• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3727-3732
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• 2013

The interaction between metalloporphyrins and diazine tautomers was investigated using quantum chemistry method. The results showed that the metal atom in the metalloporphyrin was not coplanar with porphin ring, and zinc porphyrin has the most extent of its non-coplanar nature. The most stable complex in nine complexes was iron porphyrin. NBO analysis indicated that the interaction between the lone pair of electrons on the nitrogen atom and the unoccupied lone pair orbital of metal contributes significantly to the stability of the complexes. Through the conceptual DFT parameter and Fukui dual descriptor, the thermodynamic stability and reactivity of complexes were analyzed. The density difference function (DDF) analyzes were performed to explore the rearrangement of electronic density after the coordination interaction. NICS calculation indicated that metalloporphyrin aromaticity was reduced after the coordination interaction, and aromaticity of diazine tautomer was increased along direction vector of the coordination interaction force.

• 천문학회보
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• 제41권1호
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• pp.79.1-79.1
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• 2016

We investigated the dynamical properties of the K2-3 multi-planet system. Recently three transiting planets are discovered using the extended Kepler2 (K2) mission (Crossfield et al. 2015). We extended their preliminary stability study by considering a substantial longer integration time. Since planet mass is not known from photometry we calculated exoplanets masses using empirical mass-radius relations (Weiss & Marcy 2014). Forward numerical integration was done using the MERCURY integration package (Chambers 1999). Our results demonstrate that this system is stable over a time scale of $10^8years$. Furthermore, we investigated the dynamical effects of a hypothetical planet in the semi-major axis vs eccentricity space. For stable orbits of the hypothetical planet we calculated transit-timing variation (TTV) and radial velocity signals. We find that for a hypothetical perturber with mass 1-13 Mjup, semi-major axis 0.2 - 0.8 AU and eccentricity 0.00-0.47 the following timing signals for the planet K2-3 b is ~ 5 sec, K2-3 c is ~ 130 sec and for K2-3 d is ~ 190 sec. The radial velocity signal of the hypothetical planet is ~ 4 m/s. Using typical transit-timing errors from the K2 mission, we find that the above hypothetical planet would not be detectable. Its radial velocity signal, however, would be detectable using the APF 2.4m telescope or HARPS at the ESO/La Silla Observatory in Chile.

• 천문학회보
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• 제39권1호
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• pp.37.2-37.2
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• 2014

Gas in disk galaxies interacts nonlinearly with a underlying stellar spiral potential to form galactic spiral shocks. Numerical simulations typically show that these shocks are unstable to the wiggle instability, forming non-axisymmetric structures with high vorticity. While previous studies suggested that the wiggle instability may arise from the Kelvin-Helmholtz instability or orbit crowding of gas elements near the shock, its physical nature remains uncertain. It was even argued that the wiggle instability is of numerical origin, caused by the inability of a numerical code to resolve a shock that is inclined to numerical grids. In this work, we perform a normal-mode linear stability analysis of galactic spiral shocks as a boundary-value problem. We find that the wiggle instability originates physically from the potential vorticity generation at a distorted shock front. As the gas follows galaxy rotation, it periodically passes through multiple shocks, successively increasing its potential vorticity. This sets up a normal-mode that grows exponentially, with a growth rate comparable to the orbital angular frequency. We show that the results of our linear stability analysis are in good agreement with the those of local hydrodynamic simulations of the wiggle instability.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.201-204
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• 2002

