• Title/Summary/Keyword: Organic binder

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Development of Organic-Inorganic Hybrid Insulating Materials with Semi-Non-Combustible Using by Recycling Gypsum (재활용 석고 부산물을 이용한 준불연 유무기 융합 단열재 개발 연구)

  • Ha, Joo-Yeon;Shin, Hyun-Gyoo;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.431-437
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    • 2019
  • The purpose of this study is to develop an organic-inorganic hybrid insulation materials which has an economic feasibility of organic level and excellent adiabatic performance and fire stability by impregnating organic materials with inorganic binder solutions. The organic base was commercial polyurethane sponge, and the inorganic binder slurry was prepared by mixing water and additives into recycled gypsum byproducts. As a result of evaluation of the developed materials, it was confirmed that it not only has excellent insulation performance of a thermal conductivity of 0.051 W/mK or less but also it is a semi-non-combustible materials specified in the Ministry of Land, Infrastructure and Transport Notice No. 2015-744. The developed materials can also be controlled for thermal conductivity and flame retardance according to density control during manufacturing process, and thus it can be applied to various insulation materials.

Comparison Study of Polymer and Ti Sol-Gel Carbon Coating on Ti for PEMFC Bipolar Plates (고분자전해질 연료전지용 Ti 분리판을 위한 고분자와 Ti Sol-Gel 탄소코팅의 비교 연구)

  • Won-Seog Yang;Jae-Ho Lee;Hee-Suk Roh;Ju-Hyun Yoo;Chul-Min Park;Su-Yeon Lee;Sung-Mo Moon
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.447-456
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    • 2023
  • In this work, we performed a comparative study examining two coatings on Ti Gr.1 for use in fuel cell bipolar plates. The coatings consisted of carbon black as the conductor along with acrylic polymer and Ti Sol-Gel binder as the binder. Ti Sol-Gel that had precipitated as TiO2 in areas impregnated between carbon black gaps, thereby acting as a binder for carbon black and serving as a polymer coating. Neither of the coatings peeled off during the 90° bend test to check formability. The contact resistance of the TiO2 coating was found to be lower than that of the polymer binder coating. Moreover, due to coating shrinkage (denser) that occurred during the heat treatment process, the TiO2 binder coating showed almost the same level of corrosion resistance, as measured by potentiostatic and EIS tests, despite being thinner than the polymer coating. However, both the polymer binder coating and the TiO2 binder coating had many pores and irregularities internally (around 10 ~ 100 nm) and on the surface (0.1 ~ 2 ㎛). We considered that these pores and irregularities contributed to the lower corrosion resistance.

Effects of Suspension Composition on Defects in Aqueous Tape Casting of Alumina Ceramics: A Rheological Study

  • Shin, Hyo-Soon
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.1-6
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    • 2005
  • In aqueous alumina tape casting, the effects of altering the composition of the suspensions, the binders and the casting thickness were studied. The rheological behavior of the suspensions and the defects of the dried tapes were examined and the relationships between them are discussed. The changes in the defect regions reported in the previous paper were related with the rheological properties with variations of the binder, the composition and the casting thickness. The shear thinning factor increased with the organic content and the solid content (the decrease of water content). The apparent viscosity increased with the shear thinning factor. The relation between the shear thinning factor and the log apparent viscosity was similar for all binder types. In the relation between the defect free region and the rheological properties, the defect free region became narrower with increasing casting thickness. The defect free region is independent of binder type. Therefore, the thicker tape is more difficult to produce in aqueous alumina tape casting. Knowledge of the rheological properties of the suspensions could help Predict the defect type and the possibility of defect free dried tapes.

Preparation and Characteristics of Transparent Anti-static Films (투명 대전방지 필름 제조 및 특성)

  • 김종은;심재훈;서광석;윤호규;김명화;황공현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.1
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    • pp.52-59
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    • 2000
  • In order to develop the transparent anti-static film with higher than 80% transparency to visible light, organic conductive compounds, N-methyl phenazinium 7,7,8,8-tetracyanoquinonedimethane (TCNQ) com-plex salts was synthesized and bar-coated on the polythylene terephthalate (PET) film using polymer binders. The best surface properties were obtained when acrylic binder was used. A single layer of TCNQ made of a acrylic binder showed a surface resistance of 10\ulcorner $\Omega$/ , a conductivity of 10\ulcorner S/cm, and a transparency of 75%. An optical microscopic examination revealed that the binder was first solidi-fied on the surface of PET film over which the needle-shaped TCNQ crystals were grown. An acrylic polyol coating over the TCNQ layer improved the transparency to 87%, becuase the acrylic polyol covers the surface of TCNQ crystals to reduce the surface roughness. This conductive material has thermal stability at room temperature and 4$0^{\circ}C$ over 4,000 h.

