• Title/Summary/Keyword: Organic glasses

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Review of the Polycarbonate (Polycarbonate의 고찰)

  • Choi, Gei-Hun
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.313-322
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    • 2004
  • Glasses are to be classified in organic glasses and inorganic glasses. Generally, we just call glasses instead of calling inorganic glasses and call synthetic resin or plastic instead of calling organic glasses. One of the ophthalmic plastic glasses develops into polycarbonate resin in organic glasses. Recently, polycarbonate resin is widely known because it has larger index and impact than plastic lens. Ours study analyzed about polycarbonate resin in ophthalmic substance.

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Photochromism of Diarylethene-Doped Organic-Inorganic Hybrid Low Melting Glass (Diarylethene이 첨가된 저융점 유-무기 하이브리드 유리의 광변색 특성)

  • Kim, Ji-Kyung;Kim, Myeong-Jeong;Park, Sung-Je;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.28-32
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    • 2006
  • Diarylethene in photochromic materials was doped in organic-inorganic hybrid low-melting glasses were synthesized through a nonaqueous acid-base reaction process, which consists of network units including a small number of bridging oxides. The organic phase is a dichlorodimethylsilane while the inorganic phase is a tin(II) chloride. Diarylethene was incorporated into the glasses without any degradation of its functionality. The open form of diarylenthene, which is converted from the opening one upon UV-irradiation, is change to the closed form visible light-irradiation. The rate constant of the photochemical reaction is $31.78\times10^{-3}s^{-1}$ with 400 W UV lamp irradiation.

Synthesis and Characterization of Bifunctional Organic-Glasses Based on Diphenylhydrazone and Barbituric Acid Derivative for Photorefractive Application

  • Lee, Sang-Ho;Choi, Chil-Sung;Kim, Nak-Joong;Choi, Dong-Hoon;Park, Ki-Hong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.12
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    • pp.1793-1798
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    • 2003
  • A series of amorphous molecules that possess both photoconductive and electro-optic properties was synthesized in order to investigate photorefractive properties of bifunctional organic-glasses. Diethylaminobenzaldehyde-diphenylhydrazone was covalently attached to 5-(4-diethylamino-benzylidene)-1,3-dimethylpyrimidine-2,4,6-trione through a flexible alkyl chain (3, 4, 5, 6 and 10 carbons) containing two ether linkages. The longer linkage not only lowered the glass transition temperature ($T_g$) of the molecules, but also allowed faster orientation of the chromophore. To examine the photorefractive properties, a 50 ${\mu}$m-thick film was prepared from the mixture of a bifunctional molecule, butyl benzyl phthalate, and $C_{60}$. The photoconductivity of this composite was as high as $8.01\;{\times}\;10^{-12}$ S/cm at 60 V/ ${\mu}$m, and the maximum diffraction efficiency ( ${\eta}_{max}$) of 50 ${\mu}$m-thick film was about 5% at 80 V/ ${\mu}$m.

Effects of Chalcogenide Glasses Thin Film Encapsulation Layer on Lifetime of Organic Light Emitting Diodes

  • Fanghui, Zhang;Jianfei, Xi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.839-842
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    • 2009
  • In this paper, chalcogenide glasses material(Se, Te, Sb) is firstly used as encapsulation layer of OLEDs under high vacuum of $10^{-4}$Pa. In the experiments, properties of OLEDs encapsulated by Se, Te, Sb thin film is compared with that of device encapsulated by traditional method. It is found that Se, Te, Sb film can extend lifetime of devices to 1.4, 2, 1.3 times respectively. Chalcogenide glasses film as encapsulation layer has little effect on some characteristics of device. The research indicated that OLEDs can be well protected upon applying Se, Te, Sb film as encapsulation layer. It is clear that it can prolong the lifetime obviously.

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Synthesis of Glasses from Metal Alkoxide (금속 알콕시드로부터 유리의 합성에 관한 연구)

  • 최석진;김병훈
    • Journal of the Korean Ceramic Society
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    • v.21 no.2
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    • pp.127-134
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    • 1984
  • Basic research on the formation of monolithic glasses from metal alkoxide has been done concerning gelling of silicon alkoxides and dehydration of those gells. The felling time were increased with increasing of Carbon number of alkyl radical of alkoxide and am-ount of water and the lower pH value of water. Large portions of water and organic materials were rem-oved below 25$0^{\circ}C$ and shrinkage of glass took place above 80$0^{\circ}C$ Therefore heating up to 25$0^{\circ}C$ and above 75$0^{\circ}C$ must be done gradually with rate of 0.5$^{\circ}C$/min.

