• Title/Summary/Keyword: Organic Pollutants

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Study on Health Risk Assessment of Carcinogenic Chemicals in Drinking Water (음용수 중 유해 화학 물질에 대한 위해성 평가에 관한 연구 - I. 발암성 화학 물질을 중심으로 -)

  • Chung, Yong;Shin, Dong-Chun;Kim, Jong-Man;Park, Seong-Eun;Yang, Ji-Yeon;Lee, Ja-Koung;Hwang, Man-Sik;Park, Yeon-Shin
    • Environmental Analysis Health and Toxicology
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    • v.10 no.1_2
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    • pp.1-14
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    • 1995
  • The purpose of this research is to assess the health risk of pollutants in drinking water and recommend the guidelines and management plans for maintaining good quality of drinking water. This study has been funded as a national project for three years from 1992 to 1995. This study(the second year, 1993-1994) was conducted to monitor 32 species of carcinogenic chemicals such as volatile organic compounds(VOCs), polynuclear aromatic hydrocarbons(PAHs), pesticides and heavy metals of drinking water at some area in six cities of Korea, and evaluate health risk due to these chemicals through four main steps of risk assessment in drinking water. In hazard identification, 32 species of carcinogenic chemicals were identified by the US EPA classification system. In the step of exposure assessment, sampling of raw, treated and tap water from the public water supply system had been conducted from 1993 to 1994, and 32 chemicals were analyzed. In dose-response assessment, cancer potencies, unit risk estimates and virtually safe doses of carcinogens were obtained by TOX-RISK (Version 3.1). In risk characterization of detected chemicals, health risk due to carcinogens such as vinyl chloride, carbon tetrachloride, dichloromethane, 1, 2-dichloromethane, chloroform, benzene and arsenic of tap water in several cities exceeded 10$^{-5}$ level. We suggest that non-regulated chemicals which exceed 10$^{-5}$ excess cancer risk level, such as vinyl chloride, carbon tetrachloride and 1, 2-dichloroethane, should be monitored periodically and be regulated by the Drinking Water Management Act, and database for exposure parameter of our own situation should be established.

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An Analysis of First Flush Phenomenon of Non-point Source Pollution during Rainfall-Runoff Events from Impervious Area (불투수성 지역의 강우유출수에 대한 비점오염물질의 초기유출현상 분석)

  • Ahn, Tae-Ung;Bum, Bong-Su;Kim, Tae-Hoon;Choi, I-Song;Oh, Jong-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.9
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    • pp.643-653
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    • 2013
  • In this study, trend analysis was performed by various runoff analysis method of Non-point Pollution Source(NPS) at the impervious area. The characteristics of rainfall at impervious area appeared to be influenced by rainfall strength and it appeared that first flush phenomenon occurs often if rainfall strength acts largely. It is judged that the measure is required to be prepared against that now that concentration difference of non-point pollution source appeared to be big by precedent number of days of no rainfall. As the result of calculating Decrease Rate (DR) by first flush of non-point pollution source, it is judged that it is important to prepare the measure against the pollutants about initial rain and it is necessary to calculate the capacity of non-point pollution source processing facilities regarding that now that the non-point pollution source integrated at impervious area showed the characteristics that are flowed out in high concentration by initial rain in case of non-rainfall considering the characteristics of non-point pollution source at impervious area. When taking 50% of non-point pollution source as the standard for decrease rate that was evaluated previously, it appeared as 15~60 min in case of TSS and it appeared as 30~90 min in case of organic compound, but the characteristic whose decrease rate is below 50% also appeared even till rainfall-runoff ends. Based on that, it is judged that it could be used as the reference when designing the structural BMPs facilities later.

Assessment of Performances of Low Impact Development (LID) Facilities with Vegetation (식생이 조성된 LID 시설의 효율 평가)

