• 제목/요약/키워드: Optical absorption

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2011년 봄 황사시기 제주도 고산에서의 황사와 오염입자의 광흡수 기여도 산정 (Estimation of the Light Absorption Contribution for Asian Dust and Polluted Particles at Gosan, Jeju during the Asian Dust Episode in the Spring 2011)

  • 이시혜;김상우;윤순창
    • 한국대기환경학회지
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    • 제28권4호
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    • pp.411-422
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    • 2012
  • Ground-based in-situ measurements of aerosol optical properties at Gosan climate observatory have been analyzed to investigate the optical contribution of Asian dust and polluted particles on light absorption in springtime 2011. During the Asian dust episode, the contribution of Asian dust particle to aerosol absorption coefficient estimated about 45% at 370 nm and about 23% at 520 nm. Especially, black carbon in dust plume contributes about 48% to aerosol light absorption at 520 nm since the airmass are transported from the Gobi and inner Mongolia deserts, and this airmass comes across the northeastern coast of China, near the Shandong Peninsula. In pollution case, the contributions of dust particle and black carbon to aerosol absorption coefficient estimated about 41% and 11% at 370 nm, respectively. However, pollution case shows the highest light absorption of 48% for brown carbon at 370 nm, which indicates the significantly high mass concentration of organic carbon ($6.3{\pm}2.2{\mu}g\;m^{-3}$) in pollution plume can contribute to the increase of light absorption at near-UV spectral region.

Lock-in 증폭기를 채용한 주파수영역 확산 광단층촬영 시스템 (Frequency-domain Diffuse Optical Tomography System Adopting Lock-in Amplifier)

  • 전영식;백운식
    • 한국광학회지
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    • 제22권3호
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    • pp.134-140
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    • 2011
  • 본 논문에서는 생체 내부를 비침습적으로 영상화하기 위한 방법으로 생체내에서의 빛의 전파가 흡수보다는 산란이 지배적으로 작용하는 근적외선(NIR, near-infrared) 영역의 레이저 광원 및 광 검출기를 이용하여 주파수영역(frequency-domain) 확산 광 단층촬영(DOT, diffuse optical tomography) 시스템을 구현하였으며, 생체조직을 모사한 액체 팬텀에 광학적 특성이 다른 이형성분(anomaly)을 삽입하여 실험적으로 흡수 및 산란 분포에 대한 영상을 복원함으로써 이형성분의 위치와 형태에 대한 정보를 획득하였다.

도우핑된 비정질 실리콘의 온도에 따른 광학적 특성 (Temperature Effects on the Optical Properties of Doped Amorphous Silicon)

  • 박진석;한민구;이정한
    • 대한전자공학회논문지
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    • 제23권4호
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    • pp.506-514
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    • 1986
  • Experimental results are reported concerning temperture effects from room temperature to 100\ulcorner on the optical properties of N-and P-type hydrogenated amorphous silicon films prepared by RF glow discharege. Optical absorption coefficient and optical bandgap have been measured and analyzed as a function of temperature. Optical absorption coefficient increase monotonically with temperature, while the optical bandgape of doped amorphous silicons decrease linearly by about 4-7x10**-4 [ev/k].

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유기 색소 분자의 비선형 흡수 (Nonlinear Absorption in Dithienothiophene-based Chromophores)

  • Park, H.;Kim, H.;E. Kang;Lee, J.;Lee, K.;M. Cha
    • 한국광학회:학술대회논문집
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    • 한국광학회 2000년도 하계학술발표회
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    • pp.164-165
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    • 2000
  • There has recently been a considerable amount of interest in two-photon(TP) processes because of their applications to 3-D optical data storage and imaging, up-conversion lasing, and optical power limiting. Recently, the role of Dithienothlophene(DTT) as $\pi$-center of two-photon absorption(TPA) molecules was reported to give a large enhancement of TPA, compared with the benzeniods counterparts.$^{[1]}$ In this report, we carried out two experiments to investigate nonlinear optical absorption of the molecules in which central DTT is attached through conjugation to either a D/D or a D/A pair at the ends, forming a D-$\pi$-D(1 and 3) or D-$\pi$-A(2 and 4) sequence(Fig.1). All the samples were prepared in solutions with the same molar concentration. (omitted)

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Effect of annealing atmosphere on the properties of chemically deposited Ag2S thin films

  • Pawar, S.M.;Shin, S.W.;Lokhande, C.D.;Kim, J.H.
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 춘계학술발표대회
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    • pp.34.2-34.2
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    • 2009
  • The silver sulphide (Ag2S) thin films have been chemically deposited from an alkaline medium (pH 8 to 10) by using a silver nitrate and thiourea as a Ag and S ion precursor sources. Ethylene Damine tetraacetic acid (EDTA) was used as a complexing agent. The effect of annealing atmosphere such as Ar, N2+H2S and O2 on the structural, morphological and optical properties of Ag2S thin films has been studied. The annealed films were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical absorption techniques for the structural, morphological, and optical properties, respectively. XRD studies reveal that the as-deposited thin films are polycrystalline with monoclinic crystal structure, is converted in to silver oxide after air annealing. The surface morphology study shows that grains are uniformly distributed over the entire surface of the substrate. Optical absorption study shows the as-deposited Ag2S thin films with band gap energy of 0.92eV and after air annealing it is found to be 2.25 eV corresponding to silver oxide thin films.

