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Development and Performance Test of a l00hp HTS Motor

  • Sohn, M.H.;Baik, S.K.;Lee, E.Y.;Kwon, Y.K.;Yun, M.S.;Moon, T.S.;Park, H.J.;Kim, Y.C.;Ryu, K.S.
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.4
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    • pp.27-31
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    • 2004
  • This paper describes the development and fabrication of a high temperature superconducting motor which consists of HTS rotor and air-core stator. The machine was designed for the rated power of 100hp at 1800 rpm. The HTS field windings are composed of the double-pancake coils wound with AMSC's SUS-reinforced Bi-2223 tape conductor. These were assembled on the support structure and fixed by a bandage of glass-fiber composite. The cooling system is based on the heat transfer mechanism of the thermosyphon by using GM cryocooler as cooling source. The cold head is in contact with the condenser of a Ne-filled thermosyphon. The rotor assembly was tested independently at the stationary state and combined with stator. Characteristic parameters such as reactances, inductances, and time constants were determined to obtain a consistent overview of the machine operation properties. This motor has met all design parameters by demonstrating HTS field winding, cryogenic refrigeration systems and an air-core armature winding cooled with air. The HTS field winding could be cooled down below 30K. No-load test of open-circuit characteristics(OCC) and short-circuit characteristics(SCC) and load test with resistive load bank were conducted in generator mode. Maximum operating current of field winding at 30K was 120A. From OCC and SCC test results synchronous inductance and synchronous reactance were 2.4mH, 0.49pu, respectively. Efficiency of this HTS machine was 93.3% in full load(100hp) test. This paper will present design, construction, and basic experimental test results of the 100hp HTS machine.

High Transparent, High Mobility MoO3 Intergraded InZnO Films for Use as a Transparent Anode in Organic Solar cells

  • Kim, Hyo-Jung;Kang, Sin-Bi;Na, Seok-In;Kim, Han-Ki
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.343-343
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    • 2014
  • We reported on the electrical, optical, structural and morphological properties fabricated by co-sputtering for use as an anode for organic solar cells (OSCs). By adjusting RF and DC power of $MoO_3$ and IZO targets during co-sputtering, we fabricated the $MoO_3$-IZO electrode with graded content of the $MoO_3$ on the IZO films. At optimized $MoO_3$ thickness of 20 nm, the $MoO_3$ graded IZO electrode showed a higher mobility ($33cm^2/V-Sec$) than directly deposited $MoO_3$ on IZO film ($26cm^2/V-Sec$). At visible range (400nm~800nm), optical transmittance of the $MoO_3$ graded IZO electrode is higher than that of directly deposited $MoO_3$ on IZO film. High mobility of $MoO_3$ graded on IZO is attributed to less interface scattering between $MoO_3$ and IZO. To investigate the feasibility of $MoO_3$ graded IZO films, we fabricated conventional P3HT:PCBM based OSCs with $MoO_3$ graded IZO as a function of MoO3 thickness. The OSC fabricated on the $MoO_3$ graded IZO anode showed a fill factor of 66.53%, a short circuit current of $8.121mA/cm^2$, an open circuit voltage of 0.592 V, and a power conversion efficiency of 3.2% comparable to OSC fabricated on ITO anode and higher than directly deposited $MoO_3$ on IZO film. We suggested possible mechanism to explain the high performance of OSCs with a $MoO_3$ graded IZO.

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Characteristics of ITO/Ag-Pd-Cu/ITO Multilayer Electrodes for High Efficiency Organic Solar Cells

  • Kim, Hyo-Jung;Kang, Sin-Bi;Na, Seok-In;Kim, Han-Ki
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.257.1-257.1
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    • 2014
  • We investigated characteristics of ITO/Ag-Pd-Cu (APC)/ITO multilayer electrodes prepared by direct current magnetron sputtering for use as an anode in organic solar cells (OSCs). To optimize electrical properties of ITO/APC/ITO multilayer, we fabricated the ITO/APC/ITO multilayer at a fixed ITO thickness of 30 nm as a function of APC thickness. Compare to the surface of Ag layer on ITO, the APC had a smooth surface morphology. At optimized APC thickness of 12 nm, the ITO/APC/ITO multilayer exhibited a sheet resistance of $6{\Omega}/square$ and optical transmittance of 84.15% at a wavelength of 550 nm which is comparable to conventional ITO/Ag/ITO multilayer. However, the APC-based ITO multilayer showed a higher average transmittance in a visible region than the Ag-based ITO multilayer. The higher average transmittance of ITO/APC/ITO multilayer indicated the multilayer is suitable anode for organic solar cells with P3HT:PCBM active layer. OSCs fabricated on the optimized ITO/ACP/ITO multilayer exhibited a better performance with a fill factor of 64.815%, a short circuit current of $8.107mA/cm^2$, an open circuit voltage of 0.59 V, and power conversion efficiency (3.101%) than OSC with ITO/Ag/ITO multilayer (2.8%).

