• Title/Summary/Keyword: Open circuit

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A Study of Ceria on Low-temperature Sintering Using Sintering Aids for Solid Oxide Fuel Cells (소결 조제를 이용한 고체산화물 연료전지용 세리아 전해질의 저온소결 특성 연구)

  • Oh, Chang Hoon;Song, Kwang Ho;Han, Jonghee;Yoon, Sung Pil
    • Journal of Hydrogen and New Energy
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    • v.25 no.3
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    • pp.280-288
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    • 2014
  • SDC (Samarium doped Ceria) electrolyte was developed for Intermediate temperature SOFC ($500^{\circ}C-800^{\circ}C$) which showed a good electrical conductivity. In this study, we used sintering aids to reduce the SDC sintering temperature down to $1000^{\circ}C$, especially which can help the SOFC scale-up. In order to reduce the SDC sintering temperature, $Li_2CO_3$ and $TiO_2$ were used as a sinering aids for decreasing sintering temperature. $Li_2CO_3$ and $TiO_2$ doped SDC sintered at $1000^{\circ}C$ showed 99% of the theoretical density and higher electrical conductivity than the pure SDC sintered at $1500^{\circ}C$. When measuring the OCV (Open circuit voltage) with the $Li_2CO_3$ and $TiO_2$ doped SDC electrolyte, however, the OCV values were lower than the theoretical OCV values which means that the modified SDC still had electronic conductivity.

Fabrication and Electrochemical Characterization of LSM/GDC based Cathode Supported Direct Carbon Fuel Cells (직접탄소 연료전지용 LSM/GDC 공기극 지지체 제조 및 전기화학 특성 평가)

  • Ahmed, Bilal;Wahyudi, Wandi;Lee, Seung-Bok;Song, Rak-Hyun;Lee, Jong-Won;Lim, Tak-Hyoung;Park, Seok-Joo
    • Journal of Hydrogen and New Energy
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    • v.24 no.3
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    • pp.230-236
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    • 2013
  • In this study, successive coating and co-sintering techniques have been used to fabricate LSM/GDC based cathode supported direct carbon fuel cells. The porous LSM/GDC cathode substrate, dense, thin and crack free GDC and ScSZ layers as bi-layer electrolyte, and a porous Ni/ScSZ anode layer was obtained by co-firing at $1400^{\circ}C$. The porous structure of LSM/GDC cathode substrate, after sintering at $1400^{\circ}C$, was obtained due to the presence of GDC phase, which inhibits sintering of LSM because of its higher sintering temperature. The electrochemical characterization of assembled cell was carried out with air as an oxidant and carbon particles in molten carbonate as fuel. The measured open circuit voltages (OCVs) were obtained to be more than 0.99 V, independent of testing temperature. The peak power densities were 116, 195 and $225mWcm^{-2}$ at 750, 800 and $850^{\circ}C$, respectively.

Visualization of Water Distribution in Cathode Side of a Direct Methanol Fuel Cell Using Neutron Radiography (중성자 라디오그래피 방법을 이용한 직접 메탄올 연료전지 공기극의 내부 물 분포 가시화)

  • Je, Jun-Ho;Doh, Sung-Woo;Kim, Tae-Joo;Kim, Jong-Rok;Xie, Xiaofeng;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.10
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    • pp.965-970
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    • 2012
  • In this study, the water distribution in the cathode side of a direct methanol fuel cell (DMFC) is visualized using a neutron imaging technique at the Neutron Radiography Facility (NRF), KAERI. It is difficult to quantify the water content in the cathode side because of $CO_2$ gas. A compared open circuit voltage (OCV) image, relative $CO_2$, and water distribution can be visualized by the neutron imaging technique. This means that the neutron imaging technique is useful for the optimization of the flow field design and the establishment of water management, and, in turn, for the improvement of the cell performance.

Fabrication of Solid Electrolyte Oxygen Sensors Using $CaF_{2}$ and their Characteristics ($CaF_{2}$를 이용한 고체전해질 산소센서의 제조및 그 특성)

  • Lee, Jae-Hyun;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.3 no.2
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    • pp.40-49
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    • 1994
  • Potentiometric cell oxygen sensors using $CaF_{2}$ were fabricated for monitering the oxygen partial pressure in the low temperature range ($300^{\circ}C{\sim}$500^{\circ}C). The disk type oxygen sensors consist of a reference electrode: Air($O_{2}:21%$)|Pt, a solid electrolyte $CaF_{2}$, and a sensing metel Pt electrode. And the change in open circuit emf of the disk type cell was about 45mV for the oxygen concentration range, $0.1%{\sim}10%$, at the cell temperature of $400^{\circ}C$. Also, the reference electrode incorporated type sensor showed the change of 40mV for 0.1% to 10% oxygen partial pressure range.

