• Title/Summary/Keyword: Organic cation

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Differences in Soil Chemical Properties Under Multi-layer System, USGA System and Mono-layer System for a Sports Turf (스포츠용 잔디의 다단구조, USGA구조 및 단층구조 지반에서 토양 화학성 차이)

  • Kim, Kyoung-Nam
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.9 no.5
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    • pp.50-59
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    • 2006
  • This study was initiated to investigate soil chemical properties under different soil systems. Data such as soil acidity(pH), electrical conductivity(EC), organic matter content(OMC), and cation exchange capacity(CEC) were analyzed with samples from multi-layer, USGA, and mono-layer systems. N, P, K and micronutrients were also measured. Multi-layer system was built up to 60-cm depth with rootzone layer, intermediate layer and two drainage layers. USGA system 45 centimeters deep was constructed with rootzone layer, intermediate layer and drainage layer. Mono-layer system, however, was made only with a 30-cm rootzone layer. Differences were observed in soil pH, EC, OMC, CEC and micronutrients. Soil pH was acceptable for turfgrass growth a year after establishment, being 5.5 to 6.5 in the study. Differences were greatly observed for EC among soil systems. Values of EC for multi-layer, USGA, and mono-layer systems were 39.79, 31.26 and 103.54 uS/em, respectively. The increase rate was approximately 4 to 8 times greater with mono-layer system than those with other two systems. Therefore, it was necessary to avoid micronutrient deficiency such as Fe, Mn etc. through an effective management program in mono-layer system because of its faster potential feasibility of salt accumulation. The greatest OMC was associated with USGA system, being 0.97% which was 11% over that of the other systems. Slight differences were observed for CEC among them. Mono-layer system produced 1.45 me/100g, 10.3% and 8.9% lower in CEC than those of multi-layer and USGA system, respectively. Micronutrients such as Fe, Zn, and Mn etc. were below the level required for turf growth, regardless of soil systems. It was considered that one year after turf establishment was not enough to build up micronutrients in sand-based soil systems to the normal level for a turf growth. These results demonstrate that intensive management program including grow-in concept fertilization should be integrated into sand-based soil systems, even after a year in establishment. Regular nutrient monitoring by soil analyses is a strong necessity to decide the kinds and amount of fertilizer. Also, strategic management program must be selectively employed according to sports turf soil systems.

Effect of Soil Conditioner and Loess on Physio-Chemical Properties of Dredged Soil and Seedling Height Growth of Ulmus davidiana var. japonica (토양개량재와 황토가 준설토의 이화학성과 느릅나무의 초기 생장에 미치는 영향)

  • Lee, Hanna;Park, Chanwoo;Lim, Joo-Hoon;Koo, Namin;Lee, Im Kyun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.18 no.3
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    • pp.1-11
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    • 2015
  • This research was conducted to compare the effect of soil amendment and loess on physial and chemical properties of dredged soil and primary height growth of Ulmus davidiana var. japonica. Three types of research plots: control plot (Dredged soil only), DC treatment plot (Dredged soil + soil amendment) and DCL treatment plot (Dredged soil + soil amendment + Loess) were set at Okgu research site in Saemanguem. 32 trees of U. davidiana var. japonica were planted in each plots after 14 months from the construction. Soil texture, pH, electrical conductivity (EC), organic matter (OM), total nitrogen (TN), available P, exchangeable cation ($K^+$, $Na^+$, $Mg^{2+}$, $Ca^{2+}$) and sodium chloride were measured after 3 years from the construction. Also, survival rate and height of U. davidiana var. japonica were measured 22 months after planting, and the correlation between height of trees and the physico-chemical properties of soil were analyzed. Even though pH in both DC and DCL treatment plots are lower than control plot, they are still alkaline (> pH 8). OM, TN and available P in both DC and DCL treatment were higher than the control. Particularly, the content of available P in both DC and DCL treatment plots are 1.4~5.1 times and 2.0~3.1 times higher than the control respectively. The concentration of exchangeable Mg in DCL treatment plot was 1.1~5.5 times higher than the control (p < .05). The survival rate of the species was the highest in DCL treatment plot (98%) followed by DC treatment plot and the control. The average height of the trees in both DC and DCL treatment plots is 1.1m while the control is 0.8m. OM, TN, available P, K+ were significantly related to the height of U. davidiana var. japonica(p < .01). The results indicate that soil amendment affects on soil physial and chemical properties of dredged soil and height growth of U. davidiana var. japonica.