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Photodegradation of Volatile Organic Compound (VOC) Through Pure TiO2 and V-Doped TiO2 Coated Glasses

  • Moon, Jiyeon;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.425.2-425.2
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    • 2014
  • $TiO_2$ possesses great photocatalytic properties but absorbs only UV light owing to high band gap energy (Eg = 3.2 eV). By narrowing the band gap through doping a metal ion, the photocatalytic activity can be enhanced in condition of the light of a higher than 365 nm wavelength. Main purpose for this study is to evaluate the activities of metal doped $TiO_2$ for degrading the volatile organic compounds (VOCs); p-xylene is chosen in the VOC removal test. Vanadium is selected in this study because an ionic radius of vanadium is almost the same as titanium ion and vanadium can be easily doped into $TiO_2$. V-doped $TiO_2$ was synthesized by sol-gel methods and compared with pure $TiO_2$. Pure TiO2 powder and V-doped $TiO_2$ powder were coated on glasses by spray coating method. UV-Visible spectrophotometer was used for the measurement of the band gap changes. VOC concentration degradation level was tested with using various UV light sources in an enclosed chamber. Catalytic activities of prepared samples were evaluated based on the experimental results and compared with coated pure $TiO_2$ sample.

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Regulation of precursor solution concentration for In-Zn oxide thin film transistors

  • Chen, Yanping;He, Zhongyuan;Li, Yaogang;Zhang, Qinghong;Hou, Chengyi;Wang, Hongzhi
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1300-1305
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    • 2018
  • The tunable electronic performance of the solution-processed semiconductor metal oxide is of great significance for the printing electronics. In current work, transparent thin-film transistors (TFTs) with indium-zinc oxide (IZO) were fabricated as active layer by a simple eco-friendly aqueous route. The aqueous precursor solution is composed of water without any other organic additives and the IZO films are amorphous revealed by the X-ray diffraction (XRD). With systematic studies of atomic force microscopy (AFM), X-ray photoemission spectroscopy (XPS) and the semiconductor property characterizations, it was revealed that the electrical performance of the IZO TFTs is dependent on the concentration of precursor solution. As well, the optimum preparation process was obtained. The concentrations induced the regulation of the electronic performance was clearly demonstrated with a proposed mechanism. The results are expected to be beneficial for development of solution-processed metal oxide TFTs.

Variable surface coatings composed of organic-inorganic hybrid polymers

  • Kessler, Daniel;Bahnmuller, Stefan;Theato, Patrick
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.315-315
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    • 2006
  • A variable surface coating with the potential to fulfill the requirements of industry will be presented. Via controlled radical polymerization methods from a functionalized Polymethylsilsesquioxane delivers an inorganic-organic block copolymer, which can be easily modified and tuned for different applications. Spin coated or dip coated on various substrates show promising results. By using different block copolymers the contact angle on a silicon wafer can be varied in a range of $90^{\circ}\;up\;to\;145^{\circ}$ After curing and complete condensation a perfect adhesion on glasses, plastics and metals is achieved.

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Study on the Eco-friend Frame Sheet with Improved Glasses Temple's Insertion-processibility by Blending Plasticizer of High Specific Heat (친환경 안경테 판재의 심입 가공성 향상을 위한 고비열 가소제 혼입에 관한 연구)

  • Seo, Young Min;Lee, Hae Sung;Lee, Sung Jun;Jung, Sang Won;Kim, Hyun-Chul;Kim, Eun Joo;Go, Young Jun;Choi, Jin Hyun;Lee, Se Guen
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.1
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    • pp.11-17
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    • 2013
  • Purpose: To improve glasses temple's insert processibility of CA/PEG blend, triacetin with higher specific heat values in the processing temperature range is used as second plasticizer. Methods: The total amount of plasticizer is fixed at 30 wt% by CA. To determine optimal CA/PEG/triacetin blend for glasses frame, blends with different composition ratio were examined by various analysis: thermal properties, mechanical properties, glossiness. Results: Specific heat of the CA/PEG blend increased as the content of triacetin. In CA/PEG/triacetin blends, as triacetin concentration is increased, glass transition temperature is decreased and heat conservation rate of composites is increased. Furthermore, CA/PEG/triacetin blend exhibited higher mechanical properties and similar gloss characterization with CA/PEG blend. Conclusions: It is possible to improve the processibility inserting metal support to CA temple through varying the weight ratio of PEG/triacetin. The extruded sheets of CA/PEG/triacetin blend had better glossiness and mechanical properties than those of CA/PEG blend.

Development of IGZO TFTs and Their Applications to Next-Generation Flat-Panel Displays

  • Hsieh, Hsing-Hung;Lu, Hsiung-Hsing;Ting, Hung-Che;Chuang, Ching-Sang;Chen, Chia-Yu;Lin, Yusin
    • Journal of Information Display
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    • v.11 no.4
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    • pp.160-164
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    • 2010
  • Organic light-emitting devices (OLEDs) have shown superior characteristics and are expected to dominate the nextgeneration flat-panel displays. Active-matrix organic light-emitting diode (AMOLED) displays, however, have stringent demands on the performance of the backplane. In this paper, the development of thin-film transistors (TFTs) based on indium gallium zinc oxide (IGZO) on both Gen 1 and 6 glasses, and their decent characteristics, which meet the AMOLED requirements, are shown. Further, several display prototypes (e.g., 2.4" AMOLED, 2.4" transparent AMOLED, and 32" AMLCD) using IGZO TFTs are demonstrated to confirm that they can indeed be strong candidates for the next-generation TFT technology not only of AMOLED but also of AMLCD (active-matrix liquid crystal display).