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Electrical, Optical and Structural Properties of ZrO2 and In2O3 Co-sputtered Electrdoes for Organic Photovoltaics (OPVs)

  • Cho, Da-Young;Shin, Yong-Hee;Chung, Kwun-Bum;Na, Seok-In;Kim, Han-Ki
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.473.1-473.1
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    • 2014
  • We report on the characteristics of Zr-doped $In_2O_3$ (IZrO) films prepared by DC-RF magnetron cosputtering of $In_2O_3$ and $ZrO_2$ targets for use as a transparent electrode for high efficient organic solar cells (OSCs). The effect of $ZrO_2$ doping power on electrical, optical, structural, and surface morphology of the IZrO film was investigated in detail. At optimized $ZrO_2$ RF power of 50 W, the IZrO film exhibited a low sheet resistance of 20.71 Ohm/square, and a high optical transmittance of 83.9 %. Furthermore, the OSC with the IZrO anode showed a good cell-performance: fill factor of 61.71 %, short circuit current (Jsc) of $8.484mA/cm^2$, open circuit voltage (Voc) of 0.593 V, and power conversion efficiency (PCE) of 3.106 %. In particular, the overall OSC characteristics of the cell with the IZrO anode were comparable to those of the OSC with the conventional Sn-doped $In_2O_3$ (FF of 65.03 %, Jsc of $8.833mA/cm^2$, Voc of 0.608 V, PCE of 3.495 %), demonstrating that the IZrO anode is a promising alternative to ITO anode in OSCs.

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Dual-Band Negative Group Delay Circuit Using λ/4 Composite Right/Left-Handed Short Stubs

  • Choi, Heung-Jae;Mun, Tae-Su;Jeong, Yong-Chae;Lim, Jong-Sik;Eom, Soon-Young;Jung, Young-Bae
    • Journal of electromagnetic engineering and science
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    • v.11 no.2
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    • pp.76-82
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    • 2011
  • In this paper, a novel design for a dual-band negative group delay circuit (NGDC) is proposed. Composite right/left-handed (CRLH) ${\lambda}/4$ short stubs are employed as a dual-band resonator. A CRLH ${\lambda}/4$ short stub is composed of a typical transmission line element as the right-handed component and a high-pass lumped element section as the left-handed component. It is possible to simultaneously obtain open impedances at two separate frequencies by the combination of distinctive phase responses of the right/left-handed components. Negative group delay (NGD) can be obtained at two frequencies by using dual-band characteristics of the CRLH stub. In order to achieve a bandwidth extension, the proposed structure consists of a two-stage dual-band NGDC with different center frequencies connected in a cascade. According to the experiment performed, with wide-band code division multiple access (WCDMA) and worldwide interoperability for microwave access (WiMAX), NGDs of $-3.0{\pm}0.4$ ns and $-3.1{\pm}0.5$ ns are obtained at 2.12~2.16 GHz and 3.46~3.54 GHz, respectively.

Effect of Annealing Process Pressure Over Atmospheric Pressure on Cu2ZnSn(S,Se)4 Thin Film Growth (대기압 이상의 열처리 공정압력이 Cu2ZnSn(S,Se)4(CZTSSe) 박막 성장에 미치는 영향)

  • Lee, Byeong Hoon;Yoo, Hyesun;Jang, Jun Sung;Lee, InJae;Kim, Jihun;Jo, Eunae;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.29 no.9
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    • pp.553-558
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    • 2019
  • $Cu_2ZnSn(S,Se)_4(CZTSSe)$ thin film solar cells areone of the most promising candidates for photovoltaic devices due to their earth-abundant composition, high absorption coefficient and appropriate band gap. The sputtering process is the main challenge to achieving high efficiency of CZTSSe solar cells for industrialization. In this study, we fabricated CZTSSe absorbers on Mo coated soda lime glass using different pressures during the annealing process. As an environmental strategy, the annealing process is performed with S and Se powder, without any toxic $H_2Se$ and/or $H_2S$ gases. Because CZTSSe thin films have a very narrow stable phase region, it is important to control the condition of the annealing process to achieve high efficiency of the solar cell. To identify the effect of process pressure during the sulfo-selenization, we experiment with varying initial pressure from 600 Torr to 800 Torr. We fabricate a CZTSSe thin film solar cell with 8.24 % efficiency, with 435 mV for open circuit voltage($V_{OC}$) and $36.98mA/cm^2$ for short circuit current density($J_{SC}$), under a highest process pressure of 800 Torr.