The rates of the aminolysis of S-phenyl substituted-acetate series $(RC(=O)SC_6H_4Z$, with R=Me, Et, i-Pr, t-Bu and Bn) with benzylamines $(XC_6H_4CH_2NH_2)$ are not correlated simply with the Taft's polar $({\sigma}^{\ast})$ and/or steric effect constants $(E_s)$ of the substituents due to abnormally enhanced rate of the substrate with R=Et. Furthermore, the cross-interaction constant, ${\rho}x_z$ , is the largest with R=Et. These anomalous behaviors can only be explained by invoking the vicinal bond $({\sigma})$-antibond $({\sigma}^{\ast})$ charge transfer interaction between C-$C{\alpha}$ and C-S bonds. In the tetrahedral zwitterionic intermediate, $T^{\pm}$ , formed with R=Et the vicinal ${\sigma}_{c-c}-{\sigma}^{\ast}_{c-s}$ delocalization is the strongest with an optimum antiperiplanar arrangement and a narrow energy gap, ${\Delta}{\varepsilon}={\varepsilon}_{{\sigma}^{\ast}}-{\varepsilon}_{\sigma}$. Due to this charge transfer interaction, the stability of the intermediate increases (with the concomitant increase in the equilibrium constant K (= $k_a/k_{-a}$)) and also the leaving ability of the thiophenolate leaving group increases (and hence $k_b$ increases) so that the overall rate, $k_n\;=\;Kk_b$, is strongly enhanced. Theoretical support is provided by the natural bond orbital (NBO) analyses at the B3LYP/6-31+$G^{\ast}$ level. The anomaly exhibited by R=Et attests to the stepwise reaction mechanism in which the leaving group departure is rate limiting.

• Transactions on Electrical and Electronic Materials
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• 제15권6호
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• pp.328-332
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• 2014

Thin film transistors (TFTs) with an amorphous silicon zinc tin oxide (a-2SZTO) channel layer have been fabricated using an RF magnetron sputtering system. The effect of the change of excitation electron on the variation of the total interfacial trap states of a-2SZTO systems was investigated depending on sputtering power, since the interfacial state could be changed by changing sputtering power. It is well known that Si can effectively reduce the generation of the oxygen vacancies. However, The a-2SZTO systems of ZTO doped with 2 wt% Si could be degraded because the Si peripheral electron belonging to a p-orbital affects the amorphous zinc tin oxide (a-ZTO) TFTs of the s-orbital overlap structure. We fabricated amorphous 2 wt% Si-doped ZnSnO (a-2SZTO) TFTs using an RF magnetron sputtering system. The a-2SZTO TFTs show an improvement of the electrical property with increasing power. The a-2SZTO TFTs fabricated at a power of 30 W showed many of the total interfacial trap states. The a-2SZTO TFTs at a power of 30 W showed poor electrical property. However, at 50 W power, the total interfacial trap states showed improvement. In addition, the improved total interfacial states affected the thermal stress of a-2SZTO TFTs. Therefore, a-2SZTO TFTs fabricated at 50 W power showed a relatively small shift of threshold voltage. Similarly, the activation energy of a-2SZTO TFTs fabricated at 50 W power exhibits a relatively large falling rate (0.0475 eV/V) with a relatively high activation energy, which means that the a-2SZTO TFTs fabricated at 50 W power has a relatively lower trap density than other power cases. As a result, the electrical characteristics of a-2SZTO TFTs fabricated at a sputtering power of 50 W are enhanced. The TFTs fabricated by rf sputter should be carefully optimized to provide better stability for a-2SZTO in terms of the sputtering power, which is closely related to the interfacial trap states.

• 항공우주시스템공학회지
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• 제17권2호
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• pp.94-102
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• 2023

큐브위성용 태양전지판 분리장치는 열선 또는 저항소자의 발열로 나일론선을 절단하여 구조물의 구속을 해제하는 나일론선 절단방식 구속분리장치가 주로 적용되고 있다. 일반적으로 태양전지판 조립체의 발사하중을 고려한 구조해석을 수행하여 구속분리장치의 설계가 이루어지고 있으나, 발사 이후 궤도 열환경에 대한 구속분리장치의 열적 검토 및 분석사례는 전무한 실정이다. 따라서, 본 논문에서는 현재 개발중인 큐브위성 STEP Cube Lab-II에 적용되는 나일론선 절단 기반 구속분리장치의 열적 안정성 평가를 수행하고자 한다. 위성이 POD (Picosatellite Orbital Deployer)에서 사출되고 태양전지판이 전개되기까지의 분리장치 온도 분포를 검토하여 분리장치의 허용온도 범위 내에서 안정적인 구속 분리가 될 수 있도록 분리장치에 대한 궤도 열해석을 수행하였다. 또한, 열해석 결과를 기반으로 열진공시험을 수행하여 분리장치의 설계를 검증하였다.

