which show the cis-trans photo-isomerization characteristics. The dynamic behavior of these polar molecules on the water surface of the Kuhn type LB deposition apparatus was detected electrically by using the displacement current method.

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$D_2$ Adsorption on Ti-deposited Metal Organic Frames

  • 사공길;이지화
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.312-312
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    • 2011
  • 초고진공 장치 내에서 질량분석기와 티타늄 증착기를 이용하여 IRMOF-3에 증착된 티타늄과 수소 간의 흡착 특성을 TPD (Temperature Programmed Desorption)을 통하여 연구하였다. 티타늄을 흡착시키지 않은 순수한 IRMOF-3에 35K에서 주입한 중수소에 대한 TPD 데이터에서는 중수소가 저온 장치에 물리흡착된 약 50K에서의 작은 피크 이외에는 다른 흡착 특성을 보이지 않는다. 하지만 티타늄 2ML (Monolayer)를 흡착 시킨 IRMOF-3의 TPD 데이터에서는 약 60K와 95K에서의 두 피크가 보인다. 이는 분산된 티타늄과 중수소 사이에는 0.16eV와 0.25eV의 결합에너지를 가지는 두 가지의 다른 결합이 있다는 사실을 보여준다. 그리고 40K~110K에서 수소와 HD는 나오지 않고, 중수소만 나온 점은 주입한 중수소가 IRMOF-3에 분산된 티타늄에 쿠바스 상호작용에 의하여 분자상태로 화학 흡착되어 있을 것이라는 증거가 된다.

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SAW 디바이스를 이용한 냄새센서의 특성 (Characteristics of odorant sensor using SAW Device)

  • 김기영;김종민;신훈규;최웅성;권영수;장상목
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1457-1459
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    • 1994
  • A surface acoustic wave(SAW) sensor for the detection of odorants has been constructed by depositing various phospholipids and fatty acids onto the surface of the SAW device. Applying the Langmuir-Blodgett technique, it was possible to deposit the optimal number of layers which was found to be between 10 and 20. Menthone, amylacetate, acetoin, and other organic gases showed different affinities to the coated lipids. An explanation is given for different odorant affinities based on the monolayer properties of phospholipids.

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Polyimide 터널 장벽을 이용한 Au/polyimide/유기 단분자막/Pb 구조에서 비탄성 전자 터널링에 관한 연구 (Inelastic Electron Tunneling in Au/polyimide/monolayer Organic Film/Pb Structures using a Polyimide Barrier)

  • 이호식;이원재;장경욱;최명규;이성일;김태완;;이준웅
    • 한국전기전자재료학회논문지
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    • 제17권2호
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    • pp.196-200
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    • 2004
  • Using polyimide Langmuir-Blodgett(LB) films as a tunneling harrier, we fabricated Au/Polyimide/1-layer arachidic acid/Pb structure in order to investigate electron transport properties through a junction. It was found that 9-layer polyimide LB films function as a good tunneling harrier in a study of current-voltage(I-V) chararteristics. And several peaks originating in the vibrational modes of the constituent molecules of 1-layer arachidic acid LB films were clearly observed in d$^2$V/dI$^2$- V corves.

열자격 변위 전류법에 의한 인지질막의 구조 연구 (A study on the structural of phospholipid membranes by thermally stimulated displacement current method)

  • 이경섭;김우연;권영수;이준응;강도열
    • E2M - 전기 전자와 첨단 소재
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    • 제9권7호
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    • pp.696-701
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    • 1996
  • In this study, deposited lipid membranes on the electrode and detected thermally stimulated displacement current generated from it. The researchers examined displacement current of electric conduction organic monolayer generated due to orient change of monolayers alkylchain and changed of dipole moment vertical component due to thermally stimulated. We paid attention to the phase transition temperature obtained by the thermally stimulated displacement current of lipid membrane layers this time. We detected the thermally stimulated displacement current peak of layers. From above results the transition temperature dilauroylphosphatidylcholine layers is about 43.deg. C. This study also compared above results with those obtained by differential thermal analysis method.

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유기박막의 자격속도에 따른 응답특성에 관한 연구 (A Study on the Response Characteristic by Stimulus Speed of Organic Thin Films)

  • 조수영;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.385-388
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    • 1997
  • We hate examined the electrical properties of L-${\alpha}$-DLPC Langmuir(L) films by using a displacement current measuring technique with pressure stimulation. Displacement current was generated when the sample spread volume was about 280${\mu}\ell$, 360${\mu}\ell$ and compression velocity was about 30, 40, 50mm/min. Displacement current was generated in the range of gas state, gas/fluid state and fluid state in the course of monolayer compression. From the result, it is known that displacement current is generated in the range of high surface pressures as compression velocity become faster.

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