  • Hong, Jung Sun;Kim, Lee-Hyung
    • Ecology and Resilient Infrastructure
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    • v.3 no.2
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    • pp.100-109
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    • 2016
  • Low impact development (LID) facilities are established for the purpose of restoring the natural hydrologic cycle as well as the removal of pollutants from stormwater runoff. Improved efficiency of LID facilities can be obtained through the optimized interaction of their major components (i.e., plant, soil, filter media, microorganisms, etc.). Therefore, this study was performed to evaluate the performances of LID facilities in terms of runoff and pollutant reduction and also to provide an optimal maintenance method. The monitoring was conducted on four LID technologies (e.g., bioretention, small wetlands, rain garden and tree box filter). The optimal SA/CA (facility surface area / catchment area) ratio for runoff reduction greater than 40% is determined to be 1 - 5%. Since runoff reduction affects the pollutant removal efficiency in LID facilities, SA/CA ratio is derived as an important factor in designing LID facilities. The LID facilities that are found to be effective in reducing stormwater runoff are in the following order: rain garden > tree box filter > bioretention> small wetland. Meanwhile, in terms of removal of particulate matter (TSS), the effectiveness of the facilities are in the following order: rain garden > tree box filter > small wetland > bioretention; rain gardens > tree box filter > bioretention > small wetland were determined for the removal of organic matter (COD, TOC), nutrients (TN, TP) and heavy metals (Cu, Pb, Cd, Zn). These results can be used as an important material for the design of LID facilities in runoff volume and pollutant reduction.

Plant uptake potential of endosulfan from soil by carrot and spinach (다소비 채소작물인 시금치와 당근의 토양 중 엔도설판 흡수이행능)

  • Choi, Geun-Hyoung;Jeong, Dong-Kyu;Lim, Sung-Jin;Ro, Jin-Ho;Ryu, Song-Hee;Park, Byung-Jun;Moon, Byung-Cheol;Kim, Jin Hyo
    • Journal of Applied Biological Chemistry
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    • v.60 no.4
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    • pp.339-342
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    • 2017
  • Residual endosulfan in an agricultural environment has been reported, although endosulfan was listed to persistent organic pollutants and banned. To produce the safe crop from endosulfan residue risk, the plant uptake potential of endosulfan from soil to crop should be studied. In here, the plant uptake potentials of endosulfan in various crops were surveyed and ranged from 0.002-4.460. And the bioconcentration factors (BCF) of total endosulfan in carrot and spinach were calculated from the pot experiment. The BCFs in carrot and spinach were 0.285 and 0.040-0.047 respectively. Endosulfan sulfate was contributed to over 42.8% of the crop residue as a major contributor among the three endosulfan congeners in both of carrot and spinach.

Temporal and Spatial Distribution of Benthic Polychaetous Community in the northern Jinhae Bay (진해만 북부해역 저서다모류 군집의 시$\cdot$공간적 분포)

  • Lim, Kyeong-Hun;Shin, Hyun-Chool
    • Korean Journal of Environmental Biology
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    • v.23 no.3 s.59
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    • pp.238-249
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    • 2005
  • The present study was carried out to apprehend that the pollutants originating from Jinhae Industrial Complex affect benthic polychaetous community in the northern Jinhae bay. An investigation on the macrobenthic community in Jinhae bay was conducted in September, December of 2002 and March of 2003. The benthic fauna showed mean density of 2,151 ind. $m^{-2}$ in September of 2002, 2,427 ind. $m^{-2}$ in December of 2002 and 2,394 ind. $m^{-2}$ in March of 2003. Major faunal groups are polychaetes, crustaceans and mollusks, corresponding to $73.7\%,\;12.0\%\;and\;11.7\%,$ in total mean density during all of the sampling season, respectively. The most abundant species was Lumbrineris longifolia $(24.85\%),$ followed by Tharyx sp. $(21.70\%),$ Mesochaetopterus sp. $(6.20\%),$ Heteromastus filiformis $(5.39\%),$ Prionospio sp. $(5.18\%),$ Clycinde sp. $(4.29\%),$ etc. Tharyx sp. was the highest abundant species in September of 2002, and Lumbrineris longifolia was the dominant species in another sampling seasons. The density and the species number of polychaetes were high around Chori Is. and poor near Jinhae Industrial Complex area. Cluster analysis based on the species composition showed that Jinhae bay could be divided into three regions except in March of 2003. In December of 2002, there are very distinct regions by the cluster analysis. The density of benthic polychaetes in Jinhae bay was higher than that in the other coastal area of Korea, due to the predominance by some of opportunistic species, such as Lumbrineris longifolia, Tharyx sp. and Heteromastus filiformis, etc. It means that the study area were in the process of organic enrichment.

