• 제목/요약/키워드: One-step synthesis

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Bisphenol sulfone산계 고분자의 합성 및 나일론 오염방지성에 관한 연구 (Ⅱ) (Studies on the Synthesis of Bisphenol Sulfonate Polymers and Their Staining Resist Effect in the Dyeing of Nylon/Cotton Union (Ⅱ))

  • 최영주;송승종;윤남식
    • 한국염색가공학회지
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    • 제13권2호
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    • pp.1-1
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    • 2001
  • In the Previous studies, we reported about the synthesis of poly[3-methylence-3-methylenesodiumbisulfite-bis(4-hydroxypheny)sulfone] (PMSBPS) and their effect on the staining of direct dye on nylon in the dyeing of nylon/cotton union. The results showed that PMSBPS have good staining resist effect on nylon in the dyeing of nylon/cotton union. In this study, the staining resist effects of PMSBPS in varied dyeing process and method were investigated, and the fastness to washing, light, and rubbing of the deed N/C unions was tested. The results are as follows ; 1. In the two bath two step method, the staining of direct dye on nylon was decreased with the concentration of PMSBPS, and the fastness to washing, light, and rubbing of the dyed N/C unions were increased by addition of PMSBPS. 2. In the one bath two step method, optimun concentration of PMSBPS was 4% 0.w.f..

Bisphenol sulforn산계 고분자의 합성 및 나일론 오염방지성에 관한 연구 (II) (Studies on the Synthesis of Bisphenol Sulfonate Polymers and Their Staining Resist Effect in the Dyeing of Nylon/cotton Union ( II ))

  • 최영주;송승종;윤남식
    • 한국염색가공학회지
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    • 제13권2호
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    • pp.87-92
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    • 2001
  • In the Previous studies, we reported about the synthesis of poly(3-methylence-3-methylenesodiumbisulfite-bis(4-hydroxypheny )sulfone] (PMSBPS ) and their effect on the staining of direct dye on nylon in the dyeing of nylon/cotton union. The results shoved that PMSBPS have good staining resist effect on nylon in the dyeing of nylon/cotton union. In this study, the staining resist effects of PMSBPS in varied dyeing process and method were investigated, and the fastness to washing, light, and rubbing of the deed N/C unions was tested. The results are as follows , 1. In the two bath two step method, the staining of direct dye on nylon was decreased with the concentration of PMSBPS, and the fastness to washing, light, and rubbing of the dyed N/C unions were increased by addition of PMSBPS. 2. In the one bath two step method, optimun concentration of PMSBPS was 4% 0.w.f..

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MoS2 Layers Decorated RGO Composite Prepared by a One-Step High-Temperature Solvothermal Method as Anode for Lithium-Ion Batteries

  • Liu, Xuehua;Wang, Bingning;Liu, Jine;Kong, Zhen;Xu, Binghui;Wang, Yiqian;Li, Hongliang
    • Nano
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    • 제13권11호
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    • pp.1850135.1-1850135.8
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    • 2018
  • A one-step high-temperature solvothermal approach to the synthesis of monolayer or bilayer $MoS_2$ anchored onto reduced graphene oxide (RGO) sheet (denoted as $MoS_2/RGO$) is described. It was found that single-layered or double-layered $MoS_2$ were synthesized directly without an extra exfoliation step and well dispersed on the surface of crumpled RGO sheets with random orientation. The prepared $MoS_2/RGO$ composites delivered a high reversible capacity of $900mAhg^{-1}$ after 200 cycles at a current density of $200mAg^{-1}$ as well as good rate capability as anode active material for lithium ion batteries. This one-step high-temperature hydrothermal strategy provides a simple, cost-effective and eco-friendly way to the fabrication of exfoliated $MoS_2$ layers deposited onto RGO sheets.

A Simple One-Step Synthesis of Alkylation Product from Cyclic Allylic Alcohol and Resorcinol

  • Baek, Seung-Hwa;Kim, Young-Ok
    • Archives of Pharmacal Research
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    • 제15권4호
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    • pp.304-308
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    • 1992
  • The alkylation of resorcinol with cyclic allylic alcohol in non-aqueous acid medium gives intermolecular Friedel-Craft compounds. The products are primary alkylation products. The likage always occurs between carbon 3 of cyclic allylic alcohol and the position 2, 4, 5 or 6 of the resorcinol.

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란탄늄 및 네오디늄 금속의 착물합성과 전기화학적 특성 (Synthesis and Electrochemical Characteristics of Lantanium and Neodynium Metal Complexes)

  • 오제직
    • 분석과학
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    • 제6권1호
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    • pp.83-92
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    • 1993
  • 0.05M TEAP를 지지전해질로 한 아세톤용액에서, 란탄늄 및 네오디늄과 몇 가지 리간드의 착물에 대한 전기화학적 거동인 환원전류의 유형, 가역성, 안정도상수, 전류함수 등을 폴라로그래피와 순환전압전류법으로 조사하였다. 환원파는 2단계로 나타났으며, 반응은 확산지배적이고 비가역적이었다. 또한 란탄족 금속이온의 착물에 대하여 안정도상수를 측정하였다.

