• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.53-54
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• 2005

We report on plasma damage free-sputtering technologies for organic light emitting diodes (OLEDs), organic thin rim transistor (OTFT) and flexible displays by using a box cathode sputtering (BCS) method. Specially designed BCS system has two facing targets generating high magnetic fields ideally entering and leaving the targets, perpendicularly. This target geometry allows the formation of high-density plasma between targets and enables us to realize plasma damage free sputtering on organic layer without protection layer against plasma. The OLED with top cathode prepared by BCS shows electrical and optical characteristics comparable to OLED with thermally evaporated Mg-Ag cathode. It was found that TOLED with ITO or IZO top cathode layer prepared by BCS has much lower leakage current density ($1\times10^{-5}$ mA/cm2 at -6V) than that ($1\times10^{-1}\sim10^{\circ}mA/cm^2$)of OLED prepared by conventional DC sputtering system. This indicates that BCS technique is a promising electrode deposition method for substituting conventional thermal evaporation and dc/rf sputtering in fabrication process of organic based optoelectronics.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.152-152
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• 2016

We studied the effect of the silver grid size on graphene transparent conducting films for flexible organic solar cells (OSCs). The silver grid was used an assistant layer of the graphene to reduce the sheet resistance of substrates. Silver grid with various graphene sizes for optimizing transmittance and sheet resistance of substrates were fabricated on polyethylene terephthalate (PET) substrates to form the hybrid films. The optimized grid geometry on the single layer graphene (SLG) was the grid dimension $200{\mu}m{\times}200{\mu}m{\times}50nm{\times}2{\mu}m$ (length ${\times}$ width ${\times}$ height ${\times}$ linewidth), where the sheet resistance was $55.73{\Omega}/square$ with the average transmittance of ~ 92.83 % at 550 nm. The properties of the OSCs fabricated using SLG with optimized silver grids on PET substrates show a short circuit current of $10.9mA/cm^2$, an open circuit voltage of 0.58 V, a fill factor of 60.8 %, and a power conversion efficiency (PCE) of 3.9 %. The PCE was improved about 91% than that of the OSCs using the SLG without the silver grid. These results demonstrate that the optimized grid geometry to the based on the graphene transparent electrodes contribute to improving the performance of OSCs.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.1
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• pp.40-46
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• 2007

A laboratory scale experiment on phenol conversion properties by pulsed corona discharge process was carried out. Effects of operating parameters such as applied voltage, input oxygen, and electrode geometry on phenol conversion and solution properties were investigated. Electrical discharges generated in liquid phase increased the liquid temperature by heat transfer from current flow, decreased the pH value by producing various organic acids from phenol degradation, and increased conductivity by generating charge carriers and organic acids. The oxygen supply enhanced the phenol conversion through the ozone generation dissolution and the production of OH radicals. Series type electrode configuration induced more ozone production than reference type configuration because it produced gas phase discharges as well as liquid phase discharges. Therefore, the higher phenol conversion and TOC(total organic carbon) removal efficiency were obtained in series type configuration.

• Journal of Environmental Health Sciences
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• v.35 no.6
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• pp.500-509
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• 2009

Passive samplers have been used for many years for the sampling of organic vapors in work environment atmospheres. Currently, all passive samplers used in domestic occupational monitoring are foreign products. This study was performed to evaluate variable parameters for the development of passive organic samplers, which include the geometry of the device and diffusive length for the sampler design. Four prototype diffusive lengths; A-1(4.5 mm), A-2(7.0 mm), A-3(9.5 mm), A-4(12.0 mm) were tested for adsorption performances to a chemical mixture (benzene, toluene, trichloroethylene, and n-hexane) according to the US-OSHA's evaluation protocol. A dynamic vapor exposure chamber developed and verified by related research was used for this study. The results of study are as follows. The results in terms of sampling rate and recommended sampling time test indicate that the most suitable model was A-3 (9.5 mm diffusive lengths on both sides) for passive sampler design in time weighted average (TWA) assessment. Sampling rates of this A-3 model were 45.8, 41.5, 41.4, and 40.3 ml/min for benzene, toluene, trichloroethylene, and n-hexane, respectively. The A-3 models were tested on reverse diffusion and conditions of low humidity air (35% RH) and low concentrations (0.2 times of TLV). These conditions had no affect on the diffusion capacity of samplers. In conclusion, the most suitable design parameters of passive sampler are: 1) Geometry and structure - 25 mm diameter and 490 $mm^2$ cross sectional area of diffusion face with cylindrical form of two-sided opposite diffusion direction; 2) Diffusive length - 9.5 mm in both faces; 3) Amount of adsorbent - 300 mg of coconut shell charcoal; 4) Wind screen - using nylon net filters (11 ${\mu}m$ pore size).