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AN ELECTROCHEMICAL STUDY ON SURFACE FINISH OF DENTAL AMALGAM (아말감의 표면연마에 관한 전기화학적 연구)

  • Suk, Chang-In;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.16 no.2
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    • pp.18-32
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    • 1991
  • The purpose of this study was to observe characteristic properties of amalgam through the polarization curves and SEM images from 4 type amalgams (Amalcap, Shofu spherical. Dispersalloy and Tytin) with 3 different surface finish procedures (polishing, burnishing and carving) by using the potentiostats (EG & GPARC) and SEM (Jeol JSM-35). After each amalgam alloy and Hg was triturated as the direction of the manufacturer by means of mechanical amalgamator (Samki), the triturated mass was inserted into the cylndrical metal mold which was 12 mm in diameter and 10 mm in height and was pressed with $100kg/cm^2$. 4 specimens of each type amalgam were burnished with egg burnisher and another 4 specimens of each type amalgam were carved with Hollenback carver. Above 8 specimens and remaining untreated 4 specimens were stored at room temperature for about 7 days. Untreated 4 specimens of each type amalgam were polished with abrasive papers (Deer) from #400 to #1200 and finally on the polishing cloth with $0.5{\mu}m$ and $0.06{\mu}m$ $Al_2O_3 $ powder suspended water. Anodic polarization measurements was employed to compare the corrosion behaviours of the amalgams in 0.9% saline solution at $37^{\circ}C$. The open circuit potential was determined after 30 minutes immersion of specimen in electrolyte. The scan rate was 1 mV/sec and the surface area of amalgam exposed to the solution was $0.64cm^2$ for each specimen. All the potentials reported are with respect to a saturated calomel electrode (SCE). SEM images of each specimen were taken after + 800 mV (SCE) polarization. The results were as follows: 1. The corrosion potential of high copper amalgam was more anodic than that of low copper amalgam. 2. The polished amalgam were more resistant to corrosion than any other burnished and carved amalgam. 3. In the case of polishing, current density of high copper amalgam was lower than that of low copper amalgam.

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Effect of Xylanase Supplementation on the Net Energy for Production, Performance and Gut Microflora of Broilers Fed Corn/Soy-based Diet

  • Nian, F.;Guo, Y.M.;Ru, Y.J.;Peron, A.;Li, F.D.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.9
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    • pp.1282-1287
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    • 2011
  • The objective of this study was to assess the effect of xylanase on net energy for production, performance, nutrient digestion and gut microflora of broilers fed corn/soy-based diet. Eighty-four day-old male broiler chicks were allocated to two groups receiving two treatments, respectively. Each treatment had six replicate cages with seven broilers per cage. The diets were based on corn and soybean. The treatments were: i) basal diet reduced in apparent metabolizable energy (-0.63 MJ/kg compared to commercial diet specifications); ii) basal diet supplemented xylanase at 4,000 u/kg feed. The experiment used the auto-control, open circuit respiration calorimetry apparatus to examine the heat production and net energy for production. The results revealed that xylanase supplementation did not affect growth performance and diet AME value, but increased $NE_p$ value by 18.2% (p<0.05) and decreased daily heat production per $kg^{0.75}$ by 31.7% (p<0.05). There was no effect (p>0.05) of xylanase supplementation on the ileal digestibility of N and hemicelluloses, but the ileum digestibility of energy was increased by 2% by xylanase supplementation (p<0.05). Xylanase supplementation increased (p<0.05) the count of lactobacillus and bifidobacterial in the caecum.

