• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
• /
• pp.390-393
• /
• 2008

To improve the blue responses of screen-printed single crystalline silicon solar cells, we investigated an emitter etch-back technique to obtain high emitter sheet resistances, where the defective dead layer on the emitter surface was etched and became thinner as the etch-back time increased, resulting in the monotonous increase of short circuit current and open circuit voltage. We found that an optimal etch-back time should be determined to achieve the maximal performance enhancement because of fill factor decrease due to a series resistance increment mainly affected by contact and lateral resistance in this case. To elucidate the reason for the fill factor decrease, we studied the resistance analysis by potential mapping to determine the contact and the lateral series resistance. As a result, we found that the fill factor decrease was attributed to the relatively fast increase of contact resistance due to the dead layer thinning down with the lowest contact resistivity when the emitter was contacted with screen-printed silver electrode.

• 한국수소및신에너지학회논문집
• /
• 제24권5호
• /
• pp.421-427
• /
• 2013

We report on the time dependent degradation of cell in dye-sensitized solar cells (DSSC). The photovoltaic performance of DSSC over a period of time was investigated in liquid electrolyte based on triiodide/iodide during six days. It was found that the short circuit current density ($j_{sc}$) of the cell dropped from 9.9 to $7mA/cm^2$ while efficiency (${\eta}$) of the cell decreased from 4.4 to 3.3%. The parameters corresponding to fundamental electronic and ionic processes in a working DSSC are determined from the electrochemical impedance spectrascopy (EIS) at open-circuit potential ($V_{oc}$). EIS study of the DSSC in the this work showed that the electron life time ${\tau}_r$ and chemical capacitance $C_{\mu}$ decreased significantly after six days. It was correlated the $j_{sc}$ and efficiency decreased after six days.

• 한국전기전자재료학회논문지
• /
• 제34권2호
• /
• pp.90-98
• /
• 2021

Piezoelectric ceramic fiber composite (PCFC) was fabricated using a planar electrode printed piezoelectric ceramic fiber driven in transverse mode for small-scale wind energy harvester applications. The PCFC consisted of an epoxy matrix material and piezoelectric ceramic fibers sandwiched by interdigitated electrode (IDE) patterned polyimide films. The PCFC showed an excellent mechanical performance under a continuous stress. For the fabrication of PCB cantilever harvester, five -PCFCs were vertically attached onto a flexible printed circuit board (PCB) substrate, and then PCFCs were serially connected through a printed Cu circuit. The energy harvesting performance was evaluated applying an inverted structure, which imples its free leading edge located at an open end but the trailing edge at a clamped end, to enhance strain energy in a wind tunnel. The output voltage of the PCB cantilever harvester was increased as the wind speed increased. The maximum output power was 17.2 ㎼ at a resistance load of 200 ㏀ and wind speed of 9 m/s. It is considered that the PCB cantilever energy harvester reveals a potential use for wind energy harvester applications.

• 한국구조물진단유지관리공학회 논문집
• /
• 제25권4호
• /
• pp.28-36
• /
• 2021

콘크리트 구조물의 내부의 매립된 철근은 부동태 피막으로 인해 부식으로부터 보호된다고 알려져 있다. 구조물의 경제적인 내구수명 산정을 위해 부식 발생 시기를 지연시키거나 초기 부식 시점을 평가하는 것은 매우 중요하다. 본 연구에서는 3 가지 수준의 피복두께(60 mm, 45 mm, 30 mm), 물-시멘트 비(40.0%, 50.0%, 60.0%), 염화물 농도(0.0%, 3.5%, 7.0%)를 고려한 콘크리트 시편을 대상으로 부식 모니터링을 수행하였는데, 한천(Agar) 기반 소켓 형식 센서를 활용하여 OCP를 측정하였다. OCP 측정 시 습윤 조건에서는 전위가 감소하고 건조 조건에서는 감소된 전위가 일부 회복하는 거동을 확인하였다. 모든 물-시멘트 비에서 피복두께가 30 mm의 경우 가장 낮은 OCP값이 측정되었으며, 피복두께가 30 mm에서 45 mm로 증가할 때 빠르게 OCP가 회복하였다. 이는 피복두께가 염화물 이온의 침투에 효과적인 방어기구로 작용하기 때문이다. 염화물 농도가 증가함에 따라 물-시멘트 비의 영향보다 피복두께에 대한 영향이 더 지배적인 경향을 보이는 것으로 도출되었다. 시편의 해체 후 추가적인 모니터링과 염화물량의 평가를 수행하면 제안된 부식 모니터링 기법의 신뢰성을 높일 수 있을 것으로 판단된다.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 추계학술대회 논문집
• /
• pp.394-394
• /
• 2009

Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the polymer light-emitting diode and new materials for nano and micro hollow-capsules, and bio- or chemo-sensors. We synthesized neutral polyfluorenes containing bromo-alkyl groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl side groups in neutral polyfluorenes were quaternized by tri-methyl amine solution. The electrochemical and optical properties of water-soluble conjugated polymers are discussed. This novel synthesized water-soluble conjugated polymers were used as a interfacial dipole layer between active layer and metal cathode in polymer solar cell for enhancement of open-circuit voltage (Voc), which is one of the most critical factors in determining device characteristics. We also investigated the device performance of polymer solar cell with different metal cathode such as Al, Ag, Au and Cu. In polymer solar cell, novel cationic water-soluble conjugated polymers were inserted between active layer and high-work function cathode (Al, Ag, Au and Cu).

• 전력전자학회논문지
• /
• 제14권4호
• /
• pp.333-342
• /
• 2009

중성점 클램핑 방식(Neutral Point Clamped) 인버터로 알려져 있는 3레벨 NPC 인버터는 그 구조적 특성상 직류-링크(DC-link) 중성점(Neutral Point)에서 전압이 변동한다. 지금까지 많은 논문에서 이 문제에 대한 연구가 진행되었고 다양한 형태의 해결책들이 제시되었다. 그러나 인버터 내부에서 고장이 발생하여 그에 따른 고장허용제어가 NPC 인버터 시스템에 적용되었을 경우 중성점 전압변동은 정상 운전 시 나타나는 전압변동과 다르게 나타나기 때문에 고장허용 제어에 따른 중성점 전압변동에 대한 분석이 필요하다. 본 논문에서는 삼각파 비교 변조방법을 시스템에 적용하였을 경우 정상운전과 고장 발생 과 고장허용 제어 적용 시 직류-링크 중성점 전압 변동이 어떤 양상으로 나타나는지 분석하고 고장허용 제어에 의한 NPC 인버터의 고장검출 시간과 커패시터의 용량 사이의 관계를 고찰하였다. 시뮬레이션과 실험 결과를 이용하여 이론적 분석의 타당성을 검증하였다.

• Restorative Dentistry and Endodontics
• /
• 제46권1호
• /
• pp.6.1-6.10
• /
• 2021

Objectives: The aim of this study was to evaluate the corrosion resistance of heat-treated (Reciproc and WaveOne) and non-heat-treated (ProTaper and Mtwo) superelastic nickel-titanium endodontic files when immersed in a 5.25% sodium hypochlorite solution. Materials and Methods: Anodic polarization curves were obtained with potential sweeps that began at the open circuit potential or corrosion potential (E_corr). The pitting potential (E_pit) was identified on the anodic polarization curve as the potential at which a sudden increase in current was observed. The micromorphology of the 28 tested files was analyzed before and after the electrochemical assay using scanning electron microscope (SEM). The data were analyzed using 1-way analysis of variance with the post hoc Bonferroni test (for E_corr) and the Student t-test for independent samples (for E_pit). Results: The mean E_corr values were 0.506 V for ProTaper, 0.348 V for Mtwo, 0.542 V for Reciproc, and 0.321 V for WaveOne files. Only WaveOne and Protaper files exhibited pitting corrosion, with E_pit values of 0.879 V and 0.904 V, respectively. On the SEM images of the ProTaper and WaveOne files, cavities suggestive of pitting corrosion were detected. Conclusions: Signs of corrosion were observed in both heat-treated and non-heat-treated files. Of the evaluated files, WaveOne (a heat-treated file) and ProTaper (a non-heat-treated file) exhibited the lowest corrosion resistance.