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$Zn_4$$ GeSe_6$$Co^{2+}$를 첨가한 $Zn_4$$ GeSe_6$:$Co^{2+}$단결정의 광학적 특성 (Optical properties of undoped and $Co^{2+}$-doped $Zn_4$$ GeSe_6$ single crystals)

  • 김덕태
    • E2M - 전기 전자와 첨단 소재
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    • 제10권2호
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    • pp.105-112
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    • 1997
  • Undoped and Co$^{2+}$-doped Zn$_{4}$GeSe$_{6}$ single crystals were grown by the Chemical Transport Reaction method using iodine as a transporting agent. The crystal structure of these compounds determined by X-ray diffraction analysis was monoclinic structure. The direct energy gaps of these compounds were measured and the temperature dependence of the optical energy gap were closely investigated over the temperature range 10-290K. The temperature dependence of the optical energy gap is well presented by the Varshni equation. Also the optical absorption peaks of Zn$_{4}$GeSe$_{6}$ :Co$^{2+}$ single crystal observed, centered at 5437, 6079, 7142, 12950, 13462, 14786 and 15735 $cm^{-1}$ /, can be explained in terms of the electronic transitions of Co$^{2+}$ ions located at Td symmetry of the host materials. According to the crystal-field theory, the crystal-field, Racah and spin-orbit coupling parameters obtained from the absorption bands are given by Dq = 361$cm^{-1}$ /, B = 655$cm^{-1}$ / and .lambda. = 284$cm^{-1}$ / respectively.ively.

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Differential Optical Absorption Spectroscopy를 이용한 대기오염 측정 및 분석 (Air Pollution Measurement and Analysis using a Differential Optical Absorption Spectroscopy)

  • 김상우;원재광;박기학;윤순창;홍천상
    • 한국대기환경학회지
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    • 제17권5호
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    • pp.375-384
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    • 2001
  • Optical remote sensing techniques are particularly advantageous over the conventional fixed point methods because with these methods large-area monitoring can be possible and sample preparation difficulties are avoidable. Instruments based on the differential optical absorption spectroscopy (DOAS) technique are widely used for monitoring air pollutants in urban areas in recent years. In this study, $O_3$, SO$_2$, NO$_2$, and VOCs (benzene, toluene, xylene, and styrene) are measured continuously at Sihwa industrial area using a DOAS from February to November. 1999. Intercomparison between the DOAS method and the conventional methods (filed point samplers for $O_3$, NO$_2$, and SO$_2$, and adsorbent sampling methods and gas chromatography for VOCs) are performed simultaneously at the same site. The time series of the DOAS data and that of fixed point method show good match at the view point of the tendency, but the absolute concentration values of these two methods differ quite a lot from each other; correlation coefficients shows 0.78 for $O_3$and 0.97 for SO$_2$. However, the results of VOCs measurements are not quite satisfactory ; the spectral interference with $O_2$and $O_3$appears to be the major cause of the errors for VOCs .

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혼합 매로시아닌 LB막의 광흡수 스펙트라 (Optical Absorption Spectra of Mixed Merocyanine Dye LB films)

  • 신훈규;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.35-42
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    • 1996
  • In this Paper, optical absorption were performed on LB films of binary mixtures of three kinds of merocranine dyes DO, DS, and 6Me-BS, where DS and 6Me-DS form J-like aggregates but not DO in single component films. The observed optical absorption spectra of mixed films were markedly defendent on the combination of dyes. [6Me-DS]$\sub$1-x/[DOl]$\sub$x/ LB films show a sharp red shifted J-like band peak in the whole concentration range. We found the formation of f aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye DO, in a single component case. Farther investigations on the present and other mixed-dye films will be needed to clarify these points.

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OPTICAL PROPERTIES OF INDIUM OXIDE AND INDIUM TIN OXIDE FILMS PREP ARED BY SPUTTERING

  • Fujita, Yasuhiko;Kitakizaki, Kaoru
    • 한국표면공학회지
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    • 제29권6호
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    • pp.660-665
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    • 1996
  • Thin films of indium oxide and indium tin oxide have been prepared by d.c. magnetron sputtering onto the fused silica substrates kept at 90, 200 and $300^{\circ}C$. In order to elucidate the optical absorption process in low energy region below 3 eV, we have analyzed the absorption coefficients obtained from reflectance and transmittance measurements for these films based on the Lucovsky model. It has been found for the first time that a defect center in the band gap is located at 0.8~1.4 eV below the Fermi level in all films and arises from oxygen vacancies in their films. The optical absorption in low energy region is explained to be dominated by the transition of electrons trapped at the positively charged (+2e) oxygen vacancies with s-like nature to the conduction band formed from the 5s-orbit in indium atoms.

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광 흡수 Sepectra 에 의한 메로시아닌 LB막의 구조제어 (Structure Control of Merocyanine LB Films by Optical Absorption Spectra)

  • 신훈규;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.401-404
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    • 1996
  • Optical absorption were performed on LB films of binary mixtures of three kinds of merocyanine dyes [DO], [DS], and [6Me-DS], where [DS] and [6Me-DS] from J-like aggregates but not [DO] in single component films. The observed optical absorption spectra of mixed films were markedly dependent on the combination of dyes. [DS]$_{1-x}$ [DO]$_{x}$ LB films show a sharp red shift J-like band peak in the while concentration range. We found the formation of J-aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye [DO], in a single component case. Further investigations on the present and other mixed dye films will be needed to clarify these points.ts.

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