Physical activity level, total daily energy expenditure, and estimated energy expenditure in normal weight and overweight or obese children and adolescents (소아청소년의 비만여부에 따른 신체활동수준, 1일 총에너지소비량 및 에너지필요추정량의 평가)

  • Kim, Myung Hee;Kim, Eun Kyung
    • Journal of Nutrition and Health
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    • v.45 no.6
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    • pp.511-521
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    • 2012
  • The purposes of this study were to assess the physical activity level (PAL) and the total daily energy expenditure (TEE) as well as to evaluate the validity of prediction equation for the estimated energy requirement (EER) in normal weight and overweight or obese children and adolescents. The subjects comprised of 100 healthy Korean students aged between 7-18. The anthropometric data was collected. PAL was calculated from the physical activity diary by the 24-hour recall method, and the resting metabolic rate (RMR) was measured by an open-circuit indirect calorimetry using a ventilated hood system. Daily energy expenditure was PAL multiplied by RMR. EER was calculated by using the prediction equation published in KDRIs. There was no significant difference in the means of age and height between the 46 obese subjects and 54 nonobese subjects. The weight and BMI of the obese group (60.2 kg, $25.3kg/m^2$) were significantly higher than those of the nonobese group (42.4 kg, $18.4kg/m^2$). However, PAL was not significantly different between the two groups (nonobese 1.45, obese 1.46). TEE of the obese group (2,212 kcal/day) was significantly higher than that of the nonobese group (1,774 kcal/day). EER (individual PA) and EER (light PA) were significantly higher than TEE (p < 0,001); however, EER (sedentary PA) was not significantly different with TEE in the two groups. These results showed that the levels of physical activity were the same as the sedentary activity both in the nonobese and obese Korean students; moreover, the predictive equation for EER published in KDRI overestimated the TEE of Korean children and adolescents. Therefore, in further research, a new predictive equation for EER should be developed for Korean children and adolescents through the doubly labeled water method.

A study on the capacitance-voltage characteristics of the CdZnS/CdTe heterojunction (CdZnS/CdTe 이종접합의 커패시턴스-전압 특성에 관한 연구)

  • Lee, Jae-Hyeong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.6
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    • pp.1349-1354
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    • 2011
  • In this work, we fabricated the CdZnS/CdTe heterojunction and investigated the C-V characteristics to determine the depletion width and the charge density distribution. A parallel experiment on CdS/CdTe heterojunction was also carried out for comparison. The depletion region width, for CdZnS/CdTe heterojunction, was nearly constant, regardless of bias voltage. However, the depletion region was wider than that of CdS/CdTe heterojunction due to high resistivity of CdZnS film. The interface charge density of CdZnS/CdTe heterojunction was increased linearly with the bias voltage and showed lower values than those for CdS/CdTe junction. The open circuit voltage of CdZnS/CdTe heterojunction solar cells increased with zinc mole ratio due to reducing of the electron affinity difference between CdZnS and CdTe films. However, the increase of series resistance due to the high resistivity of Cd1-xZnxS films results in reducing conversion efficiency.

A study on the electrical characteristics of CdZnS/CdTe heterojunction (CdZnS/CdTe 이종접합의 전기적 특성에 관한 연구)

  • Lee, Jae-Hyeong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.7
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    • pp.1647-1652
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    • 2010
  • A CdS film has been used as a window layer in CdTe and Cu(In,Ga)$Se_2$ thin films solar cell. Partial substitution of Zn for Cd increases the photocurrent and the open-circuit voltage by providing a match in the electron affinities of the two materials and the higher band gap. In this paper, CdZnS/CdTe and CdS/CdTe heterojunctions were fabricated and the electrical characteristics were investigated. Current-voltage-temperature measurements showed that the current transport for CdS/CdTe heterojunction was controlled by both tunneling and interface recombination. However, CdZnS/CdTe heterojunction displayed different current transport mechanism with the operating temperature. For above room temperature, the current transport of device was generation/recombination in the depletion region and was the leakage current and/or tunneling in the range below room temperature.

A Study on a Low Power Underwater Communication Modem for Implementation of Underwater Sensor Networks (수중 센서 네트워크를 위한 저전력 수중 통신 모뎀 연구)

  • Choi, Yong-Woo;Hwang, Jun Hyeok;Park, Dong Chan;Kim, Suk Chan
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.3
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    • pp.268-273
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    • 2015
  • Recently many countries are researching actively underwater sensor networks for securing ocean resources and changes of ocean environment in all over the world. Current the commercial modem are not suitable because it has characteristics of long distance, higher price, larger power consumption with the special object mainly. In this paper, a low power and compact underwater communication modem which is suitable for underwater sensor networks is implemented. It is comprised by using a simple analog circuit for non-coherent BFSK modulation method, ultra low power MCU and orthogonal codes with a less operation and a simple implementation. It was experimented an underwater communication using our modem in a water tank and open sea farms. It communicates fewer than $10^{-4}$ bit error rate.