• Title/Summary/Keyword: Organic acid mixture

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Study on Organic Material Used in Bioreactor for the Treatment of Acid Mine Drainage (산성 광산 폐수 처리용 생물반응기에 사용되는 유기물의 연구)

  • 김경호;나현준;이성택
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.45-50
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    • 1997
  • The change of industrial structure has brought the sharp declination of mine products, and has made many mines closed, which results in environmental pollution by untreated acid mine drainage(AMD). AMD with low pH and high concentration of heavy metals could severely destroy the ecosystem. Many researches have been carried out for the treatment of AMD. In this study, we have treated AMD with oak compost, mushroom compost, sludge cake and cow manure which usually used in AMD treatment systems, and compared the capability of each organic matter. Cow manure and oak compost have been most effective among 4 organic materials. Oak compost removed the heavy metals by ion exchange between Ca-rich particles and soluble heavy metal ions. It also captured the heavy metals using bound functional groups like -OH and -COO-. Sulfate reducing bacteria existing in the cow manure removed effectively heavy metals by producing metal sulfide compound. Therefore, it is effective to use both organic materials in mixture on the treatment of AMD.

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Hydrolysis of Castor Oil with Lipases and Organic Solvents (Lipase와 유기용매를 이용한 Castor Oil의 가수분해)

  • Jeon, Gyu-Jong;Hur, Byung-Ki;Yang, Ji-Won
    • KSBB Journal
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    • v.14 no.6
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    • pp.696-701
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    • 1999
  • The enzymatic hydrolysis of Castor oil for the mass production of ricinoleic acid was studied to find out the optimum conditions such as solvents and the weight ratio of substrate to enzyme. Three different lipases were tested for the hydrolysis of castor oil: lipase from Porcine Pancrease(lipsase PP), lipase from Candida cylindracea(lipase CC), lipase from Candida Rugosa(lipase CR). The poor mass transfer in water caused a low degree of hydrolysis of castor oil. To overcome this problem, organic solvents were used. Among organic solvents tested, hydrophobic solvents gave better results of hydrolysis than hydrophilic solvents. Organic solvents also lowered or changed the effect of pH. Isopropyl ether made complete hydrolysis of castor oil. The ratio of water to isopropyl ether and the ratio of weight ratio of lipase to castor oil were important for the hydrolysis of castor oil. At 30$^{\circ}C$ castor oil was completely hydrolyzed by 4 wt% of lipase in the mixture of isopropyl ether and water(1:1 in volume).

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Development of Fluid Silicic Acid Coating with Paint Materials of the Steel Electric Power Facilities (강재 전력시설물을 위한 액상 규산질 도장제 개발에 대한 연구)

  • Kwon, Seung-Jun;Park, Sang-Sun;Lee, Sang-Min;Lee, Myung-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.1
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    • pp.57-64
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    • 2008
  • Generally, organic paint on steel towers can guarantee durability in normal condition but occasionally shows its deterioration on the power line tower and electric power facilities, exposed to light(ultra violet) or heat. The objective of this study is to develope the inorganic paint material based on fluid silicic acid for steel electric power facilities. For the purpose, optimal mixture proportion is derived through 6 preliminary test and, additionally physical and durability performance test are carried out for selected specimens. The performances of developed organic paint material is similar to those of organic paint material. If resistance to chemical attack is improved, the developed inorganic paint is evaluated to replace the organic paint and obtain wide application.

Changes of the Microbial Population and Determination of Pepsin and In vitro Digestibilities of Pasteurized and Cured Food Wastes (살균${\cdot}$숙성된 남은 음식물의 공정별 미생물 분포 및 Pepsin과 In vitro 소화율 평가)

  • Baik, Y. H.;Ji, K. S.;Kwak, W. S.
    • Journal of Animal Environmental Science
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    • v.11 no.2
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    • pp.125-134
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    • 2005
  • This study was conducted to evaluate changes of microbial population, pepsin digestibility of protein and in vitro digestibility of nutrients of food waste mixture pasteurized and cured using a rotary drum system. A pasteurization process (30 min at $80^{\circ}C$) tended to decrease microbial populations and eliminated (P<0.05) molds in food waste mixture. The subsequent curing process increased (P<0.05) lactic acid bacteria counts which were reduced by the heated pasteurization process. The heated pasteurization process decreased (P<0.05) pepsin digestibility of protein in food waste mixture. In vitro digestibilities of dry matter and organic matter were high in the order of bakery by-product, wheat bran, food waste (=barley bran). These results indicate that food waste mixture pasteurized and cured using a semi-dehydration rotary drum system may be an effective animal feed resource.

