• Title/Summary/Keyword: Organic additive

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High-Mobility Ambipolar Polymer Semiconductors by Incorporation of Ionic Additives for Organic Field-Effect Transistors and Printed Electronic Circuits (이온성 첨가제 도입을 통한 고이동도 고분자 반도체 특성 구현과 유기전계효과트랜지스터 및 유연전자회로 응용 연구)

  • Lee, Dong-Hyeon;Moon, Ji-Hoon;Park, Jun-Gu;Jung, Ji Yun;Cho, Il-Young;Kim, Dong Eun;Baeg, Kang-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.3
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    • pp.129-134
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    • 2018
  • Herein, we report the manufacture of high-performance, ambipolar organic field-effect transistors (OFETs) and complementary-like electronic circuitry based on a blended, polymeric, semiconducting film. Relatively high and well-balanced electron and hole mobilities were achieved by incorporating a small amount of ionic additives. The equivalent P-channel and N-channel properties of the ambipolar OFETs enabled the manufacture of complementary-like inverter circuits with a near-ideal switching point, high gain, and good noise margins, via a simple blanket spin-coating process with no additional patterning of each active P-type and N-type semiconductor layer.

Effects of Air Supply Rate and Eggshell Addition on Liquid Fertilizer Efficiency of Aerobic Stabilized Organic Wastewater Sludge (공기공급량과 계란 껍질 첨가가 유기성 폐수슬러지 액비 비효효과에 미치는 영향)

  • Cheon, Hyo-Chang;Hwang, Eung-Ju;Kim, Sang-Hyoun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.8
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    • pp.578-582
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    • 2011
  • Aerobic digestion of organic sludge generates stabilized slurry which could be used as a nitrogen-rich liquid fertilizer. In this study, the effects of air supply rate and eggshell addition on the sludge fertilizer efficiency were examined. Sludge from a wastewater treatment plant in a food industry was fed to a lab-scale aerobic digester, and the fertilizer efficiency was assessed by the growth of cucumber. Increase of air supply rate up to 200 mL/L/min enhanced the fertilizer efficiency as well as the nitrification efficiency. The addition of eggshell, a potassium-rich leftover, in fertilizer application was also beneficial to the cucumber growth. A proper control of air supply rate and the use of an inexpensive additive would guarantee the quality of sludge liquid fertilizer.

Optimization of Aqueous Methanol Extraction Condition of Total Polyphenol from Spent $Lycium$ $chinense$ Miller to Develop Feed Additives for Pig (양돈용 사료 첨가제 개발을 위하여 구기자 부산물로부터 메탄올수용액을 이용한 총 폴리페놀 추출조건 최적화)

  • Shim, Kwan-Seob;Na, Chong-Sam;Oh, Sung-Jin;Choi, Nag-Jin
    • Korean Journal of Organic Agriculture
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    • v.20 no.1
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    • pp.91-99
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    • 2012
  • This study was conducted to develop a functional feed additive for pig with spent $Lycium$ $chinense$ Mill fruit. We investigated the optimum conditions for the extraction of polyphenol from spent $Lycium$ $chinense$ Mill using methanol. Methanol concentration as a solvent for extraction, extraction time and the volume of solvent per a gram of solid (ground spent Lyceum chinense Mill) were selected as parameters. Three levels of parameters were configured according to Box Behnken experiment design, a fractional factorial design, and total 15 trials were employed. Total polyphenol concentration from each trial was used as response from experiment system and effects of parameters on total polyphenol extraction efficiency were determined using response surface model. As a result, all terms in analysis of variance, regression ($p$ = 0.001), linear ($p$ = 0.002), square ($p$ = 0.017) and interaction ($p$ = 0.047) was significant and adjusted determination coefficient ($R^2$) was 94.7%. Total polyphenol extraction efficiency was elevated along increased methanol content and decreased solvent to solid ratio. However extraction time did not affect the efficiency. This study provides a primary information for the optimum extraction conditions to maximize total polyphenol recovery from spent Lycium chinens Mill fruit and this result could be applied to re-use of argo-industrial by-products and to develop of functional feed additives in organic farming.

Unhardening Phenomena of SCW constructed in Organic Soil (가설 토류벽용 SCW의 미경화 현상)

  • 김교원;송정락;강기영
    • The Journal of Engineering Geology
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    • v.1 no.1
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    • pp.11-18
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    • 1991
  • A series of laboratory tests were conducted to verify the unhardening phenomena of Soil-Cement Wall (SCW) and the results are presented in this paper. Specimens are prepared by mixing the site soil with cement and additives at a various ratio. The hydration of the cement mixed with the in-situ soil was retarded due to the higher organic content of the soil. In order to remove the influence of the organic matters in hydration reaction, calcium chloride (CaCI$_2$) was added as an acceleration additive at a different ratio. The optimum ratio of the calcium chloride for the higher SCW strength was determined as 2% of cement weight. The strength, however, was decreased by adding 4 and 6% of the additives. The effect of other additives, NaOH and NaSiO$_2$, were also investigated and the results are included. The strength of SCW by adding sodium hydroxide was lowered. And the short term strength by adding sodium silicate was increased but the long term strength was decreased.