A Geochemical Study on the Dispersion of Heavy Metal Elements in Dusts and Soils in Urban and Industrial Environments (도시 및 산업환경 분진 및 토양중의 중금속 원소들의 분산에 관한 지구화학적 연구)

  • Chon, Hyo-Taek;Choi, Wan-Joo
    • Economic and Environmental Geology
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    • v.25 no.3
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    • pp.317-336
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    • 1992
  • The garden soils, main road dusts, residential road dusts, and playground soils/dusts of Seoul, Geumsan, Onsan, and Taebaek areas were analyzed in order to investigate the level of heavy metal pollution by urbanization and industrialization. The soil pH is in the range of 5.48~8.40 and was generally neutral. The color of soils and dusts is mainly Raw Umber to dark greyish Raw Umber. Some samples from Taebaek city, a coal mining area, showed a deep black color due to contamination by coal dusts. Major minerals of the dusts and soils are quartz, feldspars, and micas, reflecting the composition of the parent rocks. However, pyrite was found as a major mineral in the samples of industrial road dusts of Onsan, a smelting area, and resicential road dusts of Taebaek. Thus, the high level of heavy metals in mining and smelting areas can be explained with the sulfide minerals. The mode of occurences of heavy metals in Seoul, a comprehensive urbanized area, were related to the metallic pollutants and organic materials through observation by scanning eletron microscopy. In main road and residential road dusts of Onsan area, Cd, Zn, and Cu were extremely high. Some industrial road and residential road dusts of Seoul area showed high Cu, Zn, and Pb contents, wereas some garden soils and residential road dusts of Taebaek area were high in As content. In general, the heavy metal contents in dust samples were two to three times higher than those in soil samples. Main road dust samples were the most reflective from the discriminant analysis of multi-element data. Cadmium, Sb, and Se in Onsan area, As in Taebaek area, Pb and Te in Seoul area were most characteristic in discriminating the studied areas. Therefore, Cd in smelting areas, As in coal mining areas, and Pb in metropolitan areas can be suggested as the characteristic elements of each pollution pattern. The dispersion of heavy metal elements in urban areas tends to orignate in main roads and deposit in garden soils through the atmosphere and residential roads. The heavy metal contamination in Seoul is characteristic in areas with high population, factory, road, and traffic decsities. Heavy metal contents are high in the vicinity of smelters in Onsan area and are decayed to background levels from one kilometer away from the smelters.

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Use of Plant Materials for Decontamination of Waste Water Polluted with 2,4-Dichlorophenol (2,4-Dichlorophenol로 오염된 폐수의 정화를 위한 식물체의 이용)

  • Lee, Jung-Eun;Park, Jong-Woo;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.18 no.3
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    • pp.292-297
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    • 1999
  • This study was performed to estimate the possibility of use of plant materials as catalytic agents fur the decontamination of waste waters contaminated with organic pollutants by using 2,4-dichlorophenol(2,4-DCP) as a model pollutant. Plant materials containing high peroxidase activity were selected as catalysts for the removal of 2,4-DCP. Peroxidase activity, which plant materials were containing, was measured, and the greatest peroxidase activity was observed in shepherd's purse, followed by turnip, sweet potato, Chinese cabbage and white radish. The peroxidase activity in shepherd's purse was four times higher than that of horseradish purchased in U.S.A. Using shepherd' s purse and turnip, it was investigated the effect of various factors on the decontamination of 2,4-DCP through oxidative coupling. The removal of 2,4-DCP was extremely fast, and a maximal removal could be achieved within 3 min for shepherd' s purse and 15min for turnip. The pH range was from 3.0 to 8.0 and the amount of $H_2O_2$ added was 9mM when maximal removal was achieved(over 90%). No increasing removal of 2,4-DCP was observed due to increasing the amount of $H_2O_2$ added (over 9mM). The initial concentration affected the transformation of 2,4-DCP incubated with plant materials. When turnip was used as catalytic agent, it was observed decreasing transformation of 2,4-DCP due to increasing initial concentration.

