• Macromolecular Research
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• v.13 no.4
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• pp.314-320
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• 2005

Crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at various crosslinking temperatures using poly(acrylic acid-co-maleic acid) (PAM) containing different PAM contents. The thermal properties of these PVA/PAM membranes prepared at various reaction temperatures were characterized using differential scanning calorimetry (DSC). The proton conductivity and methanol permeability of PVA/PAM membranes were then investigated as PAM content was varied from 3 to 13 wt%. It was found that the proton and methanol transport were dependent on PAM content in their function both as crosslinking agent and as donor of hydrophilic -COOH groups. Both these properties decreased monotonously with increasing PAM concentration. The proton conductivities of these PVA/PAM membranes were in the range from $10^{-3}\;to\;10^{-2}S/cm$ and the methanol permeabilities from $10^{-7}\;to\;10^{-6}cm^{2}/sec$. In addition, the effect of operating temperature up to $80^{\circ}C$ on ion conductivity was examined for three selected membranes: 7, 9 and 11 wt% PAM membranes. Ion conductivity increased with increasing operating temperature and showed and S/cm at $80^{\circ}C$, respectively. The effects of crosslinking and ionomer group concentration were also examined in terms of water content, ion exchange capacity (IEC), and fixed ion concentration. In addition, the number of water molecules per ionomer site was calculated using both water contents and IEC values. With overall consideration for all the properties measured in this study, $7{\sim}9\;wt%$ PAM membrane prepared at $140^{\circ}C$ exhibited the best performance. These characteristics of PVA/PAM membranes are desirable in applications related to the direct methanol fuel cell (DMFC).

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.420-424
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• 2019

In SNG (synthetic natural gas) process by proposed RIST(Research Institute of Industrial Science & Technology)-IAE(Institute for Advanced Engineering) (including three adiabatic reactors and one isothermal reactor), the methanation reaction and water gas shift (WGS) reaction take place simultaneously, and the supply of steam with syngas might control the temperature in catalyst bed and deactivate the catalyst. In this study for development of SNG process, the characteristics of the methanation reaction with a Ni-based catalyst by prepared RIST and using a low $H_2/CO$ mole ratio (including $CO_2$ 22%) are evaluated. The operating conditions ($H_2O/CO$ ratio of the $1^{st}$ adiabatic reactor, operating temperature range of $4^{th}$ isothermal reactor, etc.) were reflected the results from previous studies and in the same condition a pilot scale SNG process is carried out. As a results, the pilot scale SNG process is stable and the CO conversion and $CH_4$ selectivity are 100% and 96.9%, respectively, while the maximum $CH_4$ productivity is $660ml/g_{cat}{\cdot}h$.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.22 no.3
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• pp.8-16
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• 1986

The fishing conditions of flying squid, ommastrePhes barsram(Lesueur), in the North Pacific Ocean was studied based on the horizontal water temperature data, satellite data from NOAA and statistical data of flying squid fisheries which were collected from 1980 to 1984. The obtained results were as follows; 1. Since 1979, the Korean drift giIlnet fishery for flying squid was launched in North Pacific. Number of operating vessel and catch of flying squid increased gradually every year. The number of vessels were 111 and their annual catches were 42, 977 M/T in 1984. Therefore, Korean drift giIlnet fishery for this species has played an important role in the products of Korean high-sea fisheries. 2. In the beginning of the fisheries, fishing grounds was formed in the west of long. 1800E. In 1982, in consequence of the center which extended eastward, the fishing ground was formed long. 166$^{\circ}$W in the central North Pacific Ocean. Since 1983, the fishing grounds were formed as far as long. 161$^{\circ}$W. The range of general fishing season in the central North Pacific was from June to August. After september, fishing ground was shifted to the west, in the Northwestern Pacific. 3. The Predominant fishing season for the flying squid was August through January of the coming year. Optimum water temperature for flying sguid at surface layer in the Pacific Ocean ranged from 11 $^{\circ}$e to 17$^{\circ}$e in winter, 13$^{\circ}$e to 17$^{\circ}$e in spring, 12. 8$^{\circ}$C to 19.7$^{\circ}$e in summer and 1O.6$^{\circ}$e -18.7$^{\circ}$e in fall. 4. In summer, the Oceanographic condition in the North Pacific Ocean showed that the water temperature at surface layer was lower in 1980, 1983 and higher in 1981, 1982 and 1984 as compared with mean annual water temperature. 5. The characteristics df oceanographic conditions in the fluation, disformation, mixing and other factors of the Kuroshio and Oyashio currents, which have considerably influenced upon the water masses of the areas. 6. The data and information on surface thermal Structure interpreted from Infrared Satellite Imaginary from NOAA-7 and NOAA-8 are very available in estimating water temperature on the areas and investigating the major fishing grounds. 7. According to the fisheries statics of Japanese drift gilInet, the annual catches of flying squid considerably decreased from 225, 942 M/T in 1983 to 133, 217 M/T in 1984. 8. The fishing grounds in the central North Pacific in several fishing seasons were formed as follows: In June, the initial fishing season, the fishing grounds were formed in the vicinity of lat. 35 - 40oN, the central North Pacific east of 179$^{\circ}$E. In July, the fishing ground were formed in the wide arEa of the central North Pacific north of 400N and long. 174$^{\circ}$E-145$^{\circ}$W In Auguest, concentrative fishing operation carried out in :he central North Pacific north of 43$^{\circ}$N and East of 165$^{\circ}$W. On the other hand, in September, main fishing grounds were disappeared and moved to the west.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.12
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• pp.1367-1373
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• 2011