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Cloning, Expression, and Characterization of a Cold-Active and Organic Solvent-Tolerant Lipase from Aeromicrobium sp. SCSIO 25071

  • Su, Hongfei;Mai, Zhimao;Yang, Jian;Xiao, Yunzhu;Tian, Xinpeng;Zhang, Si
    • Journal of Microbiology and Biotechnology
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    • v.26 no.6
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    • pp.1067-1076
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    • 2016
  • The gene encoding lipase (Lip98) from Aeromicrobium sp. SCSIO 25071 was cloned and functionally expressed in Escherichia coli. Lip98 amino acid sequence shares the highest (49%) identity to Rhodococcus jostii RHA1 lipase and contains a novel motif (GHSEG), which is different from other clusters in the lipase superfamily. The recombinant lipase was purified to homogeneity with Ni-NTA affinity chromatography. Lip98 showed an apparent molecular mass of 30 kDa on SDS gel. The optimal temperature and pH value for enzymatic activity were recorded at 30℃ and 7.5, respectively. Lip98 exhibited high activity at low temperatures with 35% maximum activity at 0℃ and good stability at temperatures below 35℃. Its calculated activation energy was 4.12 kcal/mol at the low temperature range of 15-30℃. Its activity was slightly affected by some metal ions such as K+, Ca2+, and Na+. The activity of Lip98 was increased by various organic solvents such as DMSO, ethanol, acetone, and hexane with the concentration of 30% (v/v) and retained more than 30% residual activity in neat organic solvent. The unique characteristics of Lip98 imply that it is a promising candidate for industrial application as a nonaqueous biocatalyst and food additive.

INTUMESCENT INORGANIC AND ORGANIC COATINGS

  • Kodolov, V.I.;Mikhalkina, T.M.;Shuklin, S.G.;Bystrov, S.G.;Larionov, K.I.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.130-137
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    • 1997
  • Intumescent inorganic and organic coatings which dintr one from the other by the type of gas formers and the mechanisms of foam formation have been obtained and investigated. Inorganic intumescent coatings are the compositions based on water glass and mineral additives with different dispersity. Mineral additives contain adsorbed and absorbed water and carbonates which are destructed with the carbon dioxide and water evolution during the flame action on coating. The decreasing of mineral additives particle sizes under the mechanical milling with the fraction precipitation promotes the foam coke formation with less defects. Here the main structure of comparing compositions does not change. In organic coatings based on epoxy-polymers the polyammonium phosphate additive is used. It is the cabonization catalyst and the foam agent. The polyammonium phosphate of various dispersity employed is uniformly distributed on the polymeric matrix. The decreasing of the particle sizes leads to the increasing of the fire resistant properties of the intumescent coa-ting. The fire resistant analysis of the coating during more than an hour: the coating back side the temperature on plastic or wooden materials does not exceed 423K, and on metal-573K.

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Effects of a mixture of essential oils and organic acid supplementation on growth performance, blood profiles, leg bone length, and intestinal morphology in broilers

  • Liu, Shu Dong;Song, Min Ho;Yun, Won;Lee, Ji Hwan;Cho, Seung Yeol;Kim, Gok Mi;Kim, Hyeun Bum;Cho, Jin Ho
    • Korean Journal of Agricultural Science
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    • v.46 no.2
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    • pp.285-292
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    • 2019
  • This study was done to evaluate the effects of a mixture of essential oils and organic acid supplementation on growth performance, blood profiles, leg bone length and intestinal morphology in Ross broilers. A total of 40 Ross 308 broilers ($1140{\pm}80g$) were randomly allocated to 2 groups, a basal diet (CON) and a basal diet + 0.05% $Avi-protect^{(R)}$ (AVI, Mixture of 25% citric, 16.7 sorbic, 1.7% thymol, and 1.0% vanillin), with 20 replicates for every group and 1 chicken per replicate per cage. The broilers were raised in a temperature-controlled room maintained at $24{\pm}1^{\circ}C$ and $50{\pm}5%$ humidity. The body weight (p < 0.05) and weight gain (p < 0.05) of the broilers were increased in the AVI group compared with the CON group. The triglyceride (p < 0.05) and low density lipoprotein (LDL) (p < 0.05) contents were significantly decreased in the AVI group compared with the CON group. There was no significant difference in the leg bone length between the AVI and CON groups (p > 0.05). The villi height (p < 0.05) and goblet cell count (p < 0.05) were significantly increased in the AVI group compared with the CON group. In conclusion, $Avi-protect^{(R)}$ as a feed additive improved the growth performance and lipid metabolism and promoted the development of the intestinal morphology of broilers.

