Browse > Article
http://dx.doi.org/10.4191/KCERS.2005.42.1.001

Effects of Suspension Composition on Defects in Aqueous Tape Casting of Alumina Ceramics: A Rheological Study  

Shin, Hyo-Soon (Central R&D Institute, Samsung Elctro-Mechanics Co. Ltd.)
Publication Information
Abstract
In aqueous alumina tape casting, the effects of altering the composition of the suspensions, the binders and the casting thickness were studied. The rheological behavior of the suspensions and the defects of the dried tapes were examined and the relationships between them are discussed. The changes in the defect regions reported in the previous paper were related with the rheological properties with variations of the binder, the composition and the casting thickness. The shear thinning factor increased with the organic content and the solid content (the decrease of water content). The apparent viscosity increased with the shear thinning factor. The relation between the shear thinning factor and the log apparent viscosity was similar for all binder types. In the relation between the defect free region and the rheological properties, the defect free region became narrower with increasing casting thickness. The defect free region is independent of binder type. Therefore, the thicker tape is more difficult to produce in aqueous alumina tape casting. Knowledge of the rheological properties of the suspensions could help Predict the defect type and the possibility of defect free dried tapes.
Keywords
Rheology; Alumina; Tape-casting;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 T. J. Soltesz, W. M. Carty, H. J. Miller, T. R. Armstrong, and P. A. Smith, 'A Rheological Process Control Diagram for Tape Casting,' Presented at the 99th Annual Meeting of the Am. Ceram. Soc., Cincinnati, OH (1997)
2 H. S. Shin 'The Effects of Suspension Composition on Defects in Aqueous Tape Casting of Alumina Ceramics,' J. Kor. Ceram. Soc., 41 [9] 647-52 (2004)   DOI   ScienceOn
3 E. P. Hyatt, 'Making Thin, Flat Ceramics-A Review,' Am. Ceram. Soc. Bull., 65 [4] 637-38 (1986)
4 G. N. Howatt, R. G. Breckenridge, and J. M. Brownlow, 'Fabrication of Thin Ceramic Sheets For Capacitors,' J. Am. Ceram. Soc., 30 [8] 237-42 (1947)   DOI
5 G. O. Dayton, W. A. Schulze, T. R. Shrout, S. Swartz, and J. V. Biggers, 'Fabrication of Electromechanical Transducer Materials by Tape Casting,' Adv. in Ceram., Vol. 9, Forming of Ceramics, Edited by J. A. Mangels and G. L. Messing, The Am. Ceram. Soc. Inc., 115-39 (1984)
6 R. E. Mistler, 'Tape Casting: The Basic Process for Meeting the Needs of the Electronics,' Am. Ceram. Soc. Bull., 69 [6] 1022-26 (1990)
7 B. Bitterlich, C. Lutz, and A. Roosen, 'Slurries for the Tape Casting Process,' Ceram. Int., 28 [6] 675-83 (2002)   DOI   ScienceOn
8 P. Nahass, W. E. Rhine, R. L. Pober, and H. K. Bowen, 'A Comparision of Aqueous and Non-Aqueous Slurries for Tape-Casting, and Dimensional Stability in Dried Tapes,' Ceram. Trans., Vol. 15, Materials and Processes for Microelectronic Systems, Edited by K. M. Nair, R. Pohanka, and R. C. Buchanan, The Am. Ceram. Soc. Inc., 355-64 (1990)
9 H. Loest, E. Mitsoulis, and S. Spauszus, 'Free Surface Measurements and Numerical Simulations of Ceramic Tape Casting,' Interceram, 42 [2] 80-4 (1993)
10 W. R. Schowalter, 'Mechanics of Non-Newtonian Fluids,' Pergamon Press Ins., 72-6 (1978)
11 Y. T. Chou, Y. T. Ko, and M. F. Yan, 'Fluid Flow Model for Ceramic Tape Casting,' J. Am. Ceram. Soc., 70 [10] C280-82 (1987)
12 H. Watanabe, T. Kimura, and T. Yamaguchi, 'Particle Orientation During Tape Casting in the Fabrication of Grain-Oriented Bismuth Titanate,' J. Am. Ceram. Soc., 72 [2] 289-93 (1989)   DOI   ScienceOn
13 R. Pitchumani and V. M. Karbhari, 'Generalized Fluid Flow Model for Ceramic Tape Casting,' J. Am. Ceram. Soc., 78 [9] 2497-503 (1995)   DOI   ScienceOn
14 R. J. Farris, 'Prediction of the Viscosity of Multimodal Suspensions from Unimodal Viscosity Data,' Trans. Soc. Rheol., 12 [2] 281-301 (1968)   DOI
15 H. Loest, E. Mitsoulis, and S. Spauszus, 'Free Surface Measurements and Numerical Simulations of Ceramic Tape Casting,' Interceram, 42 [2] 80-4 (1993)
16 H. Lost, R. Lipp, and E. Mitsoulis, 'Numerical Flow Simulation of Viscoplastic Slurries and Design Criteria for a Tape Casting Unit,' J. Am. Ceram. Soc., 77 [1] 254-62 (1994)   DOI   ScienceOn
17 R. W. Flumerfelt, M. W. Pierick, S. L. Cooper, and R. B. Bird, 'Generalized Plane Couette Flow of a Non-Newtonian Fluid,' Ind. Eng. Chem. Fund., 8 [2] 354-57 (1969)   DOI