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Responses in Hepatic Xenobiotic Metabolizing and Antioxidant Enzymes in Javelin Goby Acanthogobius hasta Collected at Shihwa Lake (시화호에서 채집한 풀망둑 Acanthogobius hasta의 간장 약물대사효소계 및 항산화계의 반응)

  • Lee, Ji-Seon;Jeong, Jee-Hyun;Han, Chang-Hee;Shim, Won-Joon;Jeon, Joong-Kyun
    • Korean Journal of Environmental Biology
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    • v.26 no.2
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    • pp.94-101
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    • 2008
  • The aim of this study was to assess the responses of mixed function oxygenase (MFO) and antioxidative systems of feral Javelin goby, Acanthogobius hasta, caught in two sites of different pollution level in Shihwa lake, which has been a highly polluted lake by organic pollutants from nearby industrial complexes and sites. Enzymes analyzed in phase I of MFO system are cytochrome P450 (CYP), NADPH-cytochrome P450 reductase (P450R), NADH-cytochrome b5 reductase (b5R), and ethoxyresorufin deethylase (EROD). Phase II enzyme of glutathione S-transferase (GST) in MFO system was also investigated. Moreover, oxidative-enzyme system including catalase (CAT), glutathione reductase (GR) and total-glutathione peroxidase (GPX) activities and glutathione concentration in both of oxidized (GSSG) and reduced form (GSH) were determined. P450R, b5R, and GST activities of fish are relatively high in the polluted area, whereas hepatic EROD activity levels of fish in polluted area were lower than those of unpolluted area. CYP concentrations are not different between areas. These results indicated that feral Acanthogobius hasta were adaptive to highly polluted environment and exposed to oxidative stress in Shihwa lake.

Development of Natural and Ecological Wastewater Treatment System for Decentralized Regions and Rural Communities (분산지역 및 농촌마을 하수처리를 위한 자연정화 고도처리 공법 개발)

  • Kim, Song-Bae;Kwon, Tae-Young;Han, Jung-Yoon;Yoon, Chun-Gyeong
    • Korean Journal of Ecology and Environment
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    • v.39 no.4 s.118
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    • pp.489-497
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    • 2006
  • The feasibility of the Natural and Ecological Wastewater treatment System (NEWS) was examined for rural wastewater treatment in Korea. The intermittent trickling biofilter with high hydrophilic filter media was used for pretreatment for suspended solids and organic pollutants. The subsequent constructed wetland with porous granule materials was used for promoting nutrient removal. The results show that the removal efficiencies of the system were high with respect to the water quality parameters except COD. Even if the effluent from the biofilter did not meet the guidelines for wastewater treatment plant effluent in Korea in terms of $BOD_5$ and TN, the final effluent of the system meets the guidelines us to good performance of the constructed wetland. The regression analysis between pollutant loading rate and removal rate indicated that the system could have stable removal for SS, $BOD_5$, TN, and TP in the given influent ranges. The analysis in the winter period indicated that the wetland covered with transparent polycarbonate glass had the statble performance during the winter period dus to increase of temperature inside the wetland without any heating system. With the stable performance, effective poilutant removal, low maintenance, and cost-effectiveness, the NEWS could be considered as an alternative treatment system for decentralized regions and rural communities in Korea.

Water Quality and Particle Size Distributions of Road Runoff in Storm Event (강우시 도로유출수 수질특성 및 입경분포)

  • Lee, Jun-Ho;Cho, Yong-Jin;Bang, Ki-Woong
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.777-784
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    • 2005
  • The first flush phenomenon is defined as the initial period of road runoff during which the concentration of pollutants was significantly high. Road runoff contains significant loads of micro-particles, heavy metals and organic constituents. There were two major objectives of this study. The first objective was to characterize the road runoff. The second objective was to measure and evaluate particle sire distribution of the road runoff, Stormwater runoff was monitored on two sites of four lane road areas along with traffic volume. A total six storm events were monitored to characterize the road runoff. The quantity of road runoff and quality constituents, including chemical oxygen demand ($COD_{Cr}$), suspended solids(SS), total Kjeldahl nitrogen (TKN), ortho-phosphorus ($PO_4-P$), total phosphorus(TP), heavy metals and particle size distribution were analyzed. The results indicate that the concentration of SS, $COD_{Cr}$, TKN and TP ranges were $45{\sim}2,396\;mg/L$, $40{\sim}931\;mg/L$, $0.1{\sim}19.6\;mg/L$, and $0.2{\sim}25.1\;mg/L$, respectively. The results of the regression analysis between SS and the others constituents shows that $COD_{Cr}$, TP, Cu, Pb were highly correlated. And the results showed that the mean range of particle size and uniformity coefficient for road runoff were $6.7{\sim}23.4{\mu}$ and $6.4{\sim}10.2$, respectively.