Evaluation for Volatile Organic Compounds (VOCs) Emitted from Fused Deposition Modeling (FDM) 3D Printing Filaments (FDM 3D프린터 소재에서 방출될 수 있는 휘발성유기화합물 평가)

  • Kim, Sungho;Park, Hae Dong;Chung, Eunkyo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.32 no.2
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    • pp.153-162
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    • 2022
  • Objectives: Fused deposition modeling (FDM) 3D printer which is one of the material extrusion (MEX) technologies is an additive manufacturing (AM) process. 3D printers have been distributed widely in Korea, particularly in school and office, even at home. Several studies have shown that nanoparticles and volatile organic compounds (VOCs) were emitted from an FDM 3D printing process. The objective of this study was to identify types of chemicals possibly emitted from FDM 3D printing materials such as PLA (polylactic acid), ABS (acrylonitrile butadiene styrene), nylon, PETG (polyethylene terephthalate glycol), PVA (polyvinyl alcohol), PC (polycarbonate) filaments. Methods: 19 FDM 3D printing filaments which have been distributed in Korea were selected and analyzed VOCs emitted of 3D printing materials by headspace gas chromatography mass spectrometry (headspace GC-MS). Subsamples were put into a vial and heated up to 200℃ (500 rpm) during 20 minutes before analyzing FDM 3D printing filaments. Results: In the case of PLA filament, lactide and methyl methacrylate, the monomer components of one, were detected, and the volume ratio ranged 27~93%, 0.5~37% respectively. In the case of ABS filaments, styrene (50.5~59.1%), the monomer components of one, was detected. Several VOCs among acetaldehyde, toluene, ethylbenzene, xylene, etc were detected from each FDM 3D printing filaments. Conclusions: Several VOCs, semi-VOCs were emitted from FDM 3D printing filaments in this study and previous studies. Users were possibly exposed to ones so that we strongly believe that we recommend to install the ventilation system such as a local exhaust ventilation (LEV) when they operate the FDM 3D printers in a workplace.

Synthesis and Characterization of Ion Exchange Particles for Application of Anion Exchange Membrane (음이온교환막 적용을 위한 이온교환입자의 합성 및 특성평가)

  • Dong Jun Lee;Kwang Seop Im;Ka Yeon Ryu;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.3
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    • pp.137-147
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    • 2023
  • In this study, Br-PPO was developed by applying additive organic particles through a suspension polymerization synthesis method. The anion exchange membrane fuel cell system performance was evaluated using it to an anion exchange membrane. To improve the performance, organic ion exchange particles were prepared and added to the anion exchange membrane. Chemical structure analysis and synthesis were determined through FT-IR and NMR, and tensile strength and thermal stability were measured through TGA and UTM to determine whether it could be driven. Before the anion exchange membrane fuel cell test, the performance was evaluated by measuring the ion conductivity and ion exchange capacity. Finally, the Br-PPO-TMA-SDV (0.7%) anion exchange membrane with excellent ion conductivity and ion exchange capacity was introduced into the fuel cell system. Its performance was compared with FAA-3-50, a commercial membrane, to determine whether it could be introduced into a fuel cell system.

Studies on the Quality and Utilization of Pumpkin Silages (호박 Silage의 품질(品質) 및 이용성(利用性)에 관(關)한 연구(硏究))

  • Kim, Y.K.;Kim, S.K.
    • Korean Journal of Agricultural Science
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    • v.3 no.1
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    • pp.77-84
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    • 1976
  • The preservation efficiency, quality and utilization of silage from 3 species of pumpkins (Mammoth pumpkin, Queensland blue pumpkin, Korean pumpkin) without and with 10, and 20% wheat bran additive were studied in this experiment. Silages were analysised and tested the chemical composition, pH and quality of silages between at 40-60 days and egg performance were carried out with mammoth pumpkin silage without additive. The results were summaried as follows. 1. The losses of all silage ware lower and similar as about 15% at 6 monthes following after silage-making but all raw pumpkins were spoilaged during the winter storaging. 2. The moisture content of silages were higher as about 97% in mammoth pumpkin silage, 94% in Queensland pumpkin silage and 91% in Korean pumpkin silage without additive and all nutrient content of silage without and with additive were depended on its content of raw silage material of pumpkins and wheat bran. The contents of moisture and N-free extract were slightly decrease but not significantly difference during the silaging and other contents were not so much changed. 3. Good quality of silage were made from all pumpkins with and without additive. Organic acid contents were 2.09-2.93% of lactic acid, 0.68-1.71% of acetic acid and 0% of butyric acid and it was pH 3.8-4.0 in silages. 4. Feed intakes, egg production and quality of egg were showed good result in 5.0 and 7.5% silage feeding group as D.M. base for egg performance. (P<0.01) 5. It was concluded that good quality of silage were made from pumpkins with and without wheat bran additive and it was suggested that poor quality feedstuff may be improved it feeding value by extended palatability with pumpkin additive silage.

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