Anti-oxidant, Anti-coagulation, and Anti-platelet Aggregation Activities of Black Currant (Ribes nigrum L.) (블랙커런트의 항산화, 항응고 및 혈소판 응집저해 활성)

  • Kim, Mi-Sun;Sohn, Ho-Yong
    • Journal of Life Science
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    • v.26 no.12
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    • pp.1400-1408
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    • 2016
  • The black currant (Ribes nigrum L.) is belong to the Grossulariaceae family, and has piquant berries, which can be eaten as raw or as processed foods, such as jams, jelly, juice and syrups. In this study, the fresh juice of black currant (FJBC) from Austria and its subsequent organic solvent fractions, such as hexane fraction, ethylacetate (EA) fraction, butanol fraction and water residue, were prepared and their in-vitro anti-oxidant, anti-coagulation and anti-platelet aggregation activities were evaluated. The FJBC and EA fraction, which has concentrated polyphenol and flavonoid, showed strong radical scavenging activities and reducing power. The $RC_{50}s$ of EA fraction against DPPH anion, ABTS cation, nitrite were 136.3, 66.2 and $115.5{\mu}g/ml$, respectively, those are 1/10, 1/16, and 1/7.7 of $RC_{50}s$ of vitamin C. In anti-coagulation assay, the FJBC, EA and butanol fraction showed significant inhibitory activities against thrombin, prothrombin and coagulation factors. Furthermore, the anti-platelet aggregation activities of EA and butanol fraction were the stronger than that of aspirin. The concentrations required for 50% platelet aggregation inhibition of aspirin, EA and butanol fraction were 0.395, 0.192 and 0.261 mg/ml, respectively. The EA and butanol fraction have no hemolysis activities up to 0.5 mg/ml against human red blood cells. The results suggest that the FJBC and its EA and butanol fraction have high potentials as novel anti-thrombosis agents. This report provides the first evidence of anti-thrombosis activity of black currant.

Competitive Solvent Extraction of Alkali Metal Ions with Azacrown Ether Phosphinic Acids (아자크라운에테르포스피닉산에 의한 알카리금속이온의 경쟁용매추출)

  • Nam, Chong-Woo;Chung, Yeong-Jin;Yang, Il-Woo
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.266-272
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    • 1992
  • Azacrownoalkyl phenylphosphinic acids were synthesized and their competitive solvent extraction characteristics from water to chloroform layer were investigated. Phosphinic acids were synthesized in good yields by one step reaction of phenylphosphinate, aldehyde, and monoazacrown ether and then basic hydrolysis of the resulting phosphinate dsters. These complexing agents revealed a wide effective pH range in extraction of alkali metal ions from water to the organic phase and total metal ion loading at pH 11 was about 75%. The selectivity of the cation extraction was determined mainly by the cavity size of the azacrown ethers, showing $Na^+$ >> $K^+$ > $Rb^+$ > $Li^+$ > $Cs^+$ for the alkyl phenylphosphinic acid ${\underline{2}}$, containing monoaza-15-crown-5 and $K^+$ >> $Rb^+$ > $Na^+$ > $Cs^+$ > $Li^+$ for the alkyl phenylphosphinic acid, ${\underline{3}}$, containing monoaza-18-crown-6 moiety. Applicable pH range of these azacrown ether phosphinic acids in solvent extraction of alkali metal cations was wider than a crownether carboxylic acid with similar selectivity, showing considerable amount of metal ion loading in slightly acidic or neutral media.

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Effects of Barley Straw Application and Tillage Method on Soil Physical Property and Soybean Yield in Paddy Field (논에서 콩 재배시 보릿짚 시용과 경운방법에 따른 토양 물리성과 수량)

  • Lee, Sang-Bok;Kim, Byong-Soo;Kang, Jong-Gook;Kim, Sun;Kim, Jai-Duk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.7
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    • pp.593-598
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    • 2006
  • This study was conducted to investigate the effect of tillage methods such as plowing and rotary tillage (PRT), rotary tillage (RTG), no-tillage after barley straw application (NTB), and barley straw mulching after plowing and rotary tillage (BPR) on the growth and the yield of soybean when cultivated after the cultivation of barley. The methods were compared with the control method in which plowing and rotary tillage after barley straw incineration was applied. Barley straw application resulted in increase in organic matter, total nitrogen, phosphate, and exchangeable cation regardless of tillage methods. Porosity and moisture level in paddy soil was ranked as follows : PRT > RTG > BPR > control > NTB. Decomposition rate of barley straw dramatically increased to 41.7% toward 30 days after soybean sowing, higher in NTB, DRB, and RTG than in BPR. Weed occurrence was decreased 36% in NTB and 40% in BPR. Root activity, nodulation and the dry weight per plant of soybean at flowering stage were highest in NTB and lowest in PRT. Soybean yield in NTB was 3,070 kg/ha increasing 19%, whereas that in PRT was not increased. Therefore in case of a frequent rain during the cultivation of soybean in paddy field PRT could result in excess moisture level in soil, the cultivation without tillage is desirable.

