• Journal of Photoscience
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• v.10 no.2
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• pp.203-208
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• 2003

Two coupled molecules were successfully synthesized by condensation of amine-donor-substituted barbituric acid derivativies as nonlinear optical chromophores. A flexible spacer of the alkyl chain with different lengths of carbon chains (5 and 6 carbons) was introduced between two chromophores, which prevented crystallization and aggregation of molecules. Two coupled molecules (B-Cn-B, n=5, 6) had glass-transition temperatures on a second heating around 81 and 76$^{\circ}C$ without melting points, respectively. To explore the linear optical properties, thin-films were prepared and examined by a photometry method using Nd:YVO$_4$ CW laser. Also, microscopic and macroscopic nonlinear optical properties were measured by Hyper-Rayleigh Scattering (HRS) and the Maker Fringes method using Nd:YAG ps pulse laser, respectively. In spite of the moderate hyperpolarizabilities of coupled molecules, the second order NLO coefficient (d$\_$33/) was larger than the conventional Disperse Red 1 doped PMMA polymeric system.

• Journal of the Optical Society of Korea
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• v.17 no.3
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• pp.255-261
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• 2013

Scene-based nonuniformity correction techniques for infrared focal-plane arrays have been widely considered as a key technology, and various algorithms have been proposed to compensate for fixed-pattern noise. However, the existed algorithms' capability is always restricted by the problems of convergence speed and ghosting artifacts. In this paper, an effective scene-based nonuniformity correction method is proposed to solve these problems. The algorithm is an improvement over the constant statistics method and a temporal median is utilized with the Gaussian kernel to estimate the nonuniformity parameters. Also theoretical analysis is conducted to demonstrate that effective ghosting artifacts elimination and superior convergence speed can be obtained with the proposed method. Finally, the performance of the proposed technique is tested with infrared image sequences with simulated nonuniformity and with infrared imagery with real nonuniformity. The results show the proposed method is able to estimate each detector's gain and to offset reliably and that it performs better in increasing convergence speed and reducing ghosting artifacts compared with the conventional techniques.

• Current Optics and Photonics
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• v.1 no.6
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• pp.598-603
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• 2017

Traditional three-dimensional (3-D) laser imaging systems are based on real aperture imaging technology, whose resolution decreases as the range increases. In this paper, we develop a novel 3-D imaging technique based on the synthetic aperture technology in which the imaging resolution is significantly improved and does not degrade with the increase of the range. We consider an imaging laser radar (ladar) system using the floodlight transmitting mode and multi-beam receiving mode. High 3-D imaging resolutions are achieved by matched filtering the linear frequency modulated (LFM) signals respectively in range, synthetic aperture along-track, and the real aperture across-track. In this paper, a novel 3-D imaging signal model is given first. Because of the motion during the transmission of a sweep, the Doppler shift induced by the continuous motion is taken into account. And then, a proper algorithm for the 3-D imaging geometry is given. Finally, simulation results validate the effectiveness of the proposed technique.

• Journal of Sensor Science and Technology
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• v.19 no.2
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• pp.160-167
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• 2010

In this paper, we fabricated the optoelectronic device based on Cadmium selenide(CdSe) nanocrystal quantum dots (NQDs)/single-walled carbon nanotubes(SWNTs) heterostructure using dieletrophoretic force. The efficient charge transfer phenomena from CdSe to SWNT make CdSe-Pyridine(py)-SWNT unique heterostructures for novel optoelectronic device. The conductivity of CdSe-py-SWNT was increased when it was exposed at ultra violet(UV) lamp, and varied as a function of wavelength of incident light.

• Journal of the Korean Ceramic Society
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• v.50 no.3
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• pp.173-179
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• 2013

Wurtzite nanomaterials, such as ZnO, GaN, and InN, have become a subject of great scientific and technological interest as they simultaneously have piezoelectric and semiconductor properties. In particular, the piezoelectric potential (piezopotential) created by dynamic straining in the nanowires drives a transient flow of current in the external load, converting mechanical energy into electricity. Further, the piezopotential can be used to control the carrier generation, transport, separation, and/or recombination at the metal-semiconductor junction or p-n junction, which is called the piezophototronic effect. This paper reviews the recent advances on the piezophototronic effect to better use the piezophototronic effect to control the carrier generation, transport, separation and/or recombination for improving the performance of optoelectronic devices, such as photon detectors, solar cells and LEDs. This paper also discusses several research and design studies that have improved the output performance of optoelectronic devices.