This research concerns the development of a compression/absorption high-temperature hybrid heat pump that uses a natural refrigerant mixture. Heat pumps based on the compression/absorption cycle offer various advantages over conventional heat pumps based on the vapor compression cycle, such as large temperature glide, temperature lift, flexible operating range, and capacity control. In this study, a lab-scale prototype hybrid heat pump was constructed with a two-stage compressor, absorber, desorber, desuperheater, solution heat exchanger, solution pump, liquid/vapor separator, and rectifier as the main components. The hybrid heat pump system operated at 10-kW-class heating capacity producing hot water whose temperature was more than $90^{\circ}C$ when the heat source and sink temperatures were $50^{\circ}C$. Experiments with various $NH_3/H_2O$ mass fractions and compressor/pump circulation ratios were performed on the system. From the study, the system performance was optimized at a specific $NH_3$ concentration.

• Journal of the Korean earth science society
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• v.22 no.3
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• pp.186-194
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• 2001

The operational meso-scale short range NWP system was developed for Cheju Regional Meteorological Office located at Cheju island, Korea. The Central Meteorological Service Center, KMA has reported the information on numerical weather prediction every 12 hours. But this information is not enough to determine the detail forecast for the regional meteorological office because the terrain of the Korean peninsula is very complex and the resolution of the numerical model provided by KMA headquarter is too coarse to resolve the local severe weather system such as heavy rainfall. LAPS and MM5 models were chosen for three-dimentional data assimilation and numerical weather prediction tools respectively. LAPS was designed to provide the initial data to all regional numerical prediction models including MM5. Synoptic observational data from GTS, satellite brightness temperature data from GMS-5 and the composite reflectivity data from 5 radar sites were used in the LAPS data assimilation for producing the initial data. MM5 was performed on PC-cluster based on 16 pentium CPUs which was one of the cheapest distributed parallel computer in these days. We named this system as Halla Short Range Prediction System (HSRPS). HSRPS was verified by heavy rainfall case in July 9, 1999, it showed that HSRPS well resolved local severe weather which was not simulated by 30 km MM5/KMA. Especially, the structure of rainfall amount was very close to the corresponding observation. HSRPS will be operating every 6 hours in the Cheju Regional Meteorological Office from April 2000.

• Journal of agriculture & life science
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• v.46 no.2
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• pp.179-190
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• 2012

This study was performed to obtain a heat saving effect and enhance the efficiency of a greenhouse by using a hot water piping in order to minimize the operating costs of a greenhouse as oil prices continue to rise. This method also reduces the likelihood of accidents caused by snowdrifts in regions with heavy snowfall. In general, the experimental plot was $2.0{\sim}6.0^{\circ}C$ higher than the control plot. When the skylight felt was opened, the minimum temperature was in the range of $3.0{\sim}12.0^{\circ}C$. Therefore, we judged that damage caused by snowdrifts may be prevented partly by active heating. The temperature difference inside of the greenhouse by height was insignificant. The maximum heating load of the greenhouse according to crop was respectively about $37,000kcal{\cdot}h^{-1}$ and $41,700kcal{\cdot}h^{-1}$. During the experiment, the heat value of each designed temperature in the range of the minimum ambient temperature $-11.9{\sim}4.0^{\circ}C$ was about 95,000~322,000 kcal and it was in the range of $6,050{\sim}20,900kcal{\cdot}h^{-1}$. If it is compared with the maximum heating load, it can be shown that about 15~56% of the heating energy can be supplied. The total heat value and the amount of power consumption were 2,629,025 kcal and 677.3 kWh respectively during the experiment. If it is heated with diesel, a fossil fuel, the consumption during the experiment was 291 L and the cost was 331,700won. Total cost of using electric power was about 24,400 won and it is shown that it is about 7.5% of the cost of diesel consumption. Also, if the total amount of power consumption is converted into energy, it is approximately 582,200 kcal and the energy was just about 22% of the total heat value.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.855-861
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• 2013