Effect of Sewage Sludge Application on Growth of Corn and Chinese Cabbage and Chemical Properties of Soil (하수오니 시용이 옥수수 및 배추 생육과 토양의 화학성 변화에 미치는 영향)

  • Lee, Seung-Heon;Park, Mi-Hyun;Yoo, Sun-Ho;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.463-471
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    • 2000
  • A pot experiment was carried out to find out the effects of the sludge application on corn and Chinese cabbage growth and changes in soil chemical properties with sludges collected from 4 plants at 0, 12.5, 25, 50, and $100Mg\;ha^{-1}$ levels and chemical fertilizer. With the corn experiment, the pot where sludge and chemical fertilizers were treated together, greater amount of sludge resulted in initial growth inhibition. In general, higher sludge treatment rates resulted in better growth in the end, whereas initial growth was inhibited due to high the electrical conductivity of saturated extracts(ECe) for the Chinese cabbage. However, the highest yield among sludge treatments was lower than the yield with chemical fertilizers. While the treatments resulted in chemical changes in soil showing differences of cation exchange capacity, organic matter contents, and nitrogen contents, hardly any changes were detected before and after crops were grown. Inorganic nutrients such as Na, K, Ca and Mg showed similar changes. The ECe in soil saturation extract decreased after crops were grown. The more sludge was treated, the greater was the decrease. The differences of ECe in the soil saturation extract with varying degrees of treatment were also reduced after crops were grown. Available phosphorus content increased during growth. Due to the low nitrogen content in sludge, when nitrogen becomes the determining factor for the amount of sludge treatment, phosphorus buildup resulted from continued application of sludge could be raised. Therefore, it is advisable to use phosphorus, not nitrogen content, in determining the amount of sludge treatment and chemical fertilizer as supplementary sources for nitrogen.

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Applicability of Spent Mushroom Media as Horticultural Nursery Media (버섯재배 후 탈병배지의 원예용 상토재료 이용성 검토)

  • Lee, Chan-Jung;Cheong, Jong-Chun;Jhune, Chang-Sung;Kim, Seung-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.2
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    • pp.117-122
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    • 2009
  • This study was carried out to investigate applicability of Spent Mushroom Media(SMM) as horticultural nursery media. After the mushroom has been harvested, the SMM contains a lot of organic material, different microorganism and high density of mushroom hypha. The pH, phosphate and exchangeable cation concentrations of SMM of Flammulina velutipes were higher than those of any other treatment. The CEC and $NH_4-N$ were the highest in SMM of bottle-cultivated oyster mushroom (Pleurotus ostreatus). Bacteria and fungi showed the highest density in SMM of Flammulina velutipes. Most dominant bacteria were Microbacterium sp., Rhodococcus sp. and Agrobacterium sp. in SMM of Flammulina velutipes and Bacillus sp., Pseudomonas sp., Curtobacterium sp. and Microbacterium sp. in that of Pleurotus eryngii. The SMM contained high density of mushroom hypha that inhibited germination of seed and growth of young seedlings. Therefore, composting process of the SMM is indispensible to decline of vitality of mushroom hypha. The SMM of Flammulina velutipes with 0~30% vermiculite showed high germination rate in red pepper and chinese cabbage seeds. SMM of Pleurotus eryngii with 20% vermiculite showed 100% germination rate in red pepper seeds, but chinese cabbage seeds nearly failed to germinate with 30% vermiculite. The growth of red pepper was increased according to increasing mixture ratio of vermiculite. Accordingly, we concluded that SMM of Flammulina velutipes contained 0~30% of vermiculite can be used to horticultural growth bed for red pepper.

