• Title/Summary/Keyword: Organic functional group

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Organic Solvent Absorption characteristics of Split-type micro fiber fabrics

  • Lee, Kwang-Ju;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.95-95
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    • 2003
  • In this study, the influences of organic solvent viscosity on absorption properties of split-type micro fiber fabrics is examined with real time absorption measurement device built by our research group recently. And the absorption behavior of these fabrics is analyzed by material, fineness, construction, weight, thickness, and density of fabrics.

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EL properties of OLED devices using different NiO buffer thicknesses (NiO 완충층의 두께변화에 따른 OLED 발광특성)

  • Jeong, Tae-Jeong;Choi, Gyu-Chae;Chung, Kook-Chae;Kim, Young-Kuk;Cho, Young-Sang;Choi, Chul-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.180-180
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    • 2010
  • 본 연구에서는 P-Type의 NiO를 Glass기판의 ITO전극위에 RF-스퍼터링 방법으로 증착하였으며, NiO 완충층의 두께 변화에 따른 OLED (Organic Light Emitting Diode) 소자의 발광 특성에 대해 연구하였다[1, 2]. NiO는 우수한 전기 광학적 특성을 가지고 있어 OLED소자의 구동전압, 발광 효율 등의 특성을 향상 시킬 수 있다[3]. NiO 완충층의 두께 변화는 스퍼터링 증착시간을 통해 5-20 nm로 조절하였으며 소자의 구조는 Glass/ITO/NiO(0~20nm)/NPB(40nm)/Alq3(60nm)/LiF(0.5nm)/Al(120nm)형태로 제작하였다. ITO/NPB 계면에 NiO 완충층을 삽입함으로써 OLED 발광소자의 구동전압을 ~8V에서 ~5V (NiO, 10nm)로 낮출 수 있었다.

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Synthesis and Dispersion Stabilization of Indium Tin Oxide Nanopowders by Coprecipitation and Sol-Gel Method for Transparent and Conductive Films

  • Cho, Young-Sang;Hong, Jeong-Jin;Kim, Young Kuk;Chung, Kook Chae;Choi, Chul Jin
    • Korean Journal of Metals and Materials
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    • v.48 no.9
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    • pp.831-841
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    • 2010
  • Indium tin oxide (ITO) nanopowders were synthesized by coprecipitation and the sol-gel method to prepare a stable dispersion of ITO nano-colloid for antistatic coating of a display panel. The colloidal dispersions were prepared by attrition process with a vibratory milling apparatus using a suitable dispersant in organic solvent. The ITO coating solution was spin-coated on a glass panel followed by the deposition of partially hydrolyzed alkyl silicate as an over-coat layer. The double-layered coating films were characterized by measuring the sheet resistance and reflectance spectrum for antistatic and antireflective properties.

Selective Reduction of Organic Compounds with Al-Methanesulfonyldiisobutylalane

  • Cha, Jin-Soon;Noh, Min-Yeong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.840-844
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    • 2010
  • The new MPV type reagent, Al-methanesulfonyldiisobutylalane ($DIBAO_3SCH_3$), has been prepared and its reducing characteristics in the reduction of selected organic compounds containing representative functional groups have been examined in order to find out a new reducing system with high selectivity in organic synthesis. In general, the reagent is extremely mild, showing only reactivity toward aldehydes, ketones and epoxides. The reagent exhibits a unique reducing applicability in organic synthesis. Thus, the reagent can achieve a clean 1,2-reduction of $\alpha,\beta$-unsaturated aldehydes and ketones to produce the corresponding allylic alcohols in 100% purity. In addition, the reagent shows an excellent regioselectivity in the ring-opening reaction of epoxides. Finally, $DIBAO_3SCH_3$ shows a high stereoselectivity in the reduction of cyclic ketones to produce the thermodynamically more stable epimers exclusively.

Electrical and Luminescent Properties of OLEDs by Nickel Oxide Buffer Layer with Controlled Thickness (NiO 완충층 두께 조절에 의한 OLEDs 전기-광학적 특성)

  • Choi, Gyu-Chae;Chung, Kook-Chae;Kim, Young-Kuk;Cho, Young-Sang;Choi, Chul-Jin;Kim, Yang-Do
    • Korean Journal of Metals and Materials
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    • v.49 no.10
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    • pp.811-817
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    • 2011
  • In this study, we have investigated the role of a metal oxide hole injection layer (HIL) between an Indium Tin Oxide (ITO) electrode and an organic hole transporting layer (HTL) in organic light emitting diodes (OLEDs). Nickel Oxide films were deposited at different deposition times of 0 to 60 seconds, thus leading to a thickness from 0 to 15 nm on ITO/glass substrates. To study the influence of NiO film thickness on the properties of OLEDs, the relationships between NiO/ITO morphology and surface properties have been studied by UV-visible spectroscopy measurements and AFM microscopy. The dependences of the I-V-L properties on the thickness of the NiO layers were examined. Comparing these with devices without an NiO buffer layer, turn-on voltage and luminance have been obviously improved by using the NiO buffer layer with a thickness smaller than 10 nm in OLEDs. Moreover, the efficiency of the device ITO/NiO (< 5 nm)/NPB/$Alq_3$/ LiF/Al has increased two times at the same operation voltage (8V). Insertion of a thin NiO layer between the ITO and HTL enhances the hole injection, which can increase the device efficiency and decrease the turn-on voltage, while also decreasing the interface roughness.