Small-pore Cu-chabazite SCR catalysts with high NOx conversion at low temperatures are of interest for marine diesel engines with exhaust temperatures in the range of 150 to $300^{\circ}C$. Unfortunately, fuels for marine diesel engines can contain a high level of sulfur of up to 1.5% by volume, which corresponds to a $SO_2$ level of 500 ppm in the exhaust gases for an engine operating with an A/F ratio of 50:1. This high level of $SO_2$ in the exhaust may have detrimental effects on the NOx performance of the Cu-chabazite SCR catalysts. In the present study, a bench-flow reactor is used to investigate the effects of sulfur poisoning on the NOx performance of Cu-chabazite SCR catalysts. The SCR catalysts were exposed to simulated diesel exhaust gas stream consisted of 500 ppm $SO_2$, 5% $CO_2$, 14% $O_2$, 5% $H_2O$ with $N_2$ as the balance gas at 150, 200, 250 and $300^{\circ}C$ for 2 hours at a GHSV of 30,000 $h^{-1}$. After sulfur poisoning the low-temperature NOx performance of the SCR catalyst is evaluated over a temperature range of 150-$300^{\circ}C$ to determine the extent of the catalyst deactivation. Desulfation is also carried out at 600 and $700^{\circ}C$ for 30 minutes to determine whether it is possible to recover the NOx performance of the sulfur-poisoned SCR Catalysts.

• Journal of the Korean Society of Propulsion Engineers
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• v.2 no.3
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• pp.99-106
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• 1998

The performance of the turbofan engine, a medium scale civil aircraft which has been developing in Rep. of Korea, was analyzed and the control scheme for optimization the performance was studied. The dynamic and real-time linear simulation was performed in the previous study The result was that the fuel scedule of the step increase overshoot the limit temperature(3105 $^{\cire}R$) of the high pressure turbine and got small surge margine of the high pressure compressor. Therefore a control scheme such as the LQR(Linear Quadratic Regulator) was applied to optimizing the performance in this studies. The linear model was expected for designing controller and the real time linear model was developed to be closed to nonlinear simulation results. The system matrices were derived from sampling operating points in the scheduled range and then the least square method was applied to the interpolation between these sampling points, where each element of matrices was a function of the rotor speed. The control variables were the fuel flow and the low pressure compressor bleed air. The controlled linear model eliminated the inlet temperature overshoot of the high pressure turbine and obtained maximum surge margins within 0.55. The SFC was stabilized in the range of 0.355 to 0.43.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.461-468
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• 2019

Demand for improving dust removal efficiency in coal power plants and the dust removal requirement to the level of capturing fine particulate matter and ultrafine particles have been increasing. While bag filter and electrostatic precipitator (ESP) are typically used for dust removal in the processes operating at atmospheric pressure, metal filters or ceramic filters are employed for dust which is produced at high temperature/pressure system as in coal gasification. For dust removal at the high temperature/pressure conditions, two metal filters of five compressed/sintered layers were manufactured and applied to analyze the dust removal characteristics. Manufactured metal filters exhibited more than 99% dust removal efficiency on coal gasification fine particulates in mass basis. To evaluate the fine particulate removal efficiency of less than $2.5{\mu}m$, JIS standard fine sample was used and confirmed the removal efficiencies of 97% and 70~82% on the fine particulates of $1{\sim}2.5{\mu}m$ size range. For the size range of less than $1{\mu}m$, dust removal efficiency of manufactured metal filters significantly degraded with smaller particle size. Improving methods are proposed to overcome the limitations in applying to fine dust of less than $1{\mu}m$.

• Journal of IKEEE
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• v.23 no.4
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• pp.1461-1464
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• 2019

In this paper, we propose the development of embedded board for integrated radiation exposure protection fireman's life-saving alarm capable of location tracking and radiation measurement. The proposed techniques consist of signal processing unit, communication unit, power unit, main control unit. Signal processing units apply shielding design, noise reduction technology and electromagnetic wave subtraction technology. The communication unit is designed to communicate using the wifi method. In the main control unit, power consumption is reduced to a minimum, and a high performance system is formed through small, high density and low heat generation. The proposed techniques are equipment operated by exposure to poor conditions, such as disaster and fire sites, so they are designed and manufactured for external appearance considering waterproof and thermal endurance. The proposed techniques were tested by an authorized testing agency to determine the effectiveness of embedded board. The waterproof grade has achieved the IP67 rating, which can maintain stable performance even when flooded with water at the disaster site due to the nature of the fireman's equipment. The operating temperature was measured in the range of -10℃ to 50℃ to cope with a wide range of environmental changes at the disaster site. The battery life was measured to be available 144 hours after a single charge to cope with emergency disasters such as a collapse accident. The maximum communication distance, including the PCB, was measured to operate at 54.2 meters, a range wider than the existing 50 meters, at a straight line with the command-and-control vehicle in the event of a disaster. Therefore, the effectiveness of embedded board for embedded board for integrated radiation exposure protection fireman's life-saving alarm has been demonstrated.