• Journal of The Korean Digital Architecture Interior Association
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• v.6 no.1
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• pp.25-32
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• 2006

This paper is a study on the anthroposophic characteristics shown in the first Goetheanum. Rudolf Steiner promoted anthroposophy base on the critique of modem times. His philosophy has developed in various areas such as medical science, agriculture, education, and art. In particular, his thinking was well expressed in the first Goetheanum which was built for Anthroposophical Society. The anthrososophic architectural theory is defined here as application of cosmology, metamorphology and geometry. Steiner defined geometry as a unconscious awareness inscribed in skeletal system of human body as humans have evolved in the process of cosmological development. As a result, Steiner's architecture was able to create metamorphological spaces with harmonizing geometric and organic factors. In respect of decoration, the shapes of plants applied to the decoration still kept individuality because of being made manually, thus perfect symmetrical architecture was impossible. Moreover, the first Goetheanum placed an emphasis on formative dynamics. This was to wake an individual's self-conscienceless up, by enabling him to experience with all the senses without reasoning from the precedent.

• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.634-637
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• 2005

Hydrogen adsorption mechanism onto the porous metal-organic frameworks (MOFs) has been studied by density functional theory calculation. The selected functionals for the predict ion of interact ion energies between hydrogen and potential adsorption sites of MOF was utilized after the evaluation with the various functionals for interaction energy of $H_2C_6H_6$ model system the adsorption energy of hydrogen molecule into MOF was investigated with the consideration of the favorable adsorption sites and the orientations. We also calculated the second favorable adsorption sites by geometry optimization using every combination of two first absorbed hydrogen molecules. Based on the calculation of first and second adsorption sites and energies, the hydrogen adsorption into MOF follows a cooperative mechanism in which the initial metal sites initiate the propagation of the hydrogen adsorption on the whole frameworks. In addition, it was found that the interaction strength between the simple benzene ring with hydrogen is significantly reinforced when the benzene ring has been incorporated into the framework of MOFs.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.309-309
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• 2006

Latest developments on hybrid nanostructured materials fabricated by applying self-assembly strategies on organic/inorganic nanotemplates are discussed. Within this frame, numerous functional nanomaterials including arrays of composite metal/semiconductor nanoparticles, planar waveguides and functional multilayer thin films are generated using self-assembled polymers as templates or building blocks. In particular, surface plasmon resonance based optical sensing is employed to investigate nanofabrication processes occurring in nanoscale dimention. We also suggest unprecedented pathways to hybrid supramolecular multilayer nanoarchitectures in 1D or 2D geometry via layer-by-layer self-assembly.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.73-73
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• 2006

We investigate the influence of the confinement on the mesophase formation of diblock copolymer caged in a cylindrical pore in which the surface of the pore preferentially attracts one of the blocks. Using cell dynamics simulation, we construct phase maps as a function of the composition of diblock copolymer (f) and the pore diameter (D) relative to the period at bulk ($L_{o}$). Depending on f and $D/L_{o}$, we observe a variety of confinement-induced mesophases ranging from a simple dartboard-like structure to more complicated structures involving various forms of helices or doughnuts.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.294-294
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• 2006

Diblock copolymers whose morphology in the bulk is dictated by the volume fraction of the components and segmental interactions were confined within nanoscopic cylindrical pores. Since the confining geometry is nonplanar and nanoscopic, the extreme imposed curvature, comparable to molecular dimensions, places significant packing frustration on the chains. When incommensurability between the repeating period of diblock copolymers and the diameter of nanopore is coupled with the curvature, it causes the marked departures from bulk or even thin film behavior. The entropy penalty from the constraints and the curvature of the physical confinement determines unique nanostructures available only with this curved confinement.

• Journal of the Semiconductor & Display Technology
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• v.8 no.4
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• pp.37-42
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• 2009

The performance of an OLED(organic luminescent emitting device) fabrication system strongly depends on the design of the evaporation cell-source. Trends in display sizes have hauled the enlargement of mother glass substrates. The enlargement of substrates requires the improvement and the enlargement of the effusion cell-source for OLED evaporation process. The deposited layers should be as uniform as possible, and therefore it is important to know the effusion profile of the molecules emitted from the cell-source. Conventional 2D DSMC algorithm cannot be used for simulating the new concept cell-source design, such as a linear source. This work concerns the development of 3D DSMC (direct simulation Monte Carlo) analysis for simulating the behavior of the evaporation cell-sources. In this paper, the 3D DSMC algorithm was developed and the film thickness profiles were obtained by the numerical analysis.