• Title/Summary/Keyword: Open pore

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The Effect of PVA-Al(III) Complex on Pore Formation and Grain Growth of $UO_2$ Sintered Pellet (II) (PVA-A(III) 착물이 $Uo_2$ 소결체의 기공형성과 결정립성장에 미치는 영향(II))

  • 이신영;김형수;노재성
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.782-790
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    • 1999
  • The compressibility sinterability sintering behaviour and thermal stability of AlOOH added UO2 pellt and PVA-Al(III) complex added UO2 pellet were investigated respectively. Compared with characteristics of AlOOH added UO2 pellet the green density and the sintered density of PVA-Al(III) complex added UO2 pellet were lowered but the grain size and the pore size of that were more increased in accordance with higher compacting pressure. The AlOOH added UO2 pellet had the grain size of about 14${\mu}{\textrm}{m}$ with monomodal pore size distribution while the PVA-Al(III) complex added UO2 pellet had the grain size of about 42 ${\mu}{\textrm}{m}$ with bimodal pore size distribution. The PVA-A(III) complex added UO2 pellet had a similiar open porosity to the AlOOH added UO2 pellet and a lower resintered density change than the AlOOH added UO2 pellet.

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The Effect of Fe and Fe2O3 Powder Mixing Ratios on the Pore Properties of Fe Foam Fabricated by a Slurry Coating Process (슬러리 코팅 공정으로 제조된 Fe 폼의 기공 특성에 미치는 Fe 및 Fe2O3 분말의 혼합 비율의 영향)

  • Choi, Jin Ho;Jeong, Eun-Mi;Park, Dahee;Yang, Sangsun;Hahn, Yoo-Dong;Yun, Jung-Yeul
    • Journal of Powder Materials
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    • v.21 no.4
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    • pp.266-270
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    • 2014
  • Metal foams have a cellular structure consisting of a solid metal containing a large volume fraction of pores. In particular, open, penetrating pores are necessary for industrial applications such as in high temperature filters and as a support for catalysts. In this study, Fe foam with above 90% porosity and 2 millimeter pore size was successfully fabricated by a slurry coating process and the pore properties were characterized. The Fe and $Fe_2O_3$ powder mixing ratios were controlled to produce Fe foams with different pore size and porosity. First, the slurry was prepared by uniform mixing with powders, distilled water and polyvinyl alcohol(PVA). After slurry coating on the polyurethane(PU) foam, the sample was dried at $80^{\circ}C$. The PVA and PU foams were then removed by heating at $700^{\circ}C$ for 3 hours. The debinded samples were subsequently sintered at $1250^{\circ}C$ with a holding time of 3 hours under hydrogen atmosphere. The three dimensional geometries of the obtained Fe foams with an open cell structure were investigated using X-ray micro CT(computed tomography) as well as the pore morphology, size and phase. The coated amount of slurry on the PU foam were increased with $Fe_2O_3$ mixing powder ratio but the shrinkage and porosity of Fe foams were decreased with $Fe_2O_3$ mixing powder ratio.

The Performance Characteristics of the Open Celled Aluminum Foam Applied for Heat Dissipation (다공성 알루미늄 방열핀의 성능특성 연구)

  • Kim, Jong-Soo;Lee, Hyo-Jin
    • Journal of the Korean Solar Energy Society
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    • v.23 no.2
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    • pp.91-98
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    • 2003
  • Experimental study for a porous aluminum heat dissipator/or heat sink made by casting method is conducted to evaluate the performance of the porous aluminum heat sinks. The parameters applied for the present study are the manufacturing method. various bonding materials for the bottom plate of heat sink, and their different material, pore size, etc.. The casting method for porous aluminum heat sink is suggested for the best performance of heat dissipation in this experiment. The bottom plate applied by melting aluminum is introduced and proved their excellent characteristics compared with brazing, soldering, and bonding methods. In the present experiment, aluminum with different conductivities, such as AC8A and pure aluminum, are tested and the pure aluminums with the higher conductivity than AC8A shows their improvement of the performance. And the proper dimensions related to the pore size and the height of porous aluminum heat sinks are proposed in the present study.