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One step facile synthesis of Au nanoparticle-cyclized polyacrylonitrile composite films and their use in organic nano-floating gate memory applications

  • 장석재;조세빈;조해나;이상아;배수강;이상현;황준연;조한익;왕건욱;김태욱
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.307.2-307.2
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    • 2016
  • In this study, we synthesized Au nanoparticles (AuNPs) in polyacrylonitrile (PAN) thin films using a simple annealing process in the solid phase. The synthetic conditions were systematically controlled and optimized by varying the concentration of the Au salt solution and the annealing temperature. X-ray photoelectron spectroscopy (XPS) confirmed their chemical state, and transmission electron microscopy (TEM) verified the successful synthesis, size, and density of AuNPs. Au nanoparticles were generated from the thermal decomposition of the Au salt and stabilized during the cyclization of the PAN matrix. For actual device applications, previous synthetic techniques have required the synthesis of AuNPs in a liquid phase and an additional process to form the thin film layer, such as spin-coating, dip-coating, Langmuir-Blodgett, or high vacuum deposition. In contrast, our one-step synthesis could produce gold nanoparticles from the Au salt contained in a solid matrix with an easy heat treatment. The PAN:AuNPs composite was used as the charge trap layer of an organic nano-floating gate memory (ONFGM). The memory devices exhibited a high on/off ratio (over $10^6$), large hysteresis windows (76.7 V), and a stable endurance performance (>3000 cycles), indicating that our stabilized PAN:AuNPs composite film is a potential charge trap medium for next generation organic nano-floating gate memory transistors.

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저 전력 아키텍처 설계를 위한 새로운 자원할당 알고리즘 (A New Resource Allocation Algorithm for Low Power Architecture)

  • 신무경;인치호
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2000년도 추계종합학술대회 논문집(2)
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    • pp.329-332
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    • 2000
  • This paper proposed resource allocation algorithm for the minimum power consumption of functional unit in high level synthesis process as like DSP which is circuit to give many functional unit. In this paper, the proposed method though high level simulation find switching activity in circuit each functional unit exchange for binary sequence length and value bit are logic one value. To used the switching activity find the allocation with minimal power consumption, the proposed method visits all control steps one by one and determines the allocation with minimal power consumption at each control step.

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Flavone의 합성 중간체인 2-Aroyloxyacetophenone류의 새로운 합성법 (Synthesis of 2-Aroyloxyacetophenones as Intermediates for Flavone Synthesis)

  • 송규용;안병준
    • 약학회지
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    • 제38권1호
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    • pp.1-5
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    • 1994
  • We have synthesized some 2-(2-benzyloxybenzoyloxy)-and 2-(2,6-dibenzyloxybenzoyloxy)-acetophenones as intermediates for flavone synthesis. The reaction of polyoxygenated 2-hydroxyacetophenones with 2-benzyloxybenzoic acid or 2,6-dibenzyloxybenzoic acid in the presence of dicyclohexylcarbodiimide and p-dimethylaminopyridine resulted in a good yield$(70{\sim}89%)$ of 2-(2-benzyloxybenzoyloxy)-acetophenones or 2-(2,6-dibenzyloxybenzoyloxy) acetophenones under milder conditions and in shorter time than the previous methods. This new methods using benzoic acids instead of benzoyl chlorides saves one reaction step of acid chlorination in comparision of the previous methods.

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상위레벨 회로합성을 위한 자원제한 스케줄링 알고리즘 (A Resource-Constrained Scheduling Algorithm for High Level Synthesis)

  • 황인재
    • 융합신호처리학회논문지
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    • 제6권1호
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    • pp.39-44
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    • 2005
  • 스케줄링은 CDFG 내의 각 연산에 우선순위 관계를 유지하면서 연산이 수행될 제어스텝을 할당하는 과정으로 합성된 하드웨어의 성능에 직접적인 영향을 미치는 중요한 단계이다. 본 논문에서는 자원제한 스케줄링 알고리즘을 제안한다. 제안된 알고리즘은 주어진 그래프를 분석하여 연산유닛의 개수를 결정하고 이에 따라 각 연산을 제어스텝에 할당한다. 스케줄링 과정 중에 상대적으로 부족한 연산유닛과 여유 있는 연산유닛을 구별하여 연산유닛의 수를 조절한 후 반복적으로 성능개선을 시도하게 된다. 제안된 알고리즘의 성능을 평가하기 위하여 모의실험을 수행하였고 그 결과는 기존의 방법들에 비해 우수함을 알 수 있었다.

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