Browse > Article

Phenol Conversion Properties in Aqueous Solution by Pulsed Corona Discharge  

Lee, Hyun-Don (Department of Environmental Engineering, Jinju National University)
Chung, Jae-Woo (Department of Environmental Engineering, Jinju National University)
Cho, Moo-Hyun (School of Environmental Science and Engineering, POSTECH)
Publication Information
Abstract
A laboratory scale experiment on phenol conversion properties by pulsed corona discharge process was carried out. Effects of operating parameters such as applied voltage, input oxygen, and electrode geometry on phenol conversion and solution properties were investigated. Electrical discharges generated in liquid phase increased the liquid temperature by heat transfer from current flow, decreased the pH value by producing various organic acids from phenol degradation, and increased conductivity by generating charge carriers and organic acids. The oxygen supply enhanced the phenol conversion through the ozone generation dissolution and the production of OH radicals. Series type electrode configuration induced more ozone production than reference type configuration because it produced gas phase discharges as well as liquid phase discharges. Therefore, the higher phenol conversion and TOC(total organic carbon) removal efficiency were obtained in series type configuration.
Keywords
Pulsed Corona Discharges; Operating Parameters; Electrode Geometry; Phenol Conversion;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Oglesy, S. Jr. and Nichols, G. B., Electrostatic Precipitation, Marcel Dekker, Inc., pp. 1-13(1978)
2 Kogelschatz, U., 'Ozone generation and dust collection,' Electrical discharges for environmental purposes, E. M. Van Veldhuizen(Eds), Nova Science Publishers, Inc., New York, pp. 315-344(1999)
3 Urashima, K. and Chang, J. S., 'Removal of volatile organic compounds from air streams and industrial flue gases by non-thermal plasma technology,' IEEE Transactions on Dielectrics and Electrical Insulation, 7(5), 602-614(2000)   DOI   ScienceOn
4 Ohshima, T., Sato, K., Terauchi, H., and Sato, Masayuki, 'Physical and chemical modifications of high-voltage pulse sterilization,' Journal of Electrostatics, 42, 159-166(1997)   DOI   ScienceOn
5 Joshi, A. A., Locke, B. R., Arce, P., and Finney, W. C, 'Formation of hydroxyl radicals, hydrogen peroxide and aqueous electrons by pulsed streamer corona discharge in aqueous solution,' Journal of Hazardous Materials, 41, 3-30(1995)   DOI   ScienceOn
6 Chang, J. S., Lawless. P. A., and Yamamoto, T., 'Corona Discharge Processes,' IEEE Transactions on Plasma Science, 19(6), 1152-1166(1991)   DOI   ScienceOn
7 Jang, S. D., Son, Y. G., Oh, J. S., and Kwon, O. J., 'High voltage nano-pulse generator for industrial wastewater treatment,' Journal of Korean Society of Industrial Application, 4(3), 311-318(2001)
8 Lukes, P., Appleton, T., and Locke, B. R., 'Hydrogen peroxide and ozone formation in hybrid gas-liquid electrical discharge reactors,' IEEE Transactions in Industry Applications, 40(1), 60-67(2004)   DOI   ScienceOn
9 Lukes, P. and Locke, B. R., 'Degradation of substituted phenols in a hybrid gas-liquid electrical discharge reactor,' Industrial & Engineering Chemistry Research, 44(9), 2921-2930(2005)   DOI   ScienceOn
10 Sunka, P., Babicky, V., Clupek, M., Lukes, P., Simek, M., Schmidt, J., and Cernak, M., 'Generation of chemically active species by electrical discahrges in water,' Plasma Sources Sci. Technol., 8, 258-265(1999)   DOI   ScienceOn
11 Grymonpre, D. R., Sharma, A. K., Finney W. C, and Locke, B. R, 'The role of Fenton's reactions in aqueous phase pulsed streamer corona reactors,' Chemical Engineering Journal, 82, 189-207(2001)   DOI   ScienceOn
12 Lukes, P., 'Water treatment by pulsed streamer corona discharge,' Ph. D. Thesis, Institute of Plasma Physics, Academy of Science of the Czech Republic(2001)
13 Muhammad, A. M., Abdul, G., and Salman, A. M., 'Water purification by electrical discharges,' Plasma Sources Science and Technology, 10, 82-91(2001)   DOI   ScienceOn
14 Piskarev, M., 'Choice of conditions of an electrical discharge for generating chemically active particles for the decomposition of impurities in water,' Technical Physics, 44(1), 53-58(1999)   DOI
15 정재우, 이용환, 오종석, 손윤규, 조무현,'펄스형 전기 집진 시스템에 의한 고비저항도 먼지 제거 특성', 대한환경공학회지 , 25(2), 248-252(2003)
16 Hoeben, W. F. L. M., Veldhuizen, E. M., Rutgers, W. R., Cramers, C. A. M. G., and Kroesen, G. M. W., 'The degradation of aqueous phenol solutions by pulsed positive corona discharges,' Plasma Sources Sci. Technol., 9, 361-369(2000)   DOI   ScienceOn
17 Hoigne, J., 'Mechanisms, rates and selectivities of oxidations of organic compounds initiated by ozonation of water,' In Handbook of Ozone Technology and Appli-cations(Rice, R. G. and Netzer, A. Eds), Ann Arbor Science, Michigan, pp. 341-379(1982)