Preparation of a Porous Chitosan/Fibroin-Hydroxyapatite Composite Matrix for Tissue Engineering

  • Kim, Hong-Sung;Kim, Jong-Tae;Jung, Young-Jin;Ryu, Su-Chak;Son, Hong-Joo;Kim, Yong-Gyun
    • Macromolecular Research
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    • v.15 no.1
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    • pp.65-73
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    • 2007
  • Chitosan, fibroin, and hydroxyapatite are natural biopolymers and bioceramics that are biocompatible, biodegradable, and resorb able for biomedical applications. The highly porous, chitosan-based, bioceramic hybrid composite, chitosanlfibroin-hydroxyapatite composite, was prepared by a novel method using thermally induced phase separation. The composite had a porosity of more than 94% and exhibited two continuous and different morphologies: an irregularly isotropic pore structure on the surface and a regularly anisotropic multilayered structure in the interior. In addition, the composite was composed of an interconnected open pore structure with a pore size below a few hundred microns. The chemical composition, pore morphology, microstructure, fluid absorptivity, protein permeability, and mechanical strength were investigated according to the composition rate of bioceramics to biopolymers for use in tissue engineering. The incorporation of hydroxyapatite improved the fluid absorptivity, protein permeability, and tenacity of the composite while maintaining high porosity and a suitable microstructure.

The Effect of MgO Content on the Preparation of Porous Hydroxyapaite Scaffolds by Polymer Sponge Method (폴리머 스펀지법을 이용한 다공성 수산화아파타이트 지지체 제조 시 MgO 첨가량에 따른 영향)

  • Jin, Hyeong-Ho;Min, Sang-Ho;Lee, Won-Ki;Park, Hong-Chae;Yoon, Seog-Young
    • Korean Journal of Materials Research
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    • v.16 no.11
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    • pp.715-718
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    • 2006
  • Porous hydroxyapatite (HAp) scaffolds have been prepared by using the slurry including HAp and magnesia based on the replication of polymer sponge substrate. The influence of MgO content in slurry on the pore morphology and size, density, porosity, and mechanical strength of porous HAp scaffolds was investigated. The obtained scaffolds with average pore sizes ranging 150 to 300 mm had open, relatively uniform, and interconnected porous structure regardless of MgO content. As the MgO content increased, the pore network frame of scaffolds became to be relatively stronger, even though the pore size was not much changed. The compressive strength of the scaffolds increased rapidly with the increase of MgO content because of increasing the pore wall thickness and density of the scaffolds. As a result, the porosity, density, and compressive strength of the porous HAp scaffolds prepared by the sponge method were significantly affected by the addition of MgO.

Study on the Enhanced Specific Surface Area of Mesoporous Titania by Annealing Time Control: Gas Sensing Property (열처리 시간에 따른 메조기공 타이타니아의 비표면적 향상 연구: 가스센싱 특성 변화)

  • Hong, M.-H.;Park, Ch.-S.;Park, H.-H.
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.2
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    • pp.21-26
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    • 2015
  • Mesoporous ceramic materials were applied in various fields such as adsorbent and gas sensor because of low thermal conductivity and high specific surface area properties. This structure could be divided into open-pore structure and closed-pore structure. Although closed-pore structure mesoporous ceramic materials have higher mechanical property than open-pore structure, it has a restriction on the application because the increase of specific surface area is limited. So, in this work, specific surface area of closed-pore structure $TiO_2$ was increased by anneal time. As increased annealing time, crystallization and grain growth of $TiO_2$ skeleton structured material in mesoporous structure induced a collapse and agglomeration of pores. Through this pore structural change, pore connectivity and specific surface area could be enhanced. After anneal for 24 hrs, porosity was decreased from 36.3% to 34.1%, but specific surface area was increased from $48m^2/g$ to $156m^2/g$. CO gas sensitivity was also increased by about 7.4 times due to an increase of specific surface area.