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Early Strength and Properties of EVA Powder Modified High Strength Concrete (EVA Powder 개질 고강도 콘크리트의 초기강도 및 수밀특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.123-127
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    • 2005
  • EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

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Dispersant-Binder Interactions in Aqueous Silicon Nitride Suspensions

  • Paik, Ungyu
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.129-153
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    • 1996
  • In aqueous slurry processing of silicon nitride, the interaction of dispersant and binder on the surface of particles was studied to identify the effect of these additives on ceramic powder processing. Polymethacrylic acid (PMAA) and polyvinyl alcohol (PVA) were used as dispersant and binder, respectively. the adsorption isotherms of PMAA and PVA for the silicon nitride suspension were determined, while the adsorption of PMAA was differentiated in the mixed additive system by ultraviolet spectroscopy. These experiments were done in order to investigate the effect of these organic additives on the physicochemical properties of silicon nitride suspensions. The electrokinetic behavior of silicon nitride was subsequently measured by electrokinetic sonic amplitude (ESA). As PMAA adsorbed onto silicon nitride, the isoelectric point (pHicp) shifted from pH=6.7 to acidic pH, depending on the surface coverage of PMAA. However, adsorption of PVA did not change the pHicp of suspensions, but did decrease the surface potential of silicon nitride moderately. The rheological behavior of silicon nitride suspensions was measured to assess the stability of particles in aqueous media, and was correlated with the electrokinetic behavior and adsorption isotherm data for silicon nitride.

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A Study on Rheological Behavior of Cordierite Honeycomb Extrusion Paste (코디어라이트 허니컴 압출용 혼합체의 점성거동에 관한 연구)

  • Song, Yong-Ik;Kim, Hyung-Tae;Lee, Jin-Gu;Yoon, Won-Jung;Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.44-51
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    • 2010
  • The rheological behavior of a cordierite honeycomb extrusion paste was investigated by measuring torque values in a Brabender plastograph. The extrusion pastes were formulated using binder (methy cellulose, MC), solvent (water), plasticizer (ploy ethylene glycol, PEG) and lubricants (oleic acid, OA). The mixing sequence and optimum organic binder, at least for homogeneous mixed state, can be determined from the rheological point of view. 3%MC-30%$H_2O$-1.5%PEG-1.0%OA with respect to the cordierite powder was chosen as a binder composition for the extrusion process of cordierite powder.

The Effects of Osmogant and Binder in Membrane on Nifedipine Release from Osmotic Granule (니페디핀의 삼투성 과립에서 삼투염과 반투막내의 결합제 종류가 약물방출에 미치는 영향)

  • Jeong Sung-Chan;Cho Young-Ho;Kim Moon-Suk;Lee Bong;Khang Gil-Son;Rhee John-M.;Lee Hai-Bang
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.112-117
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    • 2006
  • To improve the type error of osmotic tablet which is one of the drug delivery system, osmotic granule could be manufactured by fluidized bed coating. It has drug layer containing different amount of osmogant and is coated with membrane including different types of binder. We confirmed that the morphology of osmotic granule was different at each coating step. The more mont of osmotic agent, the faster drug release was observed due to increasing the driving force for drug release from osmotic granule. And drug release from osmotic granule coated with membrane using different types of binder was differed by solubility of binders to water. The formation of pore in membrane was confirmed by SEM and DSC Membrane using water soluble binder released more amount of drug. From these results, we assured that difference of osmotic pressure between the inside and the outside of granule and porosity of membrane have an effect on drug release from osmotic granule.

The Strength Properties of Metal Matrix Composites by Binder Additives (금속기복합재료의 바인더 첨가제에 따른 강도 특성)

  • Park, Won-Jo;Huh, Sun-Chul
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.7
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    • pp.1051-1057
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    • 2003
  • This study is about controlled impurities, which make metal alloys, especially AC4CH alloy that is made by restraining 0.2% Fe and Aluminum to make a matrix material. A metal matrix composite is produced using the squeeze casting method. The first step in the squeeze casting method is to add some organic binder including aluminum borate whisker into the matrix. After the fabrication of a metal matrix composite, each is individually appended to an inanimate binder such as SiO$_2$, Al$_2$O$_3$, and TiO$_2$. Through experiments the mechanical property changes were investigated between the metal matrix composite and AC4CH alloy. This study proves the superiority of the mechanical property of a metal matrix composites over AC4CH according to the previous tests and results that were mentioned above. One excellent property of matrix material composites is the infiltrated TiO$_2$ reinforcement. This material is a good substitute for the existing materials that are used in the development of industries today.

Using Carboxylmethylated Cellulose as Water-Borne Binder to Enhance the Electrochemical Properties of Li4Ti5O12-Based Anodes

  • Liu, Lili;Cheng, Chongling;Liu, Hongjiang;Shi, Liyi;Wang, Dayang
    • Journal of Powder Materials
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    • v.22 no.5
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    • pp.315-320
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    • 2015
  • The present work reports a systematic study of using carboxymethylated cellulose (CMC) as water-borne binder to produce $Li_4Ti_5O_{12}$-based anodes for manufacture of high rate performance lithium ion batteries. When the LTO-to-CB-to-CMC mass ratio is carefully optimized to be 8:1:0.57, the special capacity of the resulting electrodes is $144mAh{\cdot}g^{-1}$ at 10 C and their capacity retention was 97.7% after 1000 cycles at 1 C and 98.5% after 500 cycles at 5 C, respectively. This rate performance is comparable or even better than that of the electrolytes produced using conventional, organic, polyvinylidene fluoride binder.