Study on The Electrical Characteristic Extraction of PI(Poly Imide) Substrate using T-resonator Method (T-resonator를 이용한 PI(Poly Imide) 기판의 전기적 특성 추출에 관한 연구)

  • Lee, Gwang-Hoon;Yoo, Chan-Sei;Lee, Woo-Sung;Yang, Ho-Min;Jung, Han-Ju;Kim, Hong-Sam;Lee, Bong-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.222-222
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    • 2007
  • RF circuit을 구현하는데 있어서 기판의 전기적 특성을 정확하게 아는 것은 원하는 결과를 추출하기 위해 매우 중요하다. 본 연구에서는 현재 사용되고 있는 PI 기판의 전기적인 특성인 유효 유전율과 loss tangent 값을 T-resonator률 이용해 정확하게 측정하고자 했다. T-resonator는 microstrip 구조로 구현 되었으며 conductor material은 Cu를 사용하였다. PI 기판의 두께는 25um, Cu의 두께는 PI 기판의 종류에 따라 12um 와 18um, T-resonator line width는 50um로 구현하였다. 또한 공진 주파수에 따라 stub 길이가 다른 10개의 T-resonator를 제작하였다. PI 기판의 유효 유전율을 구하기 위해 stub 길이의 open-end effect와 T-junction effect를 고려하였으며 수식을 통해 정확한 유효 유전률을 추출하였다. 또한 PI 기판의 loss tangent 추출에 필요한 dielectric loss를 추출하기 위해 unload quality factor를 분석하였다. Unload quality factor는 dielectric loss, conductor loss, radiation loss를 구성되며 conductor loss와 radiation loss를 수식에 의해 구하고 dielectric loss를 추출 하였다. 추출 된 dielectric loss를 통해 각각의 T-resonator의 loss tangent 값을 구하였다. T-resonator를 이용한 PI 기판의 측정은 비교적 복잡한 수식에 의해 이루어지지만 정확한 data를 얻을 수 있고 다른 재료의 전기적 특성을 추출하는데 응용이 가능하다.

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Effect of Hydrogen Dilution Ratio on The Si Hetero-junction Interface and Its Application to Solar Cells (수소 희석비에 따른 실리콘 이종접합 계면에 대한 분석 및 태양전지로의 응용)

  • Park, Jun-Hyoung;Myong, Seung-Yeop;Lee, Ga-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.12
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    • pp.1009-1014
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    • 2012
  • Hydrogenated amorphous silicon (${\alpha}$-Si:H) layers deposited by plasma enhanced chemical vapor deposition (PECVD) are investigated for use in silicon hetero-junction solar cells employing n-type crystalline silicon (c-Si) substrates. The optical and structural properties of silicon hetero-junction devices have been characterized using spectroscopy ellipsometry and high resolution cross-sectional transmission electron micrograph (HRTEM). In addition, the effective carrier lifetime is measured by the quasi-steady-state photocoductance (QSSPC) method. We have studied on the correlation between the order of ${\alpha}$-Si:H and the passivation quality at the interface of ${\alpha}$-Si:H/c-Si. Base on the result, we have fabricated a silicon hetero-junction solar cell incorporating the ${\alpha}$-Si:H passivation layer with on open circuit voltage ($V_{oc}$) of 637 mV.

Electrochromic Properties of Symmetric and Asymmetric Viologens (대칭, 비대칭 Viologen 유도체의 전기변색특성)

  • Kim, Sung Hoon;Bae, Jin Seok;Hwang, Seok Hwan;Gwon, Tae Sun;Do, Myung Ki;Park, Chul
    • Journal of the Korean Chemical Society
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    • v.40 no.11
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    • pp.686-691
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    • 1996
  • Several kind of viologen derivatives were synthesized and the electrochromic property of these compounds was examined by cyclovoltametric and chronoamperometric method, relating to the mechanisum of coloring reaction. The electrochromic properties of 1,1'-diethyl-4,4'-bipyridinium dibromide(EV), 1,1'-dipropyl-4,4'-bipyridinium dibromide(PV), 1,1'-dibuthyl-4,4'-bipyridinium dibromide(BV) and 1-ethyl-1'-butyl-4,4'-bipyridinium dibromide(EBV) are studied by using an propylenecarbonate/methanol solution with $Bu_4NBF_4$ as supporting electrolyte. A monomer-dimer equilibrium was proposed to explain the related observation that EV and EBV cation radical solutions are violet at an applied voltage of 1.7∼3.0V but become blue in open-circuit condition.

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Optimum Reduction Condition of SDC-NiO Composite Anode for SDC-based Single Chamber Solid Oxide Fuel Cells (SDC계 단실형 고체산화물 연료전지용 SDC-NiO 복합음극의 최적 환원 조건)

  • Min, Ji-Hyun;Ahn, Sung-Jin;Moon, Joo-Ho;Kim, Joo-Sun
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.542-547
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    • 2007
  • We have determined an optimal reduction condition for NiO-based anode in single chamber solid oxide fuel cells that involve samaria-doped ceria (SDC) as an electrolyte. Optimal condition should not only induce sufficient reduction of NiO to Ni, but also prevent the reduction of SDC electrolyte in order to achieve high open circuit voltage (OCV) and power output. Thermodynamic consideration allowed us to determine the optimal anode reduction condition as $96%H_2-4%H_2O$ atmosphere at $250^{\circ}C$. This finding was in a good agreement with the experimental verifications by monitoring the conductivities of SDC and NiO under different reducing conditions.