A study of loading property of the bioactive materials in porous Ti implants (다공성 티타늄 임플란트의 생리활성물질 담지특성에 관한 연구)

  • Kim, Yung-Hoon
    • Journal of Technologic Dentistry
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    • v.35 no.4
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    • pp.281-286
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    • 2013
  • Purpose: Surface modification is important techniques in modern dental and orthopedic implants. This study was performed to try embedding of bioactive materials in porous Ti implants. Methods: Porous Ti implant samples were fabricated by sintering of spherical Ti powders in a high vacuum furnace. It's diameter and height were 4mm and 20mm. Embedding process was used to suction and vacuum chamber. Loading properties of porous Ti implants were evaluated by scanning electron microscope(SEM), confocal laser scanning microscope(CLSM), and UV-Vis-NIR spectrophotometer. Results: Internal pore structure was formed fully open pore. Average pore size and porosity were $10.253{\mu}m$ and 17.506%. Conclusion: Porous Ti implant was fabricated successfully by sintering method. Particles are necking strongly each other and others portions were vacancy. This porous structure can be embedded to bioactive materials. Therefore bioactive materials will be able to embedding to porous Ti implants. Bioactive materials embedding in the porous Ti implant will induced new bone faster.

Micro-porous Nickel Produced by Powder Metallurgy

  • Yamada, Y.;Li, Y.C.;Banno, T.;Xie, Z.K.;Wen, C.E.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.602-603
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    • 2006
  • Micro-porous nickel (Ni) with an open cell structure was fabricated by powder metallurgy. The pore size of the micro-porous Ni approximated $30{\mu}m$ and $150{\mu}m$. For comparison, porous Ni with a macro-porous structure were also prepared by both powder metallurgy (pore size $800{\mu}m$) and the traditional chemical vapour deposition method (pore size $1300{\mu}m$). The mechanical properties of the micro-and macro-porous Ni samples were evaluated using compressive tests. Results indicate that the micro-porous Ni samples exhibited significantly enhanced mechanical properties, compared to those of the macro-porous Ni samples.

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STUDIES OF CELL COMMUNICATION BY USING GAP JUNCTION CHANNELS RECONSTITUTE IN UNILAMELLAR LIPID VESICLES

  • Joe, Cheol-O
    • Proceedings of the Korean Biophysical Society Conference
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    • 1996.07a
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    • pp.6-6
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    • 1996
  • Gap junction channels were reconstituted into unilamellar liposomes using immunoaffinity purified connexin 32 gap junction protein from rat liver. Vesicles containing open channels and close channels were separated by means of iso-osmolar sucros density gradient sedimentation. The open channels formed in lipid vesicles were permeable to a fluorescent dye molecule, lucifer yellow of which the hydrodynamic size is similar to pore size of gap junctions in vivo. (omitted)

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Investigation on the Pore Properties of the Microcellular ZrO2 Ceramics Using Hollow Microsphere (중공형 미세구를 이용한 마이크로셀룰라 지르코니아의 가공 특성 고찰)

  • Lee, Eun-Jung;Song, In-Hyuek;Kim, Hai-Doo;Kim, Young-Wook;Bae, Ji-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.108-115
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    • 2009
  • In this study, a novel-processing route for producing microcellular zirconia ceramics has been developed. The proposed strategy for making the microcellular zirconia ceramics involves hollow microsphere as a pore former which has extremely low density of $0.025\;g/cm^3$. Effects of hollow microsphere content and sintering temperature on microstructure, porosity, pore distribution, and compressive strength were investigated in the processing of microcellular zirconia ceramics. By controlling the content of hollow microsphere, it was possible to make the porous zirconia ceramics with porosities ranging from 45% to 75%. Typical compressive strength value of microcellular zirconia ceramics with ${\sim}65%$ porosity was over 50 MPa. By adjusting the mixing ratio of large and small zirconia powders, it was possible to control the pore structure from close to open pores.