Heavy Metals in Paddy Rice and Soils in Mangyeong River Area (만경강(萬頃江) 유역(流域)의 토양(土壤) 및 수도체중(水稻體中) 중금속(重金屬) 함량(含量))

  • Kim, Seong-Jo;Ryang, Hwan-Seung
    • Korean Journal of Environmental Agriculture
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    • v.5 no.1
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    • pp.11-23
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    • 1986
  • Soils and rice plants in wastewater irrigated area of the Mangyeong River receiving waster from the Jeonju Industrial Complex and municipal sewage were sampled at two depths to assess the nature and content of Cd, Cu, Pb and Zn, particularly with respect to distance from wastewater source. For metal levels of soils in these area, no difference in the heavy metal contents between the surface and the subsurface soils was found. Total contents of Cu, Pb and Zn in soils were negatively correlated with distance from the source. A positive correlation was found between contents of total and 0.1N-HCl extractable or $1N-CH_3COONH_4$ extractable heavy metals in surface soils of these area. Total contents of heavy metals in soils were positively correlated with clay, soil organic matter and cation exchange capacity. Heavy metal contents of brown rice sampled at the Jeon-ju Industrial Complex area ranged from 0.15 to 0.91 ppm for Cd, from 1.13 to 5.68 ppm for Cu, from 0.22 to 7.16 ppm for Pb and from 11.74 to 38.66 ppm for Zn. Negative correlation was found between the contents of Cd, Cu, Pb, and Zn in the brown rice and the distance from the source. The contents of Cd, Cu and Zn in rice straw were positively correlated with those in the brown rice.

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Determination of Main Indicator for the Changes of Chemical Properties in Greenhouse Soils (시설재배지 토양의 화학적 특성변화에 영향을 미치는 주요 인자 선발)

  • Yoon, Young-Eun;Kim, Jang Hwan;Kim, Song Yeob;Im, Jong Uk;Kong, Myung Suk;Lee, Young Han;Lee, Young Bok
    • Korean Journal of Environmental Agriculture
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    • v.34 no.4
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    • pp.355-358
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    • 2015
  • BACKGROUND: Changes in Korea's agricultural soil properties were analyzed at a four-year interval from 1999 to 2002 on a national scale and used as basis for the determination of the appropriate agricultural policy on maintaining food safety and soil quality. The scope of this study ideally requires sampling thousands of paddy, greenhouse, upland and orchard land across the country, however, due to limitations in economic and manpower resources, it was deemed necessary to reduce sampling site to greenhouse soil. In this study, we try to investigate the applicability of cultivated crops as criteria for selecting representing fields in greenhouse soils.METHODS AND RESULTS: Soil samples were collected from red pepper, oriental melon, watermelon and strawberry cultivated soil. Principal components analysis (PCA) was performed on soil chemical properties of the selected fields: pH, electron conductivity (EC), available phosphate (Av-P2O5), organic matter (OM), and exchangeable cation (Ex.-K, Ca, and Mg). Soil chemical properties of oriental melon cultivated soil was separated from red pepper, watermelon, and strawberry cultivated soil on PC1 and red pepper cultivated soil was separated from watermelon cultivated soil on PC2. Position on PC1 was strongly correlated with pH, Ex.-Ca and Ex.-Mg and position on PC2 was strongly correlated with OM and Av-P2O5.CONCLUSION: The soil chemical properties of greenhouse soil was assorted amongst the different crops. Therefore, the cultivated crops as a criteria for the selection of representative field in greenhouse soil would be used in the future.

Complexation of Cadmium(Ⅱ) with Soil Fulvic Acid : Effect of pH and Fulvic Acid Concentration (풀빅산과 카드뮴(Ⅱ)과의 착화합 반응 : 풀빅산의 농도와 pH의 영향)

  • Choe, Se Yeong;Jeong, Geun Ho;Jeon, Song Hui;Mun, Hui Jeong
    • Journal of the Korean Chemical Society
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    • v.38 no.8
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    • pp.585-589
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    • 1994
  • The complexation of cadmium(II) with a well characterized local soil fulvic acid was investigated at different solution pH and fulvic acid concentration using ion selective electrode. The stability constants were determined using a continuous distribution model based on Scatchard Plot; this model takes into consideration the diversitv of cation binding sites on a naturally occurring organic macromolecules even if the nature of the binding sites may not be known. The mean value of $logKi(\mu)$ was found to increase at higher pH(pH 4.0: ${\mu}=3.79{\pm}0.74$ l\;mol^{-1}; pH 6.0: ${\mu}=4.51{\pm}0.78$ l\;mol^{-1}$), and in more dilute fulvic acid concentration([FA] = 50 mgl$^{-1}: {\mu}=4.16{\pm}0.60$ l\;mol^{-1}; [FA]=151 mgl$^{-1}:{\mu}=3.75{\pm}0.5\;l\;mol^{-1}$). The intrinsic constant(logKint) for binding at the strongest site was measured to be around $4.72\;l\;mol^{-1}$ at both pH4.0 and 5.0, but was found to be increased to $6.03\;l\;mol^{-1}$ when pH was 6.0.

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