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Electrochemical Properties and Photoisomerization of DOPC-8A5H Mixture Langmuir-Blogett Films (인지질(DOPC)과 지방산(8A5H)의 혼합 LB막의 광이성질화 현상과 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun;Kim, Nam-Seok;Kim, Duck-Sool
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.874-877
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    • 2004
  • We carried out this subject to observe electrochemical properties of 1,2-dioleoyl-sn- glycero-3-phosphocholine(DOPC) mixed with fatty acid containing azobenzene group by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution. We investigated the photoisomerization and electrochemical property of the organic ultra thin film of fatty acid containing azobenzene was prepared on the hydrophilic ITO(idium tin oxide) glass plate by LB method. As a result, the absorption spectra of BASH and DOPC of mixture LB films was induced to photoisomerization by alternating irradiation of ultraviolet and visible light. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of BASH-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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Reaction of Potassium Fluoride with Orgarnic Halogen Compound-II. Dimerization, Fluorination, and Decarboxylation of Organic Iodo acids, Iodides, and Polychlorinated Acid Ester (有機할로겐化合物과 KF 과의 反應 (第2報) 有機요-드酸, 沃化物 及 多鹽素化有機酸, 에스텔의 雙合, 弗化 及 脫炭酸 反應에 關하여)

  • Kim, You-Sun
    • Journal of the Korean Chemical Society
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    • v.8 no.4
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    • pp.135-141
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    • 1964
  • The reaction of potassium fluoride with amyl iodide in presence of dimethylformamide at low temperature gave a fluorination product together with decane. Polyhalogenated acid such as ${\alpha}$, ${\beta}$,-dichloro-${\beta}$-phenyl-propionic acid gave ${\alpha}$-chlorostyrene, fluorinated styrene, and fluorinated acid. The same reaction with the ethyl ester did not give the fluorination product and gave a mixture of various dimerized product. Dibromostyrene gave bromostyrene together with fluorination product. Iodo acid such as m-iodo acid gave the salt and a trace quantity of dimerized product. Iodides such as m-iodotoluene and 1-amino-4-iodo-2-methyl benzene did not show any appreciable reactivity towards potassim fluoride. The reaction condition was described, and fluorination, ${\alpa}$-dehydrofluorination, decarboxylation, and dimerization were discussed.

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Chemical Modification of Carbon Nanotubes and Preparation of Polystyrene/Carbon Nanotubes Composites

  • Ham, Hyeong-Taek;Koo, Chong-Min;Kim, Sang-Ouk;Park, Yeong-Suk;Chung, In-Jae
    • Macromolecular Research
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    • v.12 no.4
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    • pp.384-390
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    • 2004
  • Single-walled carbon nanotubes (SWNTs) have been chemically modified through the formation of carboxylic acid functionalities or by grafting octadecylamine and polystyrene onto them. We purified SWNTs with nitric acid to remove some remaining catalysts and amorphous carbon materials. After purification, we broke the carbon nanotubes and shortened their lengths by using a 3:1 mixture of concentrated sulfuric acid and nitric acid. During these purification and cutting processes, carboxylic acid units formed at the open ends of the SWNTs. Octa-decylamine and amino-terminated polystyrene were grafted onto the cut SWNTs by condensation reactions between the amine and carboxylic acid units. The cut SWNTs did not disperse in organic solvents, but the octadecylamine-grafted and polystyrene-grafted SWNTs dispersed well in dichloromethane and aromatic solvents (e.g., benzene, toluene). Composites were prepared by mixing polystyrene with the octadecylamine-grafted or polystyrene-grafted SWNTs. Each composite had a higher dynamic storage modulus than that of a pristine polystyrene. The composites exhibited enhanced storage moduli, complex viscosities, and unusual non-terminal behavior when compared with a monodisperse polystyrene matrix because of the good dispersion of carbon nanotubes in the polystyrene matrix.