• 천문학회지
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• 제56권2호
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• pp.195-199
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• 2023

This paper is written as a follow-up observations to reinterpret the radial velocity (RV) of HD 36384, where the existence of planetary systems is known to be ambiguous. In giants, it is, in general, difficult to distinguish the signals of planetary companions from those of stellar activities. Thus, known exoplanetary giant hosts are relatively rare. We, for many years, have obtained RV data in evolved stars using the high-resolution, fiber-fed Bohyunsan Observatory Echelle Spectrograph (BOES) at the Bohyunsan Optical Astronomy Observatory (BOAO). Here, we report the results of RV variations in the M giant HD 36384. We have found two significant periods of 586 d and 490 d. Considering the orbital stability, it is impossible to have two planets at so close orbits. To determine the nature of the RV variability variations, we analyze the HIPPARCOS photometric data, some indicators of stellar activities, and line profiles. A significant period of 580 d was revealed in the HIPPARCOS photometry. H_α EW variations also show a meaningful period of 582 d. Thus, the period of 586 d may be closely related to the rotational modulations and/or stellar pulsations. On the other hand, the other significant period of 490 d is interpreted as the result of the orbiting companion. Our orbital fit suggests that the companion was a planetary mass of 6.6 M_J and is located at 1.3 AU from the host.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제12권1호
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• pp.114-120
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• 1990

This is a case report of correction of posttraumatic diplopia and enophthalmos using autogenous composite conchal cartilage and temporal fascia. The results are as follows. 1. Diplopia and enophthalmos may be persistent complications in zygomatic complex fracture. 2. The concha is a reservior of autogenous cartilage which leaves no cosmetic and functional deformity in reconstruction of orbital floor. 3. Warpping the cartilage in temporal fascia may serve to increase implant stability and get graft with smooth edge. 4. Donor incision lines are well hidden within the scalp and in auriculocephalic fold.

• 대한화학회지
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• 제20권1호
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• pp.15-18
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• 1976

염화벤젠술페닐의 바람직한 형태를 EHMO법으로 구하였다. 이 형태의 안정도는 황원자와 벤젠고리 사이의 n-${\pi}$ 콘쥬게이션에 따른다는 것을 알았다. 또 염화벤젠술페닐의 가에탄올 분해반응을 연구하여 얻은 반응속도상수를 치환기 효과와 황원자의 d-궤도함수 기여로 논의하였다. 비선형 Hammett 그래프로 부터 쌍뿔형의 중간체를 제안할 수 있었다.

• Journal of Mechanical Science and Technology
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• 제17권12호
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• pp.1922-1927
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• 2003

Nonlinear normal mode (NNM) vibration, in a nonlinear dual mass Hamiltonian system, which has 6$\^$th/ order homogeneous polynomial as a nonlinear term, is studied in this paper. The existence, bifurcation, and the orbital stability of periodic motions are to be studied in the phase space. In order to find the analytic expression of the invariant curves in the Poincare Map, which is a mapping of a phase trajectory onto 2 dimensional surface in 4 dimensional phase space, Whittaker's Adelphic Integral, instead of the direct integration of the equations of motion or the Birkhoff-Gustavson (B-G) canonical transformation, is derived for small value of energy. It is revealed that the integral of motion by Adelphic Integral is essentially consistent with the one obtained from the B-G transformation method. The resulting expression of the invariant curves can be used for analyzing the behavior of NNM vibration in the Poincare Map.