Fabrication of Ordered or Disordered Macroporous Structures with Various Ceramic Materials from Metal Oxide Nanoparticles or Precursors

  • Cho, Young-Sang;Moon, Jun-Hyuk;Kim, Young-Kuk;Choi, Chul-Jin
    • Journal of Powder Materials
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    • v.18 no.4
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    • pp.347-358
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    • 2011
  • Two different schemes were adopted to fabricate ordered macroporous structures with face centered cubic lattice of air spheres. Monodisperse polymeric latex suspension, which was synthesized by emulsifier-free emulsion polymerization, was mixed with metal oxide ceramic nanoparticles, followed by evaporation-induced self-assembly of the mixed hetero-colloidal particles. After calcination, inverse opal was generated during burning out the organic nanospheres. Inverse opals made of silica or iron oxide were fabricated according to this procedure. Other approach, which utilizes ceramic precursors instead of nanoparticles was adopted successfully to prepare ordered macroporous structure of titania with skeleton structures as well as lithium niobate inverted structures. Similarly, two different schemes were utilized to obtain disordered macroporous structures with random arrays of macropores. Disordered macroporous structure made of indium tin oxide (ITO) was obtained by fabricating colloidal glass of polystyrene microspheres with low monodispersity and subsequent infiltration of the ITO nanoparticles followed by heat treatment at high temperature for burning out the organic microspheres. Similar random structure of titania was also fabricated by mixing polystyrene building block particles with titania nanoparticles having large particle size followed by the calcinations of the samples.

Development of Environmentally Friendly Semi-Structure Poly(Ethylene/Butylene) Rubber-based Pressure Sensitive Adhesive (친환경적인 준구조용 Poly(Ethylene/Butylene) 고무수지계 점착제의 개발)

  • Hong, Soungtaek;Park, Young-Jun;Kim, Hyun-Joong;Dilger, K.
    • Journal of Adhesion and Interface
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    • v.7 no.2
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    • pp.12-18
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    • 2006
  • Recently, as industries and technologies are increased, superior adhesives having more and more developed functions and properties have been demanded. In this article, to use the merits and viscoelastic properties of poly(ethylene/butylene) rubber resin and to supplement the demerits, semi-structure pressure sensitive adhesives (PSAs) are developed. Aslo, it can be said environmentally friendly PSAs because of not use the organic solvent and not emit volatile organic compounds (VOCs).

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Electrical Properties of Organic/Inorganic Hybrid Composites for Insulation Materials

  • Kim, Sang-Cheol;Ok, Jeong-Bin;Aho, Myeong-Jin;Park, Do-Hyun;Lee, Gun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.9-13
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    • 2002
  • In this work, the surface of inorganic fillers were modified with some functional groups such as stearic acid, aliphatic long chain, vinylsilane and aminosilane to control the interaction between inorganic fillers and polymer matrix. Ethylene-vinyl acetate copolymers (EVA) with various amount of vinyl-acetate and copolyether-ester elastomer were used as polymer matrix. The addition of inorganic fillers increases flame retardancy, but results in steep drop of electrical and mechanical properties, which may be caused by the defects in the interface between organic/inorganic hybrid composites. The hybrid composites are found to show better mechanical properties and higher volume resistivities as inorganic fillers are well dispersed and have good adhesion with polymer matrix. Also, the most effective type of functional group coated on fillers depends on the chemical structure of polymer.

Functional Polymers with Controlled Molecular Architecture: Design, Synthesis and Applications

  • Frechet Jean M.J.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.1-2
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    • 2006
  • Polymer architecture plays a great role in determining the properties of functional polymers. This lecture will explore the design and the synthesis of polymers with controlled architecture and functionality. Especially featured will be star and dendritic architectures where the functional group placement and the molecular shape can be controlled. This will be followed by examples of applications illustrated with a few model systems of functional polymers designed for use in areas such as organic electronics, catalysis, surface patterning, separation and molecular recognition, and polymer therapeutics.

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Comparison of Self-Reporting Voice Evaluations between Professional and Non-Professional Voice Users with Voice Disorders by Severity and Type (음성장애가 있는 직업적 음성사용자와 비직업적 음성사용자의 음성장애 중증도와 유형에 따른 자기보고식 음성평가 차이)

  • Kim, Jaeock
    • Phonetics and Speech Sciences
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    • v.7 no.4
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    • pp.67-76
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    • 2015
  • The purpose of this study was to compare professional (Pro) and non-professional (Non-pro) voice users with voice disorders in self-reporting voice evaluation using Korean-Voice Handicap Index (K-VHI) and Korean-Voice Related Quality of Life (K-VRQOL). In addition, those were compared by voice quality and voice disorder type. 94 Pro and 106 Non-pro were asked to fill out the K-VHI and K-VRQOL, perceptually evaluated on GRBAS scales, and divided into three types of voice disorders (functional, organic and neurologic) by an experienced speech-language pathologist and an otolaryngologist. The results showed that the functional (F) and physical (P) scores of K-VHI in Pro group were significantly higher than those in Non-pro group. As the voice quality evaluated by G scale got worse, the scores of all aspects except emotional (E) of K-VHI and social-emotional (SE) of K-VRQOL were higher. All scores of K-VHI and K-VRQOL in neurologic voice disorders were significantly higher than those in functional and organic voice disorders. In conclusion, professional voice users are more sensitive to their functional and physical handicap resulted by their voice problems and that goes double for the patients with severe and neurologic voice disorders.