• Macromolecular Research
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• v.13 no.6
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• pp.521-528
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• 2005

Electrospun polyacrylonitrile (PAN) nanofibers were carbonized with or without iron (III) acetylacetonate to induce catalytic graphitization within the range of 900-1,500$^{circ}C$, resulting in ultrafine carbon fibers with a diameter of about 90-300 nm. Their structural properties and morphologies were investigated. The carbon nanofibers (CNF) prepared without a catalyst showed amorphous structures and very low surface areas of 22-31 $m^{2}$/g. The carbonization in the presence of the catalyst produced graphite nanofibers (GNF). The hydrogen storage capacities of these CNF and GNF materials were evaluated through the gravimetric method using magnetic suspension balance (MSB) at room temperature and 100 bar. The CNFs showed hydrogen storage capacities which increased in the range of 0.16-0.50 wt$\%$ with increasing carbonization temperature. The hydrogen storage capacities of the GNFs with low surface areas of 60-253 $m^{2}$/g were 0.14-1.01 wt$\%$. Micropore and mesopore, as calculated using the nitrogen gas adsorption-desorption isotherms, were not the effective pore for hydrogen storage.

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.4
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• pp.334-342
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• 2005

200-300 nm 직경을 지닌 폴리비닐리덴 플루오라이드 초극세 섬유를 전기방사법으로 제조하였다. 이들을 불응화시킨 후, $800-1800^{\circ}C$ 온도에서 탄화시켜 PVdF 계 탄소나노 섬유를 제조하여 구조 및 기공분석을 하였다. 이들은 20-30 nm 크기의 탄소입자로 이루어져 있으며 탄소나노입자는 1 nm이하의 슬릿형 나노기공을 지니고 있었다. 탄화온도가 증가함에 따라 비표면적은 $1500^{\circ}C$에서 $414\;m^2/g$로 감소하였으나, $1800^{\circ}C$에서는 $1300\;m^2/g$로 급격히 다시 증가하였으며 1 nm 이하의 나노기공만을 지닌 탄소섬유가 얻어졌다. 비표면적 및 기공특성과 수소저장특성을 관계를 조사하기 위하여 Magnetic Syspension Balance(MSB)를 사용한 중량법으로 평가한 이들의 수소저장능은 0.04-0.4wt%이었다.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.18 no.8
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• pp.2029-2036
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• 2014

The performance analysis of optoelectronic oscillator(OEO) based on a directly modulated semiconductor laser was theoretically achieved. First, the analysis was performed on the open response of the key components that constitute the OEO loop. Using the results, we simulated the open-loop characteristics of the OEO loop. By combining oscillation conditions of loop oscillator in addition to the open-loop magnitude and phase responses, theoretical performance analysis such as OEO's oscillation frequency, spurious tones and phase noise was successfully completed.

• Korean Journal of Materials Research
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• v.30 no.5
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• pp.217-222
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• 2020

The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo₂S₄ nanowire array on a Ni-foam substrate (NiCo₂S₄ NW/NF) via a two-step hydrothermal synthesis approach. This NiCo₂S₄ NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm^-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec^-1 and superior long-term stability for 20 h in 1 M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.

• Current Optics and Photonics
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• v.5 no.2
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• pp.164-172
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• 2021

In this paper a catadioptric laser-irradiation-precision test system is designed, to achieve a high-precision laser-irradiation-accuracy test. In this system, we adopt the method of imaging the entire target surface at a certain distance to realize the measurement of laser-irradiation precision. The method possesses the advantages of convenient operation, high sensitivity, and good stability. To meet the test accuracy requirement of 100 mm/km (0.01%), the coma, field curvature, and distortion over the entire field of view should be eliminated from the optical system's design. Taking into account the whole length of the tube and the influence of stray light on the structure type, a catadioptric system with a hood added near the primary imaging surface is designed. After optimization using the ZEMAX software, the modulation transfer function (MTF) of the designed optical system is 0.6 at 30 lp/mm, the full-field-of-view distortion is better than 0.18%, and the energy concentration in the 10-㎛-radius surrounding circle reaches about 90%. The illumination-accuracy test results show that the measurement accuracy of the radiation hit rate is better than 50 mm when the test distance is 1 km, which is better than the requirement of 100 mm/km for the laser-irradiation-accuracy test.