• Journal of Electrochemical Science and Technology
• /
• 제3권4호
• /
• pp.185-189
• /
• 2012

A.c. impedances of mechanically polished CP-Ti specimens were measured at open-circuit potential (OCP) with immersion time and under applied anodic potentials between -0.2 and 1 $V_{Ag/AgCl}$ in 0.1 M NaOH solution. Capacitances of native oxide films ($C_{ox,na}$) grown naturally and capacitances of anodic oxide films ($C_{ox,an}$) formed under applied anodic potentials were obtained to examine the growth of native and anodic oxide films in 0.1 M NaOH solution and how to use $C_{ox,na}$ for the surface area measurement of Ti specimen. $1/C_{ox,na}$ and $1/C_{ox,an}$ appeared to be linearly proportional to OCP and applied potential ($E_{app}$), with proportional constants of 0.086 and 0.051 $uF^{-1}\;V^{-1}$, respectively. The $C_{ox,na}$ also appeared to be linearly proportional to geometric surface area of the mechanically polished CP-Ti fixture specimen, with proportional constants of 11.3 and $8.5{\mu}F\;cm^{-2}$ at -0.45 $V_{Ag/AgCl}$ and -0.25 $V_{Ag/AgCl}$ of OCPs, respectively, in 0.1 M NaOH solution. This linear relationship between $C_{ox,na}$ and surface area is suggested to be applicable for the measurement of real surface area of Ti specimen.

• 유체기계공업학회:학술대회논문집
• /
• 유체기계공업학회 2000년도 유체기계 연구개발 발표회 논문집
• /
• pp.373-378
• /
• 2000

The crevice corrosion of local corrosion occur when the gap exist on metal surface. This crevice corrosion happen to region such as flange of pipe, contact part of casing, under gasket and packing, between valve disk and seat of pump etc. Especially The crevice corrosion of mild steel(SS 400) get serious. This paper was studied on the crevice corrosion of SS 400 in fluid environment. In $0\%,\;2\%,\;3.5\%,\;5\% NaCl$ solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by $3.5\%$ but the concentration increased over $3.5\%$, the current density was low drained. 3) The weight loss rate of SS 400 was increased as concentration of NaCl solution Increased by $3.5\%$, but the concentration increased over $3.5\%$, that of SS 400 was decreased. 4) Effect of oxygen for crevice corrosion in the concentration of $3.5\%$ NaCl solution become sensitive than that $0\%$ NaCl solution.

• 유체기계공업학회:학술대회논문집
• /
• 유체기계공업학회 2000년도 유체기계 연구개발 발표회 논문집
• /
• pp.359-365
• /
• 2000

Port facilities and marine structures used in marine environment were encountered to corrosion damages because of the influence of $Cl^-$. Generally, to protect these accidents, mainly applied anti-corrosion paint and epoxy coating. But it was still remained erosion-corrosion damage such as impingement erosion, cavitation erosion, deposit attack. There was needs to develope the new coating materials to protective those corrosion damages. This paper, polyester glass flake, vinylester glass flake lining and epoxy coating for SS were investigated electrochemical tests and cavitation erosion test for corrosion behaviour under sea water. The main results obtained are as follows, 1) Surface of epoxy coating appear erosion pin hole but surface of polyester glass flake and vinylester glass flake lining do not appear erosion pin hole after impingement-cavitation erosion test in sea water. 2) Weight loss of polyester glass flake and vinylester glass flake lining do not occur after impingement-cavitation erosion test in sea water. 3) Corrosion current density of polyester glass flake lining less drained than epoxy coating and substrate under corrosion potential.. 4) Corrosion current density of vinylester glass flake lining with three coating less drained than that of polyester glass flake lining with two coating.