Zymological characteristics of Cheju folk wine made of foxtail millet (제주토속 좁쌀약주의 약조특성)

  • Koh, Jeong-Sam;Yang, Young-Taek;Ko, Young-Hwan;Kang, Yeung-Joo
    • Applied Biological Chemistry
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    • v.36 no.4
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    • pp.277-283
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    • 1993
  • In order to brew foxtail millet wine, a folk wine of Cheju, properties of raw materials, optimum brewing conditions were inveatigated. Carbohydrate and crude fat content of glutinuous foxtail millet are 71.27% and 3.47%, respectively. Since the ratio of water to steamed millet and ethanol concentration of wine showed negative correlation, less than 250% water had to added to steamed millet to maintain ethanol concentration in wine above 13%, Sugar consumption and ethanol production increased rapidly for the first 2 days, and main fermentation was done in 4 days. Ethanol concentrations were $13.0{\sim}13.4%$ when foxtail millet was used, and they were $14.0{\sim}14.3%$ for the mixture substrates of 90% millet and 10% rice or barley. Organic acids in millet wine were lactic acid, malic acid and succinic acid. The residual carbohydrates after fermentation were mainly xylose and oligosaccharides. A trace of methanol was detected in millet wine. The content of fusel oil was low, while the concnetration of organic acids was high. Optimum conditions for millet wine-making were as follows. Glutinuous foxtail millet with 10% rice as fermentation source need to be soaked in water and steamed for enough time. Water was added to steamed millet with the ratio of 2 : 1. The resulting mixture was stmnultaneously saccharified and fermented by Aspergillus orzae and Saccharomyces cerevisiae IAM 4274 at $20^{\circ}C$ for a week. Millet wine was prepared after filtering fermented broth while pressing for a week.

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Effect of Acetic and Lactic Acid Mixtures on Control of Quarantine Nematode, Bursaphelenchus xylophilus, in Exporting Cymbidium (초산과 젖산 혼합액에 의한 수출용 심비디움 검역선충 Bursaphelenchus xylophilus의 방제 효과)

  • Seo, Yunhee;Park, Jiyeong;Cho, Myoung Rae;Chun, Jae Yong;Kim, Young Ho
    • Research in Plant Disease
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    • v.20 no.3
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    • pp.227-233
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    • 2014
  • The mixture (MX) of acetic acid (AA) and lactic acid (LA) was examined for its effectiveness in the control of the pine wood nematode Bursaphelenchus xylophilus contaminated in cymbidium culture medium. Nematode mortality in vitro was nearly 100% in AA and MX at the concentrations of 5.0-1.0% (pH 2.6 - 4.2) and in LA only at 5.0% (pH 3.5), but lowered at concentrations of 0.5-0.1% (pH 5.1-6.9) more significantly in LA than AA and MX. MX of most concentrations caused higher nematode mortality than the average response to AA and LA. All treatments of MX (0.5% and 0.25%), fosthiazate (standard and double concentrations) and culture dilution of Paenibacillus polymyxa GBR-1 ($10^7$colony-forming units/ml) reduced significantly the nematode populations in the cymbidium culture medium, compared to non-treatment control, with no significant difference among the treatments. No phytotoxicity occurred in all treatments. pH of the medium with the time after treatment and growths of 2-year-old cymbidium were not significantly different among treatments. Considering the safety and price of the organic acids, use of MX in the processes for culturing cymbidium may be a practically reliable and eco-friendly way in the control of the quarantine nematode in cymbidium.

Equilibrium investigation for dyes removal using a mixed adsorbent

  • Ravikumar, K.;Son, Young-A
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.48-52
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    • 2006
  • A mixed adsorbent prepared by pyrolysing a mixture of carbon and flyash in 1:1 ratio was tested for its deceleration ability for three different classes of dyes, namely Astrazone Blue FRR(C.I. Basic Blue 69), Teflon Blue ANL(C.I. Acid Slue 125) and Verofix Red(Reactive Red 3GL). Equilibrium investigations were carried out at the optimum conditions obtained in the previous studies. The equilibrium data fitted reasonably well to both the Freundlich and Langmuir adsorption models. However the Langmuir model was more appropriate to describe the adsorption behavior of the dyes to the hybrid absorbent system compared with the Freundlich model. The mixed adsorbent cm